Evolution of exhumation and erosion in western West Gondwanaland as recorded by detrital zircons of late Neoproterozoic and Cambrian sedimentary rocks of NW and Central Argentina

The evolution of the provenance areas for Late Neoproterozoic, Cambrian and Early Ordovician sedimentary and meta-sedimentary rocks of north central and northwest Argentina is discussed using 123 maximum ages of detrital zircons from 42 samples from this and previously published studies. Most detrital zircon ages fall into two groups: 1,200–900 Ma and 670–545 Ma. These ages are essentially identical for the non- to very low grade metamorphic late Neoproterozoic to Early Cambrian Puncoviscana Formation and the low to high grade metamorphic rocks of Eastern Sierras Pampeanas. Hence, both units are related to similar provenance areas at the same time of sedimentation. The time span from zircon crystallization in the Earth’s crust to exhumation and erosion may be very long. This is important when determining maximum ages of sedimentary rocks. Variation of zircon maxima may also be influenced by concurrent sedimentary cover of proposed provenance areas. For the late Mesoproterozoic to early Neoproterozoic zircon age group, an active mountain range of the southwest Brazilian Sunsás orogen is the most probable provenance area. The younger, late Neoproterozoic zircons are related to the continuously developing mountains of the Brasiliano orogen of southwest and south central Brazil. Young zircons, up to 514 Ma, from fossil-bearing Puncoviscana and Suncho Formation outcrops are related to late Early Cambrian volcanism contemporaneous with sedimentation. This situation continues through the Late Cambrian to the Early Ordovician, but the Sunsás orogen provenance diminishes as possible Río de la Plata craton origins become important.     

Phase fractionation and oil-condensate mass balance in the South Marsh Island Block 208–239 area,offshore Louisiana

Phase fractionation can strongly deplete oil of its volatile compounds in a regular and characteristic fashion. This process has affected oils to a remarkably uniform extent throughout the 30 × 15 km South Marsh Island 208–239 and Vermilion 30–31 area (including the Tiger Shoal, Starfak, Mound Point, Lighthouse Point, Amber, Trinity Shoal, and Aquamarine fields) just offshore Louisiana. Fractionation of the original “parent” oil likely occurred in the deep, relatively flat-lying Rob L sand that underlies the area, and produced gas-washed oils (mean API 33°) and gas condensates (mean API 50°) in a volume ratio of 1:3.5. Both fractionated oil and vapor migrated from the fractionation site to shallower reservoirs. However, the estimated ultimate production ratio of gas-washed oil to gas condensate in this group of fields is 1:0.32, about 11 times higher than would be expected on mass balance considerations alone. Thus, there is an apparent deficiency of producible gas condensate relative to the amount of producible oil for the entire study area and for every field in that area. In the case of the Tiger Shoal field, the ratio of industry-estimated ultimately producible oil to gas condensate is 1:1.1. Based on the production data, we conclude that either there is an additional 6.4 × 10⁶ m³ (43 MMbbl) of undiscovered and/or unproduced condensate in the area or that condensate has escaped preferentially in vapor form to the seafloor. The well-studied and nearly depleted Tiger Shoal field provides a good example of how chemical data can be analyzed in a way that contributes insight into the phase fractionation process and the remaining exploration potential of an area.     

User fees as sustainable financing mechanisms for marine protected areas: An application to the Bonaire National Marine Park

Marine protected areas (MPAs) have proliferated globally in the past three decades. However, inadequate funding often prevents these management regimes from fulfilling their missions. Managers have become increasingly aware that successful protection of marine ecosystems is dependent not only upon an understanding of their biological and physical processes, but also their associated social and economic aspects. Unfortunately, economic values associated with MPAs and the natural resources they protect are rarely considered in decision-making and policy development. This study addresses this information gap by examining scuba divers’ willingness to pay for access to quality recreational sites in the Bonaire National Marine Park, Bonaire, Netherlands Antilles. The findings indicate that the US$10 annual diver user fee in effect at the time of the study could be increased substantially without a significant adverse effect on island tourism. Depending on question format, mean willingness to pay for annual access ranged from US$61 to US$134 (2002$). All model specifications support the conclusion that doubling the US$10 user fee would have virtually no impact on visitation rates. The increased revenue generated from this sustainable financing mechanism is more than sufficient to fund both current and enhanced marine park operations.     

The age of the Whin Sill

The Whin Sill and its related dykes are intruded into Carboniferous strata in the North of England. Together they form a distinct petrographical province in which basic magmatism appears to have been closely related to a single phase in the structural history of the area. The relevant stratigraphical, structural and isotopic evidence suggests to the authors that the Whin Sill suite was intruded during the Stephanian, around 295 ± 6 m.y. This conclusion is supported by twenty-one new potassium-argon age determinations accompanied by a petrographical study of the factors which cause discrepancy in isotopic results from Whin Sill rocks.     

Comparison of tree transpiration under wet and dry canopy conditions in a Costa Rican premontane tropical forest

Spatial and temporal variation in wet canopy conditions following precipitation events can influence processes such as transpiration and photosynthesis, which can be further enhanced as upper canopy leaves dry more rapidly than the understory following each event. As part of a larger study aimed at improving land surface modelling of evapotranspiration processes in wet tropical forests, we compared transpiration among trees with exposed and shaded crowns under both wet and dry canopy conditions in central Costa Rica, which has an average 4200 mm annual rainfall. Transpiration was estimated for 5 months using 43 sap flux sensors in eight dominant, ten midstory and eight suppressed trees in a mature forest stand surrounding a 40‐m tower equipped with micrometeorological sensors. Dominant trees were 13% of the plot's trees and contributed around 76% to total transpiration at this site, whereas midstory and suppressed trees contributed 18 and 5%, respectively. After accounting for vapour pressure deficit and solar radiation, leaf wetness was a significant driver of sap flux, reducing it by as much as 28%. Under dry conditions, sap flux rates (J_s) of dominant trees were similar to midstory trees and were almost double that of suppressed trees. On wet days, all trees had similarly low J_s. As expected, semi‐dry conditions (dry upper canopy) led to higher J_s in dominant trees than midstory, which had wetter leaves, but semi‐dry conditions only reduced total stand transpiration slightly and did not change the relative proportion of transpiration from dominant and midstory. Therefore, models that better capture forest stand wet–dry canopy dynamics and individual tree water use strategies are needed to improve accuracy of predictions of water recycling over tropical forests. Copyright © 2016 John Wiley & Sons, Ltd.     

Obstacles to long‐term soil moisture monitoring with heated distributed temperature sensing

The field deployment of a heated distributed temperature sensor (DTS) for over three years has revealed two obstacles to estimating soil moisture (θ) that may hamper subsurface DTS applications as well as use of other subsurface thermal probes. The first observed obstacle was a hysteretic response of the DTS sensor. The relationship between θ and the temperature response (?T) within the cable was not only dependent on θ of the soil, but also on the previous wetting and drying cycles leading to that state. The second observed obstacle was soil structure healing. Soil structure healing causes the relationship between ?T and θ to evolve through time; this calibration curve becomes flatter, or less sensitive, as the surrounding soil makes better contact with the cable. Effects of the hysteretic response of the instrument and soil structure healing are largely the result of small gaps between the cable and soil. These small gaps can be approximated by a contact resistance between the cable and soil. In this article we characterize the occurrence of hysteretic and soil structure healing effects from field data and parameterize contact resistance by simulating heat transfer using a numerical modelling approach Copyright © 2015 John Wiley & Sons, Ltd.     

High-redshift voids in the excursion set formalism

Voids are a dominant feature of the low-redshift galaxy distribution. Several recent surveys have found evidence for the existence of large-scale structure at high redshifts as well. We present analytic estimates of galaxy void sizes at redshifts   z ∼ 5–10  using the excursion set formalism. We find that recent narrow-band surveys at   z ∼ 5–6.5  should find voids with characteristic scales of roughly 20 comoving Mpc and maximum diameters approaching 40 Mpc. This is consistent with existing surveys, but a precise comparison is difficult because of the relatively small volumes probed so far. At   z ∼ 7–10  , we expect characteristic void scales of ∼14–20 comoving Mpc assuming that all galaxies within dark matter haloes more massive than  10¹⁰ M_⊙  are observable. We find that these characteristic scales are similar to the sizes of empty regions resulting from purely random fluctuations in the galaxy counts. As a result, true large-scale structure will be difficult to observe at   z ∼ 7–10  , unless galaxies in haloes with masses  ≲10⁹ M_⊙  are visible. Galaxy surveys must be deep and only the largest voids will provide meaningful information. Our model provides a convenient picture for estimating the 'worst-case' effects of cosmic variance on high-redshift galaxy surveys with limited volumes.     

ELEMENTAL ABUNDANCES IN THE HAVERÖ METEORITE

Abundances of 15 major, minor and trace elements have been determined in powders and interior chips derived from the Haverö ureilite. The values are in close agreement with mean values for other ureilites, as reported in the literature. The powdered samples exhibited slightly higher abundances of O and Si, than the interior chips. It is suggested that this may be due to alteration of the samples during the powdering process