Acidity of twelve northern New England (U.S.A.) lakes in recent centuries

Studies of sediment cores from 12 acidic lakes in granitic, forested and uninhabited catchments in northern New England, U.S.A. produced diatom-inferred pH (IpH) 5.2 to 5.8 and alkalinity (Ialk) –12 to 31 µeq l^–1, with slowly declining values at some lakes, for one to four centuries prior to logging. Increases of IpH (0.05 to 0.60) and Ialk (5 to 40 µeq l^–1) correlate with logging in the catchments in the early-1800s to early-1900s. Recovery to pre-logging IpH and Ialk correlates with forest succession toward conifers, and is completed in the late-1800s to mid-1900s. Beginning at 1915–1920 (4 lakes), 1930–1950 (4 lakes) and 1965–1970 (4 lakes), IpH and Ialk start decreasing below pre-logging values due to atmospheric acidic deposition, leading to respective total decreases of 0.10 to 0.45 (X=0.25) and 5 to 25 µeq l^–1 (X=15). Inputs of anthropogenic Pb, Zn, V, polycyclic aromatic hydrocarbons, and soot from the atmosphere are first detectable in early- to late-1800s sediment, and Cu in late-1800s sediment, increase rapidly in the late-1800s to mid-1900s, and level off or decrease since the 1960s — partly due to emission controls. Decreasing Ca, Mn, and possibly Zn relative to other metals and normalized to organic content, and increasing flux of Fe to the lakes, indicate soil and water acidification after 1900.This is the fourteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

Identification of a collapsing protostar

The globular molecular cloud B335 contains a single, deeply embedded, far-infrared source. Our recent observations of H₂CO and CS lines toward this source provide direct kinematic evidence for collapse. Both the intensity and detailed shape of the line profiles match those expected from inside-out collapse inside a radius of 0.036 pc. The collapse began about 1.5 × 10⁵ years ago, similar to the onset of the outflow. The mass accretion rate is about 10 times the outflow rate, and about 0.4M should have now accumulated in the star and disk. Because B335 rotates only very slowly, any disk would still be very small (about 3 AU). The accretion luminosity should be adequate to power the observed luminosity. Consequently, we believe that B335 is indeed a collapsing protostar.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.     

Temporal X-ray astronomy with a pinhole camera

The first preliminary results from the Ariel-5 All-Sky X-Ray Monitor are presented, along with sufficient experiment details to define the experiment sensitivity. Periodic modulation of the X-ray emission is investigated from three sources with which specific periods have been associated, with the results that the 4.8 h variation from Cyg X-3 is confirmed, a long-term average 5.6 day variation from Cyg X-1 is discovered, and no detectable 0.787 day modulation of Sco X-1 is observed. Consistency of the long-term Sco X-1 emission with a shot-noise model is discussed, wherein the source behavior is shown to be interpretable as 100 flares per day, each with a duration of several hours. A sudden increase in the Cyg X-1 intensity by almost a factor of three on 22 April, 1975 is reported, after 5 months of relative source constancy. The light curve of a bright nova-like transient source in Triangulum is presented, and compared with previously observed transient sources. Preliminary evidence for the existence of X-ray bursts with duration <1 h is offered, with the caveat that there is not yet any supporting evidence to guarantee that the effect is truly astronomical.Paper presented at the COSPAR Symposium on Fast Transients in X- and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

Detrital and pedogenic magnetic mineral phases in the loess/palaeosol sequence at Lingtai (Central Chinese Loess Plateau)

A detailed rock magnetic investigation of loess/palaeosol samples from the section at Lingtai on the central Chinese Loess Plateau (CLP) is presented. Thermal demagnetisation of isothermal remanent magnetisation (IRM) and Curie temperature measurements suggest the presence of magnetite, maghemite and hematite as remanence carrying components. Bulk and grain size fractionated samples have been analysed using coercivity spectra of remanence acquisition/demagnetisation curves, which identify four main remanence carriers in different grain size fractions of loesses and palaeosols. A linear source mixing model quantifies the contribution of the four components which have been experimentally derived as dominating endmembers in specific grain size fractions. Up to two thirds of the total IRM of the palaeosols are due to slightly oxidised pedogenic magnetite. Two detrital components dominate up to 90% of the IRM of the loess samples and are ascribed to maghemite of different oxidation degree. Detrital hematite is present in all samples and contributes up to 10% of the IRM. The iron content of the grain size fractions gives evidence that iron in pedogenically grown remanence carriers does not originate from the detrital iron oxides, but rather from iron-bearing clays and mafic silicates. The contribution of pedogenic magnetite to the bulk IRM increases with the increasing degree of pedogenesis, which depends in turn on climate change.     

Shape and size of the starting Iceland plume swell

Emplacement of a large igneous province is usually accompanied by kilometre-scale uplift over an area of ∼10⁶ km². We have developed a method for mapping the dynamically supported swell associated with the North Atlantic Igneous Province by inverting palaeo-topographic information from continental margins. In the forward model, latest Palaeocene palaeo-topography around Britain and Ireland is calculated by correcting present-day topography for global sea-level change, denudation and dynamic support. We initially assume a Gaussian, axially symmetric dynamic support profile. Modelled coastlines are compared with palaeo-coastlines mapped on 2D and 3D reflection seismic data. In the inverse model, the amplitude, width and centre of the dynamically supported swell are determined by minimising misfit between modelled and observed coastlines. Uncertainties associated with global sea-level variation and denudation have little effect on this calculation. The best-fit dynamic support profile from inverting palaeo-coastline positions is in good agreement with dynamic support estimates from subsidence anomalies measured in extensional sedimentary basins fringing Britain and Ireland. However, a circular planform of dynamic support cannot simultaneously account for palaeo-coastlines, subsidence anomalies and the spatial extent of the North Atlantic Igneous Province. In combination, these data suggest that the swell was more irregular in planform. This inference can be tested in future by modelling stratigraphic data from offshore Norway, Greenland and Canada. The large areal extent and short time interval for inflation of the dynamically supported swell are best explained by rapid convective emplacement of an abnormally hot mantle layer horizontally beneath the lithosphere, during the starting phase of the Icelandic convective system. We emphasise the need to interpret the igneous record jointly with the dynamic support history when discussing models of large igneous province formation and mantle convection.     

Reconstructing the ancestral Yellowstone plume from accreted seamounts and its relationship to flat-slab subduction

Recent geodynamic analyses have emphasized the relationship between modern flat-slab subduction zones and the overriding of buoyant oceanic crust. Although most models for the evolution of the Late Mesozoic–Cenozoic Laramide orogeny in the southwestern United States involve flat-slab subduction, the mechanisms proposed are controversial. An examination of the geological evolution of the 60–50-Ma Crescent terrane of the Coast Ranges indicates that it was formed in a shallowing-upward Loihi-type oceanic setting culminating in the eruption of subaerial lavas. Plate reconstructions indicate that the Crescent terrane was emplaced into ca. 20-Ma crust, and the presence of subaerial lavas implies an uplift due to the plume of ca. 4.2 km, which we use to calculate a minimum buoyancy flux of 1.1 Mg s⁻¹, similar to that of the modern Yellowstone plume.Published paleomagnetic data indicate that the Crescent terrane was formed at a paleolatitude similar to that of the Yellowstone plume. The Crescent seamount was accreted within 5 My of the cessation of plume magmatism. Plate reconstructions indicate that it would have originated about 750 km to the west of the North American plate margin if it developed above a fixed Yellowstone plume, and are therefore consistent with the recorded very short interval between its formation and tectonic emplacement.We interpret the Crescent terrane as due to the ancestral Yellowstone plume. Such a plume would have generated an elongate swell and related plateau that would have been overridden by the North American margin. Taken together, the relationship between flat-slab and overriding of oceanic plateau in Laramide times would have been analogous to the relationship between modern Andean flat-slab subduction zones and the Juan Fernandez and Nazca oceanic plateaus.     

A fundamental Precambrian–Phanerozoic shift in earth's glacial style?

It has recently been found that Neoproterozoic glaciogenic sediments were deposited mainly at low paleolatitudes, in marked qualitative contrast to their Pleistocene counterparts. Several competing models vie for explanation of this unusual paleoclimatic record, most notably the high-obliquity hypothesis and varying degrees of the snowball Earth scenario. The present study quantitatively compiles the global distributions of Miocene–Pleistocene glaciogenic deposits and paleomagnetically derived paleolatitudes for Late Devonian–Permian, Ordovician–Silurian, Neoproterozoic, and Paleoproterozoic glaciogenic rocks. Whereas high depositional latitudes dominate all Phanerozoic ice ages, exclusively low paleolatitudes characterize both of the major Precambrian glacial epochs. Transition between these modes occurred within a 100-My interval, precisely coeval with the Neoproterozoic–Cambrian “explosion” of metazoan diversity. Glaciation is much more common since 750 Ma than in the preceding sedimentary record, an observation that cannot be ascribed merely to preservation. These patterns suggest an overall cooling of Earth's longterm climate, superimposed by developing regulatory feedbacks involving an increasingly complex biosphere.     

Stress field analysis at the El Teniente Mine: evidence for N–S compression in the modern Andes

There is a large database of triaxial stress measurements at the El Teniente Mine, Central Chile, but the complex geology, severe topography, and proximity of all measurements to extensive mining excavations made interpretation of the stress field difficult. The measurements were analyzed using three-dimensional numerical stress analysis and decomposition of the stress field into gravitational and tectonic components. By removing gravitational stresses plus local effects from the tectonic component of the stress field a calculation of the far-field tectonic stress tensor is made. It is shown that variations in the tectonic component of stress are related to shear zones cutting through the mine. The far-field major principal component of the tectonic stress field was found to be oriented approximately N–S. This is consistent with the most recent direction of local shortening based on kinematic analysis of faults, but is perpendicular to the direction of regional crustal shortening. There appears to be a limiting envelope to the magnitude of the stress field implying that the shear zones are in a state of limiting equilibrium with regional tectonic driving forces.     

Regional patterns in the paragenesis and age of inclusions in diamond, diamond composition, and the lithospheric seismic structure of Southern Africa

The Archean lithospheric mantle beneath the Kaapvaal–Zimbabwe craton of Southern Africa shows ±1% variations in seismic P-wave velocity at depths within the diamond stability field (150–250 km) that correlate regionally with differences in the composition of diamonds and their syngenetic inclusions. Seismically slower mantle trends from the mantle below Swaziland to that below southeastern Botswana, roughly following the surface outcrop pattern of the Bushveld-Molopo Farms Complex. Seismically slower mantle also is evident under the southwestern side of the Zimbabwe craton below crust metamorphosed around 2 Ga. Individual eclogitic sulfide inclusions in diamonds from the Kimberley area kimberlites, Koffiefontein, Orapa, and Jwaneng have Re–Os isotopic ages that range from circa 2.9 Ga to the Proterozoic and show little correspondence with these lithospheric variations. However, silicate inclusions in diamonds and their host diamond compositions for the above kimberlites, Finsch, Jagersfontein, Roberts Victor, Premier, Venetia, and Letlhakane do show some regional relationship to the seismic velocity of the lithosphere. Mantle lithosphere with slower P-wave velocity correlates with a greater proportion of eclogitic versus peridotitic silicate inclusions in diamond, a greater incidence of younger Sm–Nd ages of silicate inclusions, a greater proportion of diamonds with lighter C isotopic composition, and a lower percentage of low-N diamonds whereas the converse is true for diamonds from higher velocity mantle. The oldest formation ages of diamonds indicate that the mantle keels which became continental nuclei were created by middle Archean (3.2–3.3 Ga) mantle depletion events with high degrees of melting and early harzburgite formation. The predominance of sulfide inclusions that are eclogitic in the 2.9 Ga age population links late Archean (2.9 Ga) subduction-accretion events involving an oceanic lithosphere component to craton stabilization. These events resulted in a widely distributed younger Archean generation of eclogitic diamonds in the lithospheric mantle. Subsequent Proterozoic tectonic and magmatic events altered the composition of the continental lithosphere and added new lherzolitic and eclogitic diamonds to the already extensive Archean diamond suite.     

Correlation and interpretation of paleosols and loess across European Russia and Asia over the last interglacial-glacial cycle

Loess-paleosol sequences of the last interglacial-glacial cycle are correlated from European Russia to central Siberia and the Chinese Loess Plateau. During cold periods represented by marine oxygen isotope stages (OIS) 2 and 4, loess deposition dominated in the Russian Plain and the Loess Plateau. In central Siberia, loess deposition took place also, but five to seven thin, weakly developed paleosols are identified in both stages. OIS 3, in the Chinese Loess Plateau near Yangchang, consists of a loess bed that is flanked by two weakly developed paleosols. At Kurtak, Siberia, OIS 3 is represented by two distinct, stacked paleosols with no loess bed separating the paleosols. In the Russian Plain, OIS 3 consists of a single, possibly welded paleosol, representing upper and lower stage-3 climates. Brunisols and Chernozems dominate the profiles in China and Siberia, whereas Regosols, Luvisols, and Chernozems are evident in the northern and southern Russian Plain, respectively. OIS 5 is represented in China and the Russian Plain by pedo complexes in a series of welded soils, whereas in contrast, the Kurtak site consists of six paleosols with interbedded loess. The paleosols consist largely of Brunisols and Chernozems. Although the three areas examined have different climates, geographical settings, and loess source areas, they all had similar climate changes during the last interglacial-glacial cycle.