Exploring the long-term and interannual variability of biogeochemical variables in coastal areas by means of a data assimilation approach

Dynamic Harmonic Regression (DHR) models are applied here to the investigation of the interannual changes in the trend and seasonality of biogeochemical variables monitored in coastal areas. A DHR model can be regarded as a time-series component model, where the phases and amplitudes of the seasonal component, as well as the trend, are parameters that vary with time, reflecting relevant changes in the evolution of the biogeochemical variables. The model parameters and their confidence bounds are estimated by data assimilation algorithms, i.e. the Kalman filter and the Fixed Interval smoother. The DHR model structure is here identified by a preliminary spectral analysis and a subsequent minimization of the Bayesian Information Criterion, thus avoiding subjective choices of the frequencies in the seasonal component. The methodology was applied to the investigation of the long-term and interannual variability of ammonia, nitrate, orthophosphate and chlorophyll-a monitored monthly in the lagoon of Venice (Italy) during the years 1986–2008. It was found that the long-term evolutions of the biogeochemical variables were characterized by non-linear patterns and by statistically significant changes in the trend. The seasonal cycles of all the variables were characterized by a marked interannual variability. In particular, the changes in the seasonality of chlorophyll and nitrate were significantly related to the changes in the seasonality of water temperature at the study site and of nutrient concentrations in river discharges, respectively. These results indicate that the methodology could be a sound alternative to more traditional approaches for investigating the impacts of changes in environmental and anthropogenic forcings on the evolution of biogeochemical variables in coastal areas.     

Determination of the relative thermal conductivity of solid samples by X-ray diffraction device

The thermal conductivity (TC) of metal and rock samples was determined, under ambient conditions, using standard X-ray diffraction equipment in which only the diffractometer sample holder had been modified from the original. As the method is comparative, standard reference materials were used: a copper standard for the analysis of metals and marble for the rock specimens. The marble was analyzed beforehand using a quick thermal conductivity meter QTM. In experimental measurements of TC the mean reproducibility value appears to be about 4% while the accuracy is about 5% for the examined rocks, and better for metals.     

Dissociation Constants of Protonated Oxidized Glutathione in Seawater Media at Different Salinities

Oxidized glutathione (GSSG), which has four carboxylic and two amino groups, interacts with metal ions and may affect the bioavailability and geochemistry of metals in natural waters. In the present paper, six stepwise protonation constants K^\textH_i K^{\text{H}}_{i} for GSSG were measured as a function of salinity, S = 5–35‰ at t = 25°C (and in NaCl/MgCl₂ mixtures at different ionic strengths), in order to provide thermodynamic data for their acid base properties, which are useful for studying the interaction with metals in these media. The protonation enthalpies (ΔH _i /kJ mol⁻¹) were also determined at t = 25°C. The results were interpreted using the SIT model and Pitzer equations. The seawater model with the interaction parameters accounts for the differences between the values in NaCl and seawater. The results suggest that it is important to consider all of the ionic interactions in natural waters in examining the proton dissociation of GSSG.     

Hydrogeochemistry of Roccamonfina volcano (Southern Italy)

This is the first hydro-geochemical investigation carried out on the Roccamonfina Volcanic Complex groundwaters. The chemistry of Roccamonfina waters is defined by water–rock and water–rock–gas interactions. In fact, interactions between rocks of the first eruptive high-K formations and circulating groundwaters are recognized by high K concentrations. On the other hand, inverse concentration of calcium versus alkali metals is related to two different rock interactions occurring in different areas of the volcano: (a) within the caldera where groundwaters flow within latite and pyroclastic formations releasing calcium, and (b) similarly at the base of the volcano where groundwaters flowing from surrounding carbonates got strongly enriched in Ca. These geochemical processes are also associated with K (SE of caldera) and Mg/Ca (in sites located at the NE base of the volcano) decrease. Completely different dynamics occurs at Riardo groundwaters (SE). Here waters are the result of a mix between the Roccamonfina deep aquifer and the carbonate aquifer of the Riardo plain. Rich-CO₂ emissions make these waters strongly mineralized. Minor elements show a similar geochemical behavior of major ions and are crucial defining interactions processes. The evolution of Roccamonfina groundwaters is also evident along the simultaneous enrichment of Ba, Sr, and Ca. Ba increase is the result of deep local carbonate alteration enhanced by CO₂ emissions and, the lower Sr/Ca ratio, from 10 to 2 (ppb/ppm), is also due to the same process. In the light of our results the Roccamonfina aquifer can be schematically divided into two main reservoirs: (a) a superficial aquifer which basically follows the volcanic structure morphology and tectonics and (b) a deeper reservoir, originating within the oldest Roccamonfina volcano ultra potassic lavas and then flowing into the carbonate aquifers of the neighboring plain. Eventually, the chemistry of the Roccamonfina aquifer does not show any specific and visible pollution, contrary to what happens in the volcano surrounding plains. In fact, only 14% of the samples we collected (206) show a NO₃ content >30 mg/l. These sites are all located at the base of the volcano, near the plain.     

Estimating flow resistance in steep slope rills

Recent research recognized that the slope of 18% can be used to distinguish between the ‘gentle slope’ case and that of ‘steep slope’ for the detected differences in hydraulic variables (flow depth, velocity, Reynolds number, Froude number) and those representatives of sediment transport (flow transport capacity, actual sediment load). In this paper, using previous measurements carried out in mobile bed rills and flume experiments characterized by steep slopes (i.e., slope greater than or equal to 18%), a theoretical rill flow resistance equation to estimate the Darcy-Weisbach friction factor is tested. The main aim is to deduce a relationship between the velocity profile parameter Γ, the channel slope, the Reynolds number, the Froude number and the textural classes using a data base characterized by a wide range of hydraulic conditions, plot or flume slope (18%–84%) and textural classes (clay ranging from 3% to 71%). The obtained relationship is also tested using 47 experimental runs carried out in the present investigation with mobile bed rills incised in a 18%—sloping plot with a clay loam soil and literature data. The analysis demonstrated that: (1) the soil texture affects the estimate of the Γ parameter and the theoretical flow resistance law (Equation 25), (2) the proposed Equation (25) fits well the independent measurements of the testing data base, (3) the estimate of the Darcy-Weisbach friction factor is affected by the soil particle detachability and transportability and (4) the Darcy-Weisbach friction factor is linearly related to the rill slope.     

Assessment of the impact of climate change on the olive flowering in Calabria (southern Italy)

In phenological studies, plant development and its relationship with meteorological conditions are considered in order to investigate the influence of climatic changes on the characteristics of many crop species. In this work, the impact of climate change on the flowering of the olive tree (Olea europaea L.) in Calabria, southern Italy, has been studied. Olive is one of the most important plant species in the Mediterranean area and, at the same time, Calabria is one of the most representative regions of this area, both geographically and climatically. The work is divided into two main research activities. First, the behaviour of olive tree in Calabria and the influence of temperature on phenological phases of this crop are investigated. An aerobiological method is used to determine the olive flowering dates through the analysis of pollen data collected in three experimental fields for an 11-year study period (1999–2009). Second, the study of climate change in Calabria at high spatial and temporal resolution is performed. A dynamical downscaling procedure is applied for the regionalization of large-scale climate analysis derived from general circulation models for two representative climatic periods (1981–2000 and 2081–2100); the A2 IPCC scenario is used for future climate projections. The final part of this work is the integration of the results of the two research activities to predict the olive flowering variation for the future climatic conditions. In agreement with our previous works, we found a significant correlation between the phenological phases and temperature. For the twenty-first century, an advance of pollen season in Calabria of about 9?days, on average, is expected for each degree of temperature rise. From phenological model results, on the basis of future climate predictions over Calabria, an anticipation of maximum olive flowering between 10 and 34?days is expected, depending on the area. The results of this work are useful for adaptation and mitigation strategies, and for making concrete assessments about biological and environmental changes.     

Precision spacecraft navigation using a low-cost GPS receiver

Within the PROBA-2 microsatellite mission, a miniaturized single-frequency GPS receiver based on commercial-off-the-shelf (COTS) technology is employed for onboard navigation and timing. A rapid electronic fuse protects against destructive single-event latch-ups (SEL) and enables a quasi-continuous receiver operation despite the inherent sensitivity to space radiation. While limited to single-frequency C/A-code tracking with a narrow-band frontend, the receiver is able to provide precision navigation services through processing of raw GPS measurements on ground as well as a built-in real-time navigation system. In both cases, ionospheric path delays are eliminated through a combination of L1 pseudorange and carrier phase measurements, which also offers a factor-of-two noise reduction relative to code-only processing. By comparison with satellite laser ranging (SLR) measurements, a 0.3-m (3D rms) accuracy is demonstrated for the PROBA-2 reduced dynamic orbit determinations using post-processed GPS orbit and clock products. Furthermore, the experimental onboard navigation system is shown to provide real-time position information with a 3D rms accuracy of about 1?m, which notably outperforms the specification of the Standard Positioning Service (SPS). In view of their lower hardware complexity, mass budget and power requirements as well as the reduced interference susceptibility, legacy C/A-code receivers can thus provide an attractive alternative to dual-frequency receivers even for demanding navigation applications in low Earth orbit.     

具平缓电子能谱的伽玛射线暴的解析光变曲线

在标准的伽玛暴余辉模型中,电子通过费米一级加速后形成单幂律能谱分布dn/dγe∝γe-p(p≈2.3),但在某些伽玛暴事件中观测到了平缓的电子能谱分布(即p＜2).在单幂律谱和分段幂律谱两种情况下,分别给出了具有平缓电子能谱的伽玛暴余辉的解析光变曲线,并以GRB 060908为例进行了讨论.同时提出了伽玛暴低能谱危机的...     

Turbulent Dispersion of Non-uniformly Emitted Passive Tracers in the Convective Boundary Layer

The impact of spatially non-uniform emissions on the turbulence dispersion of passive tracers in the convective boundary layer is studied by means of large-eddy simulation. We explicitly calculated the different terms of the budget equations for the concentrations, fluxes and variances, and used sub-domain averaging where each sub-domain is the typical size of a large-scale model grid cell. We found that the concentration profiles in the sub-domain where the emission takes place are lightly affected by the size of the emission release. This effect becomes more relevant in the downwind sub-domain. Although sub-domain averaged fluxes are not affected by the emission source size, concentration variances are dramatically increased when the emission shrinks. This increase originates from the mixing of highly concentrated air parcels with those of low concentrations. We also found that the concentration variance at the surface is driven neither by the position of the emission source nor the strength of the shear forcing but solely by the emission variance.