A case study on the correlation of micro-contaminants and potassium in the Leine River (Germany)

River monitoring with focus on the correlation of 41 micro-contaminants with K⁺ and its temporal and spatial variation was carried out in the Leine River (Germany). A positive correlation of concentrations of wastewater-related micro-contaminants and K⁺ is to be expected in receiving waters of wastewater treatment plant (WWTP) effluent since urine is a significant source of K⁺ in WWTP effluent. This correlation was found for compounds, which meet the following criteria: (1) WWTP effluent is the dominating source of the compound, (2) variability of its mass flux in the WWTP is negligible, and (3) the compound is persistent in WWTPs and in the environment. The excellent positive correlation of carbamazepine with K⁺ resulted in the fitting of a universal linear equation to the summer and winter data. For almost all other correlating compounds (1H-benzotriazole, citalopram, diclofenac, metoprolol, sotalol, sulfamethoxazole and tolyltriazole), slopes of the line fittings were steeper in winter (x-axis: K⁺, y-axis: respective micro-contaminant). This has been attributed to a presumed lower degree of degradation and attenuation within WWTPs and in the environment due to low temperatures as well as an increase in consumption of these compounds in the winter months. As part of this research, a sampling event along the entire flow path of the Leine River (∼280 km) was conducted to identify compounds demonstrating stable ratios of various respective micro-contaminants with K⁺. Among other compounds, carbamazepine, sulfamethoxazole, and tolyltriazole demonstrated the best correlations with R² > 0.89. Potassium-equivalents of the individual micro-contaminants depended on land use and population structure of the investigated river section.     

Timing and origin of orogenic remagnetizations in Mississippian carbonates, Sawtooth Range, Montana

Paleomagnetic data and rock magnetic results suggest that a widespread orogenic remagnetization caused a pervasive chemical remanent magnetization (CRM) that resides in magnetite in the Mississippian Madison Group in the Sawtooth Range, Montana, during the Late Cretaceous to Early Tertiary. The CRM is similar to a CRM reported by workers from equivalent units in the southern Canadian Cordillera. The CRM is interpreted to be related to alteration by fluids, and there are two likely fluids: hydrocarbons which migrated into the unit and externally derived radiogenic fluids.     

Velocity Mapping Toolbox (VMT): a processing and visualization suite for moving‐vessel ADCP measurements

The use of acoustic Doppler current profilers (ADCP) for discharge measurements and three‐dimensional flow mapping has increased rapidly in recent years and has been primarily driven by advances in acoustic technology and signal processing. Recent research has developed a variety of methods for processing data obtained from a range of ADCP deployments and this paper builds on this progress by describing new software for processing and visualizing ADCP data collected along transects in rivers or other bodies of water. The new utility, the Velocity Mapping Toolbox (VMT), allows rapid processing (vector rotation, projection, averaging and smoothing), visualization (planform and cross‐section vector and contouring), and analysis of a range of ADCP‐derived datasets. The paper documents the data processing routines in the toolbox and presents a set of diverse examples that demonstrate its capabilities. The toolbox is applicable to the analysis of ADCP data collected in a wide range of aquatic environments and is made available as open‐source code along with this publication. Published 2012. This article is a U.S. Government work and is in the public domain in the USA.     

An Uncertainty Quantification Framework for Studying the Effect of Spatial Heterogeneity in Reservoir Permeability on CO2 Sequestration

A new uncertainty quantification framework is adopted for carbon sequestration to evaluate the effect of spatial heterogeneity of reservoir permeability on CO₂ migration. Sequential Gaussian simulation is used to generate multiple realizations of permeability fields with various spatial statistical attributes. In order to deal with the computational difficulties, the following ideas/approaches are integrated. First, different efficient sampling approaches (probabilistic collocation, quasi-Monte Carlo, and adaptive sampling) are used to reduce the number of forward calculations, explore effectively the parameter space, and quantify the input uncertainty. Second, a scalable numerical simulator, extreme-scale Subsurface Transport Over Multiple Phases, is adopted as the forward modeling simulator for CO₂ migration. The framework has the capability to quantify input uncertainty, generate exploratory samples effectively, perform scalable numerical simulations, visualize output uncertainty, and evaluate input-output relationships. The framework is demonstrated with a given CO₂ injection scenario in heterogeneous sandstone reservoirs. Results show that geostatistical parameters for permeability have different impacts on CO₂ plume radius: the mean parameter has positive effects at the top layers, but affects the bottom layers negatively. The variance generally has a positive effect on the plume radius at all layers, particularly at middle layers, where the transport of CO₂ is highly influenced by the subsurface heterogeneity structure. The anisotropy ratio has weak impacts on the plume radius, but affects the shape of the CO₂ plume.     

Mode of emplacement of the Slaufrudalur Pluton,Southeast Iceland inferred from three-dimensional GPS mapping and model building

The Slaufrudalur Pluton is a granitic pluton in the Tertiary lava pile of Southeast Iceland. Excellent exposures of its roof and walls made it possible to map the shape of the pluton with high-resolution GPS. Based on the GPS mapping and field observations, we reconstructed the three-dimensional shape of the Slaufrudalur Pluton with the aim to test which implications on the mechanisms of emplacement can be derived from this approach. The reconstructed pluton shape is characterised by steep walls and a flat roof at map-scale. This shape and the internal compositional layering indicate that the pluton was probably emplaced by cauldron subsidence along subvertical faults that are parallel with the strike of the regional fissure swarms. At the roof contact, the pluton exploited the original layering of the flood basalts. At outcrop-scale, however, the roof was modified by magmatic stoping, which resulted in a step-like pattern on a scale that cannot be resolved in the three-dimensional model. Hence, the reconstruction of the three-dimensional shape of the Slaufrudalur Pluton, combined with structural field studies, provided valuable information about the mechanism of its emplacement on pluton-scale. For a comprehensive understanding of all mechanisms involved in the emplacement of the Slaufrudalur Pluton, detailed structural field studies remain essential.     

Significance of boulder shape,shoreline configuration and pre-transport setting for the transport of boulders by tsunamis

Research on tsunami-induced coarse-clast transport is a field of rising interest since such deposits have been identified as useful proxies for extreme-wave events (tsunamis, storm waves) that provide crucial information for coastal hazard assessment. Physical experiments are, beside in-situ observations, the foundation of our understanding of how boulders are transported by tsunamis and provide clues to the development of empirical equations and numerical models describing the processes and fundamental mechanics. Nevertheless, investigating tsunami-induced boulder transport is a comparatively young discipline and only a few experimental studies focusing on this topic have been published so far. To improve the knowledge on nearshore tsunami hydrodynamics, physical experiments utilizing real-world boulder shapes have been carried out simulating three different shore types in a wave flume. Crucial insights were gained into boulder transport hydrodynamics and data resulting from the experiments were analysed in an empirical, statistical, quantitative and qualitative manner. The regular cuboid boulder – one of the specific shapes used in the experiments – showed the longest transport distances compared to a complex, natural boulder and a flat cuboid boulder, but also significant fluctuations regarding the total transport distance. The experiments indicate a strong influence of the shore shape on boulder transport behaviour. Experimental setups of increased mean transport distances also led to a higher spreading of results. This spreading was further amplified between the idealized-shaped cuboid and the complex-shaped boulder, which is associated with a lower drag coefficient. Due to the highly sensitive boulder reaction to divergent experimental setups, the need to recognize boundary conditions overcoming commonly considered parameters (e.g. roughness or Flatness Index) in field studies and numerical models is underlined. Beside the strong influence of initial boulder submergence and alignment, both the boulder shape and shore type influence the boulder transport pattern, increasing the total transport distance by more than 350% in some cases. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Bedload hysteresis in a glacier‐fed mountain river

Sediment transport during flood events often reveals hysteretic patterns because flow discharge can peak before (counterclockwise hysteresis) or after (clockwise hysteresis) the peak of bedload. Hysteresis in sediment transport has been used in the literature to infer the degree of sediment availability. Counterclockwise and clockwise hysteresis have been in fact interpreted as limited and unlimited sediment supply conditions, respectively. Hysteresis has been mainly explored for the case of suspended sediment transport, but it was rarely reported for bedload transport in mountain streams. This work focuses on the temporal variability of bedload transport in an alpine catchment (Saldur basin, 18.6 km², Italian Alps) where bedload transport was monitored by means of an acoustic pipe sensor which detects the acoustic vibrations induced by particles hitting a 0.5m‐long steel pipe. Runoff dynamics are dominated by snowmelt in late spring/early summer, mostly by glacier melt in late summer/early autumn, and by a combination of the snow and glacier melt in mid‐summer. The results indicate that hysteretic patterns during daily discharge fluctuations are predominantly clockwise during the snowmelt period, likely due to the ready availability of unpacked sediments within the channel or through bank erosion in the lower part of the basin. On the contrary, counterclockwise hysteresis tend to be more frequent during late glacier melting period, possibly due to the time lag needed for sediment provided by the glacial and peri‐glacial area to be transported to the monitoring section. However, intense rainfall events occurring during the glacier melt period generated predominantly clockwise hysteresis, thus indicating the activation of different sediment sources. These results indicate that runoff generation processes play a crucial role on sediment supply and temporal availability in mountain streams. Copyright © 2014 John Wiley & Sons, Ltd.     

PILOT: a balloon-borne experiment to measure the polarized FIR emission of dust grains in the interstellar medium

Future cosmology space missions will concentrate on measuring the polarization of the Cosmic Microwave Background, which potentially carries invaluable information about the earliest phases of the evolution of our universe. Such ambitious projects will ultimately be limited by the sensitivity of the instrument and by the accuracy at which polarized foreground emission from our own Galaxy can be subtracted out. We present the PILOT balloon project, which aims at characterizing one of these foreground sources, the polarized continuum emission by dust in the diffuse interstellar medium. The PILOT experiment also constitutes a test-bed for using multiplexed bolometer arrays for polarization measurements. This paper presents the instrument and its expected performances. Performance measured during ground calibrations of the instrument and in flight will be described in a forthcoming paper.     

Biogeochemistry and carbon mass balance of a coccolithophore bloom in the northern Bay of Biscay (June 2006)

Primary production (PP), calcification (CAL), bacterial production (BP) and dark community respiration (DCR) were measured along with a set of various biogeochemical variables, in early June 2006, at several stations at the shelf break of the northern Bay of Biscay. The cruise was carried out after the main spring diatom bloom that, based on the analysis of a time-series of remotely sensed chlorophyll-a (Chl-a), peaked in mid-April. Remotely sensed sea surface temperature (SST) indicated the occurrence of enhanced vertical mixing (due to internal tides) at the continental slope, while adjacent waters on the continental shelf were stratified, as confirmed by vertical profiles of temperature acquired during the cruise. The surface layer of the stratified water masses (on the continental shelf) was depleted of inorganic nutrients. Dissolved silicate (DSi) levels probably did not allow significant diatom development. We hypothesize that mixing at the continental slope allowed the injection of inorganic nutrients that triggered the blooming of mixed phytoplanktonic communities dominated by coccolithophores (Emiliania huxleyi) that were favoured with regards to diatoms due to the low DSi levels. Based on this conceptual frame, we used an indicator of vertical stratification to classify the different sampled stations, and to reconstruct the possible evolution of the bloom from the onset at the continental slope (triggered by vertical mixing) through its development as the water mass was advected on-shelf and stratified. We also established a carbon mass balance at each station by integrating in the photic layer PP, CAL and DCR. This allowed computation at each station of the contribution of PP, CAL and DCR to CO₂ fluxes in the photic layer, and how they changed from one station to another along the sequence of bloom development (as traced by the stratification indicator). This also showed a shift from net autotrophy to net heterotrophy as the water mass aged (stratified), and suggested the importance of extracellular production of carbon to sustain the bacterial demand in the photic and aphotic layers.     

Simulated diagenesis and catagenesis of marine kerogen precursors: Melanoidins as model systems for light hydrocarbon generation

Amino acids and sugars are principal constituents of marine organisms. The condensation of amino acids and sugars is one possible nonenzymatic, early diagenetic pathway for the incorporation of these compounds into more complex geopolymers. In this study, aqueous solutions consisting of l-lysine, l-histidine, l-arginine and d-(+)-glucose were heated (100°C) for up to 288 h. Portions of the melanoidin polymer isolated after heating were reheated in the presence of water (hydrous pyrolysis) for 72 h at 325°C. Reaction products were identified by GC and GC/MS. Stable isotopic (δ¹³C) and elemental analyses were used to follow thermal evolution.While the initial melanoidin was synthesized from a simple, four component system, the products generated during hydrous pyrolysis are of considerable complexity, and include straightchain and branched alkanes, alkadienes, alkynes, indole, dimethyl indane, ethyl phenol, quinoline, and xylenes, in addition to a multitude of as yet, unidentified components. Stable carbon isotopic values for the reactants and products correspond to trends observed for naturally generated geopolymers and light gases. Elemental analyses of the melanoidin prior and subsequent to hydrous pyrolysis indicate a kerogen evolution pathway similar to that observed for natural samples. Considering the intractable nature of kerogen, laboratory simulation studies of simple systems can provide an alternative approach for elucidating the origins of geopolymers and their potential for hydrocarbon generation.