The alteration of olivine in basaltic and associated lavas

Olivines which cool under oxidizing conditions exsolve iron oxides at high temperature, and at low temperatures break down to essentially chloritic materials. Olivines which cool under non-oxidizing conditions alter at intermediate temperatures to complex assemblages of chlorite and interstratified phyllosilicates containing a smectite. Alteration under oxidizing conditions at low temperature, probably below 140° C, produces iddingsite, an orientated assemblage of goethite and interstratified phyllosilicates also containing a smectite.Post-deuteric alteration extends or initiates the breakdown of olivine to phyllosilicate mixtures often resulting in widespread movement of materials through the flow. Post-deuteric alteration of iddingsite produces strongly pleochroic, highly ordered varieties which eventually break down to green phyllosilicate assemblages.Weathering of olivine may produce orientated assemblages similar to deuteric forms of iddingsite. Weathering of green alteration products results in oxidation and the liberation of discrete iron hydroxides.Alteration in all cases requires exchange of material between interstitial components and olivine. During deuteric alteration, plagioclase and pyroxene are usually unaffected.     

Coexisting clinopyroxene,garnet and amphibole from an “eclogite”, Kakanui,New Zealand

Analyses of major and rare earth elements are presented for co-existing garnet, clinopyroxene, and amphibole from a Kakanui eclogite.New and previously published analyses of garnets suggest a gradual increase of Fe and decrease of Mg from xenocrysts through garnet pyroxene eclogitic rocks to amphibole-rich eclogitic rocks. Clinopyroxenes show a parallel increase in Fe/Mg ratio and an increase in Jadeite component and decrease in Tschermak's component. These data indicate crystallization of garnet and clinopyroxene from an alkali-rich undersaturated magma and are consistent with the concept of eclogite fractionation, but rare earth data allow severe constraints to be placed on this process. The eclogites are considered to be deep-seated crystallization products of nephelinite, but eclogite fractionation is small and cannot account for the association of alkali basalt, basanite and nephelinite.     

Diatom evidence on Wisconsin and Holocene events in the Bering Sea

Previous work on surface (modern) sediments has defined diatom species which appear to be good indicators of various oceanographic/ecologic conditions in the North Pacific Ocean and marginal seas. Three long cores from the eastern and northern sides of the Aleutian Basin show changes in species assemblage which can be interpreted in terms of changes in the ocean environment during the last glaciation (Wisconsin) and the Holocene. The early and late Wisconsin maxima were times of prolonged annual sea-ice cover and a short cool period of phytoplankton productivity during the ice-free season. The middle Wisconsin interstade, at least in the southern Bering Sea, had greater seasonal contrast than today, with some winter sea-ice cover, an intensified temperature minimum, and high spring productivity. Variations in clastic and reworked fossil material imply varying degrees of transport to the basin by Alaskan rivers. The results of Jousé from the central Bering Sea generally correspond with those presented here, although there are problems with direct comparison.     

Strontian-loparite and strontio-chevkinite: Two new minerals in rheomorphic fenites from the Paraná Basin carbonatites,South America

Contributions to Mineralogy and Petrology - Strontian-loparite is recognized at Sarambi and Chiriguelo, Paraguay and at Salitre I, Brazil as an accessory mineral in rheomorphic...     

Invariant point configurations—a combinatorial approach

A combinatorial and algebraic approach has been applied to the problem of determining the number of distinct configurations of univariant reaction lines about an invariant point, NC, in nondegenerate n-component systems. The resulting expression is $$NC = [1/(4n + 8)]\left( {\sum {[2^{d/2} (\phi (2n + 4)/d]) + (n + 2) 2^{\{ (n + 2)/2\} } } } \right) - 1$$ where the summation is taken over all values of d which divide (2n + 4)evenly but which do not divide (n + 2)evenly, [(n + 2)/2]is the smallest integer greater than or equal to (n + 2)/2,and ø[(2n + 4)/d]is the number of integers less than (2n + 4)/d whose only factor is common with (2n + 4)/d is 1.This concise expression is derived through the application of Burnside's lemma, which relates the number of equivalence classes into which a set S is divided by an equivalence relation induced by a permutation group of S to the number of elements of S left invariant by the members of the permutation group. In the derivation of the above expression, the set S is taken to be the set of all possible configurations and orientations of univariant lines about an invariant point, the permutation group is taken to be the set of rigid-body symmetries of S, and the equivalence classes are composed of the different orientations of each configuration. Although the methods used to obtain the above expression are probably unfamiliar to most geologists, they are standard mathematical techniques and represent just one application of these tools to problems of geologic interest.     

Shoreline erosion rates along barrier islands of the north central gulf of Mexico

Rates of shoreline change and overwash penetration distances were calculated for barrier islands along the Louisiana, Mississippi, and Alabama coasts with the orthogonal grid mapping system (OGMS). Average rates of shoreline change are exceptionally high in Louisiana, being of the order ?4.7 to ?7.4 m yr^?1. Mississippi and Alabama recession rates are lower and range from ?2.0 to ?3.1 m yr^?1 over the period of record. Erosion rates along the shorelines of these islands have remained relatively constant over the period of study with five exceptions in coastal Louisiana and the Chandeleur-Breton Islands Arc, and two exceptions along the Mississippi-Alabama barrier islands where they have accelerated. Mean overwash penetration is greatest along Dauphin Island, Alabama, and Cat Island, Mississippi: 207.6 and 197.9 m, respectively. The Chandeleur-Brenton Islands Arc range from 88.1 m at the central barrier to 180.4 along the flanks. The Mississippi islands range from 105.2 m on Ship Island to 200.5 m along central Horn Island. Mean overwash penetration along the Louisiana barriers is highly variable: 46.3 to 211.4 m.     

Komatiites and nickel sulfide ores of the Black Swan area,Yilgarn Craton,Western Australia. 3: Komatiite geochemistry,and implications for ore forming processes

The Black Swan komatiite sequence is a package of dominantly olivine-rich cumulates with lesser volumes of spinifex textured rocks, interpreted as a section through an extensive komatiite lava flow field. The sequence hosts a number of nickel sulfide orebodies, including the Silver Swan massive shoot and the Cygnet and Black Swan disseminated orebodies. A large body of whole rock analyses on komatiitic rocks from the Black Swan area has been filtered for metasomatic effects. With the exception of mobile elements such as Ca and alkalis, most samples retain residual igneous geochemistry, and can be modelled predominantly by fractionation and accumulation of olivine. Whole rock MgO–FeO relationships imply a relatively restricted range of olivine compositions, more primitive than the olivine which would have been in equilibrium with the transporting komatiite lavas, and together with textural data indicate that much of the cumulus olivine in the sequence was transported. Flow top compositions show evidence for chromite saturation, but the cumulates are deficient in accumulated chromite. Chromite compositions are typical of those found in compound flow-facies komatiites, and are distinct from those in komatiitic dunite bodies. Incompatible trace element abundances show three superimposed influences: control by the relative proportion of olivine to liquid; a signature of crustal contamination and an overprint of metasomatic introduction of LREE, Zr and Th. This overprint is most evident in cumulates, and relatively insignificant in the spinifex rocks. Platinum and palladium behaved as incompatible elements and are negatively correlated with MgO. They show no evidence for wholesale depletion due to sulfide extraction, which was evidently restricted to specific lava tubes or pathways. The lack of correspondence between PGE depletion and contamination by siliceous material implies that contamination alone is insufficient to generate S-saturation and ore formation in the absence of sulfide in the assimilant. Contamination signatures in spinifex-textured rocks may be a guide to Ni-sulfide mineralisation, but are not entirely reliable in the absence of other evidence. The widespread vesicularity of the sequence may be attributable to assimilated water rather than to primary mantle-derived volatiles, and cannot be taken as evidence for primary volatile-rich magmas. The characteristic signature of the Black Swan Succession is the presence of highly localised disseminated sulfide within a sequence showing more widespread evidence for crustal contamination and interaction with its immediate substrate. This has important implications for the applicability of trace element geochemistry in exploration for komatiite-hosted nickel deposits.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: Peter Lightfoot     

Komatiites and nickel sulfide ores of the Black Swan area,Yilgarn Craton,Western Australia. 4. Platinum group element distribution in the ores,and genetic implications

The Black Swan komatiite sequence, in the Eastern Goldfields province of the Archaean Yilgarn Craton in Western Australia, is a body of dominantly olivine-rich cumulates with lesser volumes of spinifex textured rocks, interpreted as a section through an extensive komatiite lava flow field. The sequence hosts a number of nickel sulfide orebodies, including the Silver Swan massive shoot and the Cygnet and Black Swan disseminated orebodies. The massive sulfide orebodies of the Black Swan Succession are pervasively depleted in all platinum group elements (PGEs), particularly Pt and Pd, despite very high Ni contents. This depletion cannot be explained by R-factor variations, which would also require relatively low Ni tenors. The PGE depletion could be explained in part if the ores are enriched in a monosulfide solid solution (MSS) cumulate component, but requires some additional fractional segregation of sulfide melt upstream from the site of deposition. The Silver Swan orebody shows a remarkably consistent vertical zonation in PGE contents, particularly in Ir, Ru, Rh, Os, which increase systematically from very low levels at the stratigraphic base of the sulfide body to maxima corresponding roughly with the top of a lower layer of the orebody rich in silicate inclusions. Platinum shows the opposite trend, but is somewhat modified by remobilisation during talc carbonate alteration. A similar pattern is also observed in the adjacent White Swan orebody. This zonation is interpreted and modelled as the result of fractional crystallisation of MSS from the molten sulfide pool. The strong IPGE depletion towards the base of the orebody may be a consequence of sulfide liquid crystallisation in an inverted thermal gradient, between a thin rapidly cooling upper rind of komatiite lava and a hot substrate.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: Peter Lightfoot     

Velocity and runout simulation of destructive debris flows and debris avalanches in pyroclastic deposits,Campania region,Italy

The Campanian Apennines are characterized by the presence of monocline ridges, mainly formed by limestone. During the periods of volcanic activity of the Somma-Vesuvius and Phlegrean Fields, the ridges were mantled with pyroclastic materials in varying thickness. The pyroclastics have been involved in destructive landslides both in historical time and in the recent past (1997, 1998, 1999). The landslides occur following intense and prolonged rainfalls. In some cases, landslides extended up to 4 km into the surrounding lowlands and reached towns, causing severe destruction and over 200 deaths. Generally, the landslides begin as small debris slides that develop into large, shallow debris avalanches or debris flows involving pyroclastic horizons and colluvial soils (0.5–2 m thick) on steep and vegetated slopes, often at the heads of gullies. During motion, the landslide materials eroded vegetation and soils from the slope, so that the moving material volume tended to increase. Then, proceeding towards and beyond the base of the slopes, the phenomena evolved into hyperconcentrated streamflow due to dilution by incorporating water. The results of motion analyses are described. An empirical rheological relationship was used including two principal terms that depend on the total normal stress and on the flow velocity. On this basis, the model has simulated the velocity and duration of debris avalanches and the distribution of the deposits. The selected areas were those of Sarno/Quindici and Cervinara, where a large amount of data is available both on the material properties and geomorphological setting. It was found that the majority of the cases at the two sites can be simulated successfully with only one specific pair of rheologic parameters. This provides the possibility for first-order predictions to be made of the motion of future landslides. Such predictions will be a valuable tool for outlining potential hazard areas and designing remedial measures.