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691.
José?F.?MolinaEmail author Stefano?Poli H?kon?Austrheim Johannes?Glodny Anatolij?Rusin 《Contributions to Mineralogy and Petrology》2004,147(4):484-504
Metasomatic amphibole-eclogite sequences grew in selvages of quartz veins from the Marun-Keu complex (Polar Urals, Russia) during high-pressure metamorphism. Relicts of a pre-metasomatic eclogite-facies assemblage are present in the wallrock layers as irregular patches. Wallrock interstitial quartz trails lying at a high angle to reaction fronts provide evidence for grain-scale pore channelisation which may be produced by intergranular-fluid compositional gradients parallel to the quartz trails. Disequilibrium at vein-wallrock scale is inferred from wallrock mineral heterogeneity and from variable initial Sr isotope ratios in mineral separates. Mass-balance calculations between relicts and wallrock assemblages reveal chemical imbalances caused by open system-behaviour with two way mass-transfer. The vein-wallrock system registers a prograde history from 408–434 °C (relicts) to 526–668 °C (vein precipitates). Vein and metasomatic assemblages formed during a single fluid-rock interaction process, implying high heating rates (100 °C/Ma), which could result from heat advection by large-scale fluid circulation.Editorial responsibility: W. Schreyer 相似文献
692.
Andrea De Stefano Nathalie Lefebvre Maya Kopylova 《Contributions to Mineralogy and Petrology》2006,151(2):158-173
A suite of 80 macrodiamonds recovered from volcaniclastic breccia of Wawa (southern Ontario) was characterized on the basis
of morphology, nitrogen content and aggregation, cathodoluminescence (CL), and mineral inclusions. The host calc-alkaline
lamprophyric breccias were emplaced at 2.68–2.74 Ga, contemporaneously with voluminous bimodal volcanism of the Michipicoten
greenstone belt. The studied suite of diamonds differs from the vast majority of diamond suites found worldwide. First, the
suite is hosted by calc-alkaline lamprophyric volcanics rather than by kimberlite or lamproite. Second, the host volcanic
rock is amongst the oldest known diamondiferous rocks on Earth, and has experienced regional metamorphism and deformation.
Finally, most diamonds show yellow-orange-red CL and contain mineral inclusions not in equilibrium with each other or their
host diamond. The majority of the diamonds in the Wawa suite are colorless, weakly resorbed, octahedral single crystals and
aggregates. The diamonds contain 0–740 ppm N and show two modes of N aggregation at 0–30 and 60–95% B-centers suggesting mantle
storage at 1,100–1,170°C. Cathodoluminescence and FTIR spectroscopy shows that emission peaks present in orange CL stones
do not likely result from irradiation or single substitutional N, in contrast to other diamonds with red CL. The diamonds
contain primary inclusions of olivine (Fo92 and Fo89), omphacite, orthopyroxene (En93), pentlandite, albite, and An-rich plagioclase. These peridotitic and eclogitic minerals are commonly found within single
diamonds in a mixed paragenesis which also combines shallow and deep phases. This apparent disequilibrium can be explained
by effective small-scale mixing of subducted oceanic crust and mantle rocks in fast “cold” plumes ascending from the top of
the slabs in convergent margins. Alternatively, the diamonds could have formed in the pre-2.7–2.9 Ga cratonic mantle and experienced
subsequent alteration of syngenetic inclusions related to host magmatism and ensuing metamorphism. Neither orogenic nor cratonic
model of the diamond origin fully explains all of the observed characteristics of the diamonds and their host rocks.
Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users. 相似文献