Evaluation of ecotoxicological effects of endocrine disrupters during a four-year survey of the Mediterranean population of swordfish (Xiphias gladius)

In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1–22, Cd 1–28 and Pb 0–1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.     

Relationship between the optical properties of chromophoric dissolved organic matter and total concentration of dissolved organic carbon in the southern Baltic Sea region

Absorption and fluorescence of chromophoric dissolved organic matter (CDOM) and dissolved organic carbon (DOC) measurements were performed during three oceanographic surveys in 1994 in the southern Baltic Sea (Polish area of the Baltic Proper). DOC was measured both by high-temperature catalytic oxidation (HTCO) and low-temperature oxidation (LTO) conventional persulphate methods. CDOM fluorescence was shown to be highly correlated with absorption, with the same regression parameters, despite the seasonal change in different hydrographic conditions and the fluorescence quantum yield variations (1.23 ± 0.07 in April and 0.97 ± 0.12 in September). The results show a good correlation between the optical parameters and DOC although ˜ 70% of the DOC does not display significant absorption in the UV-visible range (350–750 nm). The non-absorbing DOC measured with HTCO method appears unaffected by seasonal changes. Consequently, total DOC can be predicted by optical methods using remote sensing techniques. The non-absorbing DOC measured by LTO method varies from 62% (April) to 76% (September), which implies that there is requirement for estimates on a seasonal basis.     

Trajectory analysis at intersections for traffic rule identification

In this paper,we focus on trajectories at intersections regulated by various regulation types such as traffic lights,priority/yield signs,and right-of-way rules.We test some methods to detect and recognize movement patterns from GPS trajectories,in terms of their geometrical and spatio-temporal components.In particular,we first find out the main paths that vehicles follow at such locations.We then investigate the way that vehicles follow these geometric paths(how do they move along them).For these scopes,machine learning methods are used and the performance of some known methods for trajectory similarity measurement(DTW,Hausdorff,and Fréchet distance)and clustering(Affinity propagation and Agglomerative clustering)are compared based on clustering accuracy.Afterward,the movement behavior observed at six different intersections is analyzed by identifying certain movement patterns in the speed-and time-profiles of trajectories.We show that depending on the regulation type,different movement patterns are observed at intersections.This finding can be useful for intersection categorization according to traffic regulations.The practicality of automatically identifying traffic rules from GPS tracks is the enrichment of modern maps with additional navigation-related information(traffic signs,traffic lights,etc.).     

The Analysis of the Seasonal,Spatial, and Compositional Distribution of Humic Substances in a Subtropical Shallow Lake

The spatial and temporal distribution of humic substances in aquatic ecosystems can have important effects on ecosystem productivity, negatively impacting primary productivity while positively impacting secondary productivity. In the present investigation, a large shallow lake ecosystem was studied to determine the spatial and seasonal variation of the composition and concentration of humic substances. Concentrations of total dissolved organic matter, humic acid, and fulvic acid were found to display significant spatial distributions (1.3…13.5 mg/L, DOM; 0.1…5.4 mg/L, HA). The distribution is described by using mapping techniques and the analysis of the spatial distribution of the lake. An analysis of the seasonal variations also indicated the dependence of the occurrence of these compounds on meteorological and hydrological conditions. To identify the potential sources of these organic materials, an analysis was made of the ratio of humic and fulvic acid fractions and total DOM. It was found that areas of high DOM concentration coincided with the areas of highest HA percentage of total DOM. Furthermore using the ratio of the normalised concentrations of HA, FA, and residual DOM (< 5000 g/mol) it was found that areas dominated by each are spatially distinct. This confirms the hypothesis that in these shallow lakes, photodegradation and bacterioplankton activity will create a residence time dependent zonation of each component of the total DOM.     

Perfluorinated compounds in blood of Caretta caretta from the Mediterranean Sea

Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.     

Combining a rainfall–runoff model and a regionalization approach for flood and water resource assessment in the western Po Valley,Italy

ABSTRACT

Selecting the best structure and parameterization of rainfall–runoff models is not straightforward and depends on a broad number of factors. In this study, the “Modello Idrologico Semi-Distribuito in continuo” (MISDc) was tested on 63 mountainous catchments in the western Po Valley (Italy) and the optimal model parameters were regionalized using different strategies. The model performance was evaluated through several indexes analysing hydrological regime, high-flow condition and flow–duration curve (FDC). In general, MISDc provides a good fit behaviour with a Kling-Gupta Efficiency index greater than 0.5 for 100% and 84% of cases for calibration and validation, respectively. Concerning the regionalization, spatial proximity approach is the most accurate solution obtaining satisfactory performance. Lastly, the predicted FDCs showed an excellent similarity with the observed ones. Results encourage to apply MISDc over the study area for flood forecasting and for assessing water resources availability thanks to the modest computational efforts and data requirements.     

Transient kinematic pile bending in two-layer soil

The dynamic response of piles to seismic loading is explored by means of an extensive parametric study based on a properly calibrated Beam-on-Dynamic-Winkler-Foundation (BDWF) model. The investigated problem consists of a single vertical cylindrical pile, modelled as an Euler–Bernoulli beam, embedded in a subsoil consisting of two homogeneous viscoelastic layers of sharply different stiffness resting on a rigid stratum. The system is subjected to vertically propagating seismic S waves, in the form of a transient motion imposed on rock outcrop. Several accelerograms recorded in Italy are employed as input motions in the numerical analyses. The paper highlights the severity of kinematic pile bending in the vicinity of the interface separating the two soil layers. In addition to factors already investigated such as layer stiffness contrast, relative soil–pile stiffness, interface depth and intensity of ground excitation, the paper focuses on additional important factors, notably soil material damping, stiffness of Winkler springs and frequency content of earthquake excitation. Existing predictive equations for assessing kinematic pile bending at soil layer interfaces are revisited and new regression analyses are performed. A synthesis of findings in terms of a set of simple equations is provided. The use of these equations is discussed through examples.     

Reactive Transport Modeling of ZVI Column Experiments for Nickel Remediation

MIN3P, a multicomponent reactive transport model for variably saturated porous media, is used to simulate the outputs of column tests carried out using zero valent iron (ZVI) for nickel contaminated groundwater remediation. The objective of this study is to investigate the main chemical reactions involved in contaminant removal and the main causes of the reactivity decline of ZVI over time. According to the results of the model the major causes of ZVI reactivity loss is identified in the mineral precipitation of α‐FeOOH on iron surface that probably caused ZVI passivation and led to a decline of the electron transfer rate. An existing empirical relationship between mineral precipitation and the reactivity loss of ZVI, included in the model, reproduced the changes in nickel removal observed during different laboratory column tests.     

Dioxin Like Compounds Bulk Deposition on Corn (Zea mais) and Alfa Alfa (Medicago sativa): Modelled Levels on Derived Silage and Hay and Their Relevance for Dairy Production

Dioxin‐like compounds from regular, occasional or fugitive airborne sources of emission may fall out on fodders close to be harvested for silage and hay production. In this way, a prolonged long‐term intake of contaminated forages in dairy animals may be envisaged, able to determine a rise of the background contamination in milk. We simulated different risk scenarios taking into account the inventoried bulk dry depositions in rural areas of the aforesaid contaminants, silage and hay biomass production per hectare, forages regimen in dairy animals, and the congeners carry‐over rate (COR) from forages to milk. Considering atmospheric depositions >10 pg I‐TE m^?2 day^?1 and accounting for a 30% COR, dairy milk could rise up to the PCDD/F level of 3 pg WHO₁₉₉₈‐TE g^?1 fat. The modelling indicates that in rural areas bulk emissions should be selectively minimised, accounting for the calendar of the different agricultural practices, because of their potential impact on the fodders. Since environmental factors play a non‐negligible role in food production, a stronger harmonisation between I‐TE and WHO_1998–2005‐TE scales with respect to dioxin‐like polychlorobiphenyl congeners inclusion is envisaged. This will allow the prevention of the human indirect exposure to such contaminants when released in the air.