Effects of oxygen and redox oscillation on degradation of cell-associated lipids in surficial marine sediments

Degradation patterns of sedimentary algal lipids were tracked with time under variable redox treatments designed to mimic conditions in organic-rich, bioturbated deposits. Uniformly ¹³C-labeled algae were mixed with Long Island Sound surface muddy sediments and exposed to different redox regimes, including continuously oxic and anoxic, and oscillated oxic: anoxic conditions. Concentrations of several ¹³C-labeled algal fatty acids (16:1, 16:0 and 18:1), phytol and an alkene were measured serially. Results showed a large difference (∼10×) in first-order degradation rate constants of cell-associated lipids between continuously oxic and anoxic conditions. Exposure to oxic conditions increased the degradation of cell-associated lipids, and degradation rate constants were positive functions (linear or nonlinear) of the fraction of time sediments were oxic. Production of two new ¹³C-labeled compounds (iso-15:0 fatty acid and hexadecanol) further indicated that redox conditions and oxic: anoxic oscillations strongly affect microbial degradation of algal lipids and net synthesis of bacterial biomass. Production of ¹³C-labeled iso-15:0 fatty acid (a bacterial biomarker) was inversely proportional to the fraction of time sediments were oxic, rapidly decreasing after 10 days of incubation under oxic and frequently oscillated conditions. Turnover of bacterial biomass was faster under continuously or occasionally oxic conditions than under continuously anoxic conditions. ¹³C-labeled hexadecanol, an intermediate degradation product, accumulated under anoxic conditions but not under oxic or periodically oxic conditions. The frequency of oxic: anoxic oscillation clearly alters both the rate and pathways of lipid degradation in surficial sediments. Terminal degradation efficiency and lipid products from degradation of algal material depend on specific patterns of redox fluctuations.     

多震相层析成像与在介质中的多波型射线跟踪

本文介绍了多震相的层析成像的思路和算法，通过穿透和反射走时可以同时作出２维和３维慢度（速度的倒数）重建。我们分析了在穿透和反射数据中确定速度和深度的不确定性，并认识到深度扰动对反射走时异常比慢度扰动更敏感。由不同波类型所提供的对速度和深度的约束，这个算法实际上减少了在一般反射层析成像在速度和深度之间的不确定性，并且也避免了在穿透层析成像中的不确定问题。线性化反演是通过从反射界面深度由分离速度参数迭代进行的。使用一个快速的２－Ｄ和３－Ｄ射线跟踪算法来计算穿透和反射走时和对幔度及反射界面深度的偏导数。深度和速度都用立方Ｂ样条函数来进行参数化。合成例子表明，当同时考虑穿透和反射时间，层析成像的结果得到改进。这个方法也应用到英国煤炭测量局（ＢｒｉｔｉｓｈＣｏａｌＭｅａｓｕｒｅｓ）沿跨线排列所记录的逆ＶＳＰ数据组。通过使用波形配合技术，用同时确定时间延迟和叠加权，可以自动拾取旅行时间。所观察到的逆ＶＳＰ层析成像可比周围介质具有较低速度的两个断层区域成像。断层的位置由附近的反射测线所确定。本文还讨论了在复杂２－Ｄ和３－Ｄ非均匀各向同性介质中地震射线跟踪方法。界面的几何形状和水平速度场都通过使用非均匀步长立方Ｂ－样条节点     

Shear-wave anisotropy and the stress field from borehole recordings at 2.5 km depth at Cajon Pass

53 local earthquakes recorded at 2.5 km depth in the Cajon Pass scientific borehole are analysed for shear-wave splitting. The time delays between the split shear waves can be positively identified for 32 of the events. Modelling these observations of polarizations and time delays using genetic algorithms suggests that the anisotropic structure near Cajon Pass has orthorhombic symmetry. The polarization of the shear waves and the inferred strike of the stress-aligned fluid-filled intergranular microcracks and pores suggests that the maximum horizontal compressional stress direction is approximately N13°W. This is consistent with previous results from earthquake source mechanisms and the right-lateral strike-slip motion on the nearby San Andreas Fault, but not with stresses measured within the uppermost 3 km of the borehole. This study suggests that the San Andreas Fault is driven by deeper tectonic stresses and the present understanding of a weak and frictionless San Andreas Fault may need to be modified. The active secondary faulting and folding close to the fault are probably driven by the relatively shallow stress as measured in the 3.5 km deep borehole.     

Measurement of PAN in the Polluted Boundary Layer and Free Troposphere Using a Luminol-NO2 Detector Combined with a Thermal Converter

Peroxyacetyl nitrate (PAN,CH³C(O)O₂NO₂) has been measured inthe polluted boundary layer and free troposphere by thermal conversion tonitrogen dioxide (NO₂) followed by detection of thedecomposition product with a Scintrex LMA-3 NO₂-luminolinstrument. Following laboratory tests of the efficiency of PAN conversionand investigations of possible interferences, the technique was evaluated atthe West Beckham TOR (Tropospheric Ozone Research) Station near the northNorfolk coast in Eastern England between September 1989 and August 1990. PANmeasured by the new technique was reasonably well correlated with PANrecorded using electron capture gas chromatography (EC/GC). PAN was alsowell correlated with ozone (O³) in the summer months. Springand autumn episodes of simultaneously high concentrations of PAN andO³ were examined in conjunction with air parcelback-trajectories and synoptic- and local-scale meteorology in a study ofthe sources of photooxidants on the east coast of England. Spring-timemeasurements of PAN made in the free troposphere in a light aircraft ataltitudes up to 3.1 km showed the presence of 0.54 and 0.26 ppbv PAN inpolar maritime and mid-latitude oceanic air masses, respectively. Thetechnique is particularly suited to airborne applications because potentialinterferences are minimised and the frequency of measurements is higher thangenerally achieved with EC/GC methods.     

Electron spin resonance spectra of marine and fresh-water manganese nodules

Eighty ferromanganese nodules from a wide variety of marine and fresh-water environments have been analyzed by electron spin resonance spectroscopy. The purpose has been to gain information on the forms in which the major constituents of manganese nodules are present. Contributions to ESR spectra of the nodules come mainly from Mn²⁺ and Fe³⁺. Deep-sea samples generally showed only broad resonance lines, and those with larger peaks close to g = 2.0 are believed to contain more Mn²⁺ than others. Some Antarctic and fresh-water nodules lack a strong Mn²⁺ resonance and have a peak around g = 4.0 which is most likely tetrahedral Fe³⁺. A number of smaller peaks in several samples could not be readily interpreted in terms of contributions from individual ionic species because of fundamental problems in preparing standards having the ion of interest in the same micro-environment as it experiences in the nodules.     

Physical processes determining the chromospheric temperature distribution

Calculations performed with several models of the solar chromosphere support Ulmschneider's conclusion that relatively short period acoustic waves heat the low chromosphere in the region just above the temperature minimum. However, these same short period waves (10 period P80 s) are not able to maintain chromospheric temperatures at heights where _5000Å(normal) < 10^-6. The calculations also show that an earlier conjecture stating that the H₂ population might influence the non-LTE chromospheric H^- population is probably not correct, due to lower values of the ratio n _e/n _H inferred from more recent observations. Finally, the calculations support Athay's contention that the Cayrel mechanism alone cannot produce the observed temperature rise, because the magnitude of the radiative cooling in the lines is too great.     

Luna 24 ferrobasalt as a low-Mg primary melt

Luna 24 very-low titanium (VLT) ferrobasalts, metabasalts, brown glasses and impact melts form a tight compositional cluster with no gradation to other groupings postulated for the Luna 24 core components. This suggests that the Luna 24 VLT ferrobasalt was extruded as a liquid of its own composition and was not derived by fractional crystallization from a more magnesian parent in a surface flow. Furthermore, the characteristics of the core lithologies are not easily visualized as components of such a differentiated flow, e.g. brown glasses. Gravitative settling models purporting to demonstrate the validity of the flow differentiation model are merely permissive.Subsurface fractionation requires that plagioclase, not olivine, be the liquidus phase.The high-Mg component in the Luna 24 core can be constrained, though not identified, chemically, and it has neither the major element, trace element, isotopic, nor mineralogical characteristics required of a possible parent to the Luna 24 VLT ferrobasalt. Thus models of fractionation lack a physical expression of the less differentiated compositions, contrary to the belief that the high-Mg component in the core is the parent material.The Luna 24 VLT ferrobasalt is probably a primary low-Mg melt from a plagioclase-bearing source region, and may have undergone little or no fractionation prior to eruption. Such a model is compatible with, and suggested by, chemical and experimental data. Caution against postulating that all Mg-poor melts are fractionated products, based on terrestrial models, is advised. The terrestrial oceanic situation of primary melts with similar Mg/Fe is probably not valid for the Moon.     

Intracratonic asthenosphere upwelling and lithosphere rejuvenation beneath the Hoggar swell (Algeria): Evidence from HIMU metasomatised lherzolite mantle xenoliths

The mantle xenoliths included in Quaternary alkaline volcanics from the Manzaz-district (Central Hoggar) are proto-granular, anhydrous spinel lherzolites. Major and trace element analyses on bulk rocks and constituent mineral phases show that the primary compositions are widely overprinted by metasomatic processes. Trace element modelling of the metasomatised clinopyroxenes allows the inference that the metasomatic agents that enriched the lithospheric mantle were highly alkaline carbonate-rich melts such as nephelinites/melilitites (or as extreme silico-carbonatites). These metasomatic agents were characterized by a clear HIMU Sr–Nd–Pb isotopic signature, whereas there is no evidence of EM1 components recorded by the Hoggar Oligocene tholeiitic basalts. This can be interpreted as being due to replacement of the older cratonic lithospheric mantle, from which tholeiites generated, by asthenospheric upwelling dominated by the presence of an HIMU signature. Accordingly, this rejuvenated lithosphere (accreted asthenosphere without any EM influence), may represent an appropriate mantle section from which deep alkaline basic melts could have been generated and shallower mantle xenoliths sampled, respectively. The available data on lherzolite xenoliths and alkaline lavas (including He isotopes, Ra < 9) indicate that there is no requirement for a deep plume anchored in the lower mantle, and that sources in the upper mantle may satisfactorily account for all the geochemical/petrological/geophysical evidence that characterizes the Hoggar swell. Therefore the Hoggar volcanism, as well as other volcanic occurrences in the Saharan belt, are likely to be related to passive asthenospheric mantle uprising and decompression melting linked to tensional stresses in the lithosphere during Cenozoic reactivation and rifting of the Pan–African basement. This can be considered a far-field foreland reaction of the Africa–Europe collisional system since the Eocene.