Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

平均经圈环流在大气角动量和感热收支中的作用

本文研究相对座标系中近地表角动量的制造和自由大气中角动量的辐散之间的平衡机制,并与绝对参考系中的机制进行比较。 对1982年元月全球角动量和感热的收支分析证明,被激发的平均经圈环流具有下述特征:其下部水平支施加于大气的惯性矩与近地表角动量的制造相平衡,上部水平支反号的惯性矩与涡动角动量通量的辐合(散)相平衡;而其垂直支的绝热加热效应则平衡着自由大气中热通量的辐散和/或大气的非绝热加热。因而,无论动力上还是热力上,平均经圈环流在大气总环流中都起着重要的作用。     

All-sky Data Assimilation of MWTS-2 and MWHS-2 in the Met Office Global NWP System.

Microwave radiances from passive polar-orbiting radiometers have been, until recently, assimilated in the Met Office global numerical weather prediction system after the scenes significantly affected by atmospheric scattering are discarded.Recent system upgrades have seen the introduction of a scattering-permitting observation operator and the development of a variable observation error using both liquid and ice water paths as proxies of scattering-induced bias. Applied to the Fengyun 3 Microwave Temperature Sounder 2(MWTS-2) and the Microwave Humidity Sounder 2(MWHS-2), this methodology increases the data usage by up to 8% at 183 GHz. It also allows for the investigation into the assimilation of MWHS-2 118 GHz channels, sensitive to temperature and lower tropospheric humidity, but whose large sensitivity to ice cloud have prevented their use thus far. While the impact on the forecast is mostly neutral with small but significant shortrange improvements, 0.3% in terms of root mean square error, for southern winds and low-level temperature, balanced by 0.2% degradations of short-range northern and tropical low-level temperature, benefits are observed in the background fit of independent instruments used in the system. The lower tropospheric temperature sounding Infrared Atmospheric Sounding Interferometer(IASI) channels see a reduction of the standard deviation in the background departure of up to 1.2%. The Advanced Microwave Sounding Unit A(AMSU-A) stratospheric sounding channels improve by up to 0.5% and the Microwave Humidity Sounder(MHS) humidity sounding channels improve by up to 0.4%.     

Active thrust tectonics in western Sicily (southern Italy): the 1968 Belice earthquake sequence

The 1968 Belice earthquake sequence, characterized by six main shocks with 5 < M < 5.4, represents the strongest seismic event recorded in western Sicily in historical times. The epicentral area is located in the Belice Valley, a region lacking any topographic lineament likely to result from a fault with significant offsets of any kind. Instrumental data show that hypocentres of the major shocks are distributed along a roughly N-dipping plane extending from about 36 km to 1 km depth. Fault plane solutions show pure thrusting mechanisms on N-dipping, ENE-trending planes, or oblique slip with a right-lateral component of motion along steep WSW-dipping planes, both as a result of approximate N-S shortening. The observed destruction indicates that isoseismal areas are elongated in an ENE direction. Similarly, the epiccntral distribution of events with M ≥ 4 outlines a roughly elliptical ENE-elongated area located 20 km NW of the Sciacca-Rocca Ficuzza thrust front. This ENE-striking structure, representing the regional morphotectonic feature closest to the epicentral area, consists of two main imbricate fan systems. In the southernmost system, Quaternary deposits (tentatively dated as 1.0–0.7 Myr old) are involved in a large ramp anticline uplifting them to a maximum altitude of 346 m. The occurrence of Holocene lacustrine piggy-back basins on the rear of this structure also indicates late Quaternary activity of the underlying thrust. Seismological, structural and morphotectonic observations suggest that multiple ruptures might have occurred during the 1968 sequence on a blind crustal thrust ramp located beneath the epicentral area. Slip propagated southwards along the shallow ramp-flat system characterizing the thin-skinned foreland fold and thrust belt of southwestern Sicily, being dispersed in flexural folding processes and diffuse strain along this path.     

A record of the Messinian salinity crisis in the eastern Ionian tectonically active domain (Greece,eastern Mediterranean)

This integrated study (field observations, micropalaeontology, magnetostratigraphy, geochemistry, borehole data and seismic profiles) of the Messinian–Zanclean deposits on Zakynthos Island (Ionian Sea) focuses on the sedimentary succession recording the pre‐evaporitic phase of the Messinian salinity crisis (MSC) through the re‐establishment of the marine conditions in a transitional area between the eastern and the western Mediterranean. Two intervals are distinguished through the palaeoenvironmental reconstruction of the pre‐evaporitic Messinian in Kalamaki: (a) 6.45–6.122 Ma and (b) 6.122–5.97 Ma. Both the planktonic foraminifer and the fish assemblages indicate a cooling phase punctuated by hypersalinity episodes at around 6.05 Ma. Two evaporite units are recognized and associated with the tectonic evolution of the Kalamaki–Argassi area. The Primary Lower Gypsum (PLG) unit was deposited during the first MSC stage (5.971–5.60 Ma) in late‐Messinian marginal basins within the pre‐Apulian foreland basin and in the wedge‐top (<300 m) developed over the Ionian zone. During the second MSC stage (5.60–5.55 Ma), the PLG evaporites were deeply eroded in the forebulge–backbulge and the wedge‐top areas, and supplied the foreland basin's depocentre with gypsum turbidites assigned to the Resedimented Lower Gypsum (RLG) unit. In this study, we propose a simple model for the Neogene–Pliocene continental foreland‐directed migration of the Hellenide thrusting, which explains the palaeogeography of the Zakynthos basin. The diapiric movements of the Ionian Triassic evaporites regulated the configuration and the overall subsidence of the foreland basin and, therefore, the MSC expression in this area.     

Modeling the influence of hydroperiod and vegetation on the cross-sectional formation of tidal channels

The evolution of the cross section of a salt-marsh channel is explored using a numerical model. Deposition on the marsh platform and erosion and deposition in the channel affect the tidal prism flowing through the cross section, such that the model captures the evolution of the stage–discharge relationship as the channel and marsh platform evolve. The model also captures the growth of salt-marsh vegetation on the marsh platform, and how this vegetation affects flow resistance and the rate of sedimentation. The model is utilized to study the influence of hydroperiod and vegetation encroachment on channel cross section. Numerical results show that a reduction in hydroperiod due to the emergence of the marsh platform causes an infilling of the channel. Vegetation encroachment on the marsh surface produces an increase in flow resistance and accretion due to organic and mineral sedimentation, with important consequences for the shape of the channel cross section. Finally, modeling results indicate that in microtidal marshes with vegetation dominated by Spartina alterniflora, the width-to-depth ratio of the channels decreases when the tidal flats evolve in salt marshes, whereas the cross-sectional area remains proportional to the tidal peak discharge throughout channel evolution.     

Early diagenesis in rapidly accumulating sediments on the Alboran slope, ODP site 976

 The oxidation and reduction that occur during early diagenesis of sediments has been studied in the interstitial waters of a rapidly accumulating sedimentary sequence from the Mediterranean margin of Spain. A series of reactions that are mediated by progressively lower free energy derived from oxidation of organic matter is evident in the sedimentary sequence. Iron and manganese are rapidly reduced. Phosphate and alkalinity maxima at a subbottom depth of 15 m indicate maximal organic matter degradation. Methane first appears at ∼20 m subbottom after sulfate is depleted, and its concentrations quickly climb. Received: 27 October 1997 / Revision received: 4 March 1998     

A comment on “Calcic amphibole equilibria and a new amphibole — plagioclase geothermometer” by J.D. Blundy and T.J.B. Holland (Contrib Mineral Petrol (1990) 104: 208–224)

Conclusions The calibration by Blundy and Holland is not a calibration of the reaction albite + tremolite = edenite + 4quartz, because the Al^IV content of amphiboles is a combined result of substitutions.The requirements for a calibration of any of these substitutions are: (1) an amphibole-activity model unequivocally accounting for each substitution and (2) a data-set, wherein all amphiboles are buffered by the same assemblages.