Melting relations of basalt-andesile-rhyolite-H2O and a pelagic red clay at 30 kb

An olivine basalt, a tonalite (andesite), a granite (rhyolite), and a red clay (pelagic sediment) were reacted, with known quantities of water in sealed noble metal capsules, in a piston-cylinder apparatus at 30 kb pressure. For the pelagic sediment, with H₂O+=7.8% and no additional water, the liquidus temperature is 1240°C, the primary phases are garnet and kyanite. The subsolidus phase assemblage is phengite mica+garnet+clinopyroxene+coesite+kyanite. With 5 wt.% water added, the liquidus temperatures and primary phases for the calc-alkaline rocks are 1280°-1180°-1080°, garnet+clinopyroxene, garnet, and quartz respectively. Garnet and clinopyroxene occur throughout the melting interval of the olivine tholeiite for all water contents. Garnet is joined by clinopyroxene 80° below the andesite plus 5% H₂O liquidus, quartz is joined by clinopyroxene 180° below the rhyolite plus 5% H₂O liquidus. The subsolidus phase assemblage is garnet+clinopyroxene+coesite+minor kyanite for all the calc-alkaline compositions. We conclude that calc-alkaline andesites and rhyolites are not equilibrium partial melting pruducts of subducted oceanic crust consisting of olivine tholeiite basalt and siliceous sediments. Partial melting in subduction zones produces broadly acid and intermediate liquids, but these liquids lie off the calc-alkaline basalt-andesite-rhyolite join and must undergo modification at lower pressures to produce calcalkaline magmas erupted in overlying island arcs.     

Agrigan: An introduction to the geology of an active volcano in the Northern Mariana Island arc

Agrigan is the tallest (965 m a.s.l.) and largest (44 km²) of the volcanoes of the northern Mariana Islands. Its slopes are asymmetric to the east; a small caldera (4 km²) dominates the interior. The volcanic edifice has been disrupted along three sets of faults: 1) exterior slump faults, 2) radial faults, and 3) interior faults related to caldera-collapse. The rocks of the volcano are characterized by porphyritic clinopyroxene-olivine-plagioclase basalts and subordinate andesites. Cumulate xenoliths composed of Fo₈₁, An₉₅ and diopside are common in the basalts. Development of the volcano began with 3–4 km of submarine growth. The earliest recognizable flows are the result of fissural Hawaiian- and Strombolian-type eruptions. These were followed by the eruption of more viscous lavas from above the present summit. Flank eruptions of basalt and andesite preceded voluminous outpourings of andesitic pyroclastics contemporaneous with caldera-collapse. Subsequent magmatic resurgence is localized along a N10E rift zone. Violent ejection of lapilli and ash occurred in 1917.     

Field and geochemical data bearing on the development of a mesozoic volcano-tectonic rift zone and back-arc basin in southernmost South America

A broad zone of dominantly subaerial silicic volcanism associated with regional extensional faulting developed in southern South America during the Middle Jurassic, contemporaneously with the initiation of plutonism along the present Pacific continental margin. Stratigraphic variations observed in cross sections through the silicic Jurassic volcanics along the Pacific margin of southernmost South America indicate that this region of the rift zone developed as volcanism continued during faulting, subsidence and marine innundation. A deep, fault-bounded submarine trough formed near the Pacific margin of the southern part of the volcano-tectonic rift zone during the Late Jurassic. Tholeiitic magma intruded within the trough formed the mafic portion of the floor of this down-faulted basin. During the Early Cretaceous this basin separated an active calc-alkaline volcanic arc, founded on a sliver of continental crust, from the then volcanically quiescent South American continent. Geochemical data suggest that the Jurassic silicic volcanics along the Pacific margin of the volcano-tectonic rift zone were derived by crustal anatexis. Mafic lavas and sills which occur within the silicic volcanics have geochemical affinities with both the tholeiitic basalts forming the ophiolitic lenses which are the remnants of the mafic part of the back-arc basin floor, and also the calc-alkaline rocks of the adjacent Patagonian batholith and their flanking lavas which represent the eroded late Mesozoic calc-alkaline volcanic arc. The source of these tholeiitic and calc-alkaline igneous rocks was partially melted upper mantle material. The igneous and tectonic processes responsible for the development of the volcano-tectonic rift zone and the subsequent back-arc basin are attributed to diapirism in the upper mantle beneath southern South America. The tectonic setting and sequence of igneous and tectonic events suggest that diapirism may have been initiated in response to subduction.     

Detecting a Global Warming Signal in Hemispheric Temperature Series: AStructural Time Series Analysis

Non-stationary time series such as global andhemispheric temperatures, greenhouse gasconcentrations, solar irradiance, and anthropogenicsulfate aerosols, may contain stochastic trends (thesimplest stochastic trend is a random walk) which, dueto their unique patterns, can act as a signal of theinfluence of other variables on the series inquestion. Two or more series may share a commonstochastic trend, which indicates that either oneseries causes the behavior of the other or that thereis a common driving variable. Recent developments ineconometrics allow analysts to detect and classifysuch trends and analyze relationships among seriesthat contain stochastic trends. We apply someunivariate autoregression based tests to evaluate thepresence of stochastic trends in several time seriesfor temperature and radiative forcing. The temperatureand radiative forcing series are found to be ofdifferent orders of integration which would cast doubton the anthropogenic global warming hypothesis.However, these tests can suffer from size distortionswhen applied to noisy series such as hemispherictemperatures. We, therefore, use multivariatestructural time series techniques to decomposeNorthern and Southern Hemisphere temperatures intostochastic trends and autoregressive noise processes. These results show that there are two independentstochastic trends in the data. We investigate thepossible origins of these trends using a regressionmethod. Radiative forcing due to greenhouse gases andsolar irradiance can largely explain the common trend.The second trend, which represents the non-scalarnon-stationary differences between the hemispheres,reflects radiative forcing due to tropospheric sulfateaerosols. We find similar results when we use the sametechniques to analyze temperature data generated bythe Hadley Centre GCM SUL experiment.     

New evidence for Jurassic continental rifting in the northern Sanandaj Sirjan Zone,western Iran: the Ghalaylan seamount,southwest Ghorveh

ABSTRACT

We address the growing controversy about the tectonic setting in which Jurassic magmatism of Iran occurred: arc or continental rift. In the Ghorveh area of the northern Sanandaj Sirjan zone (SaSZ), the Ghalayan metabasites are interlayered with marble and schist and locally cut by acidic dikes. Zircon U-Pb dating of the metabasitic rocks shows that these crystallized at ca. 145–144 Ma ago in the Late Jurassic (Tithonian). This complex was metamorphosed in the lower greenschist facies, however, some protolithic structures such as pillow lava and primary minerals are preserved. The metabasites are tholeiites with low SiO₂ (45.6–50.5 wt.%), moderate Al₂O₃ (11.3–17.0 wt.%), and high TiO₂ (0.7–2.9 wt.%) and Fe₂O₃ (9.4–14.1 wt.%). The Ghalayan metabasites are enriched in Light rare earth elements (LREEs) without significant Nb, Ta, Pb, Sr and Ba anomalies, similar to modern continental intra-plate tholeiitic basalts such as Afar and East African rifts. The Ghalaylan metabasites show wide ranges for ⁸⁷Sr/⁸⁶Sr_(i) (0.7039–0.7077) and positive ε_Nd(t) values (+0.1 to +4.6). These isotopic compositions are similar to those expected for slightly depleted subcontinental lithospheric mantle sources. Independently built discrimination diagrams indicate an intra-continental rifting regime for the source of Jurassic metabasites in the northern SaSZ. Geochemical and tectonic evidence suggests that rifting or a mantle plume was responsible for volcanic activity in the Upper Jurassic SaSZ. Considering the variation of ages of basaltic volcanism along the SaSZ, we suggest that Ghalayan basaltic magmatism reflected a submarine volcano that formed as part of the late stage continental rift, similar to Afar in the East African Rift system. Our results indicate that an extensional tectonic regime dominated SaSZ tectonics in the Middle to Late Jurassic.     

Surface runoff in a torrent catchment area in Middle Europe and its prevention

The Schesa, a sinister contributory torrent to the Ill river near Bludenz (federal province of Vorarlberg) is the largest basin-shaped gully of Middle Europe and endangers the underlying villages by torrential debris flow and gigantic mass movements. The catchment is characterized by a complex geological situation, high annual precipitation and torrential rains from spring to early autumn, which cause enormous amounts of surface runoff. Based on field investigations comprising rain simulation experiments on representative plots, investigations on land-use, vegetation cover, soil physical characteristics, geology, hydrogeology and other features of the catchment area, surface runoff coefficient maps were developed. They formed the basis for assessment of runoff potential for different scenarios in vegetation cover and land-use intensity. Calculation of runoff for the recurrent design event by use of an improved run-time method showed the urgent necessity of runoff reduction measures in large parts of the catchment area above the gully. Based on the modelling results a concept for reduction of both, surface runoff and amount of deep percolating water has been elaborated.     

Stable isotope evidence for regional-scale fluid migration in a Barrovian metamorphic terrane,Vermont, USA

We measured the C- and O-isotopic composition of carbonate minerals in the Waits River Formation, eastern Vermont, to determine the extent of fluid infiltration during regional metamorphism over an approx. 2000 km² area in a deep-seated (>25 km) Barrovian terrane. From a petrologic study of this terrane, Ferry proposed the existence of a large regional metamorphic hydrothermal system with two first-order features: (1) on the scale of the entire terrane fluid flow was focused into the axes of two major antiforms of regional extent; (2) on a smaller scale (about 100 km²) flow was further focused around synmetamorphic granitic plutons that intruded along the axes of the antiforms. We find isotopic evidence for both the regional hydrothermal activity along the antiforms and the more intense fluid flow around synmetamorphic plutons. The evidence for hydrothermal activity around the plutons is large heavy isotope depletions, up to 6–9 in ¹⁸O_carb and ¹³C_carb, in diopside zone rocks adjacent to the plutons. These isotopic shifts are greater than can be explained solely by prograde metamorphic reactions. We find two lines of evidence for the more diffuse regional flow that was focused into axes of the antiforms. First, ¹⁸O_carb and ¹³C_carb, within individual outcrops become increasingly homogeneous with increasing grade towards antiform axes, indicating that the rocks equilibrated with a permeating fluid. Second, there are depletions in ¹⁸O near the margins of the Waits River Formation which can be interpreted as a dispersed, advective infiltration front displaced toward the antiform axes. These fronts were modelled using Eq. 13 of Bickle and Baker and imply time-integrated fluid of 10⁵–10⁶ cm³/cm², which are consistent with values derived by Ferry from measured progress of prograde devolatilization reactions.     

Composition, age, and origin of the ~620?Ma Humr Akarim and Humrat Mukbid A-type granites: no evidence for pre-Neoproterozoic basement in the Eastern Desert, Egypt

The Humr Akarim and Humrat Mukbid plutons, in the central Eastern Desert of Egypt, are late Neoproterozoic post-collisional alkaline A-type granites. Humr Akarim and Humrat Mukbid plutonic rocks consist of subsolvus alkali granites and a subordinate roof facies of albite granite, which hosts greisen and Sn–Mo-mineralized quartz veins; textural and field evidence strongly suggest the presence of late magmatic F-rich fluids. The granites are Si-alkali rich, Mg–Ca–Ti poor with high Rb/Sr (20–123), and low K/Rb (27–65). They are enriched in high field strength elements (e.g., Nb, Ta, Zr, Y, U, Th) and heavy rare earth elements (La _n /Yb _n ?=?0.27–0.95) and exhibit significant tetrad effects in REE patterns. These geochemical attributes indicate that granite trace element distribution was controlled by crystal fractionation as well as interaction with fluorine-rich magmatic fluids. U–Pb SHRIMP zircon dating indicates an age of ~630–620?Ma but with abundant evidence that zircons were affected by late corrosive fluids (e.g., discordance, high common Pb). εNd at 620?Ma ranges from +3.4 to +6.8 (mean?=?+5.0) for Humr Akarim granitic rocks and from +4.8 to +7.5 (mean?=?+5.8) for Humrat Mukbid granitic rocks. Some slightly older zircons (~740?Ma, 703?Ma) may have been inherited from older granites in the region. Our U–Pb zircon data and Nd isotope results indicate a juvenile magma source of Neoproterozoic age like that responsible for forming most other ANS crust and refute previous conclusions that pre-Neoproterozoic continental crust was involved in the generation of the studied granites.