Possible effects of climate change on estuarine nutrient fluxes: a case study in the highly nutrified Schelde estuary (Belgium, The Netherlands)

Global change models predict effects of climate change on hydrological regimes at the continental scale in Europe. The aim of this study was to gain a better understanding of the possible effect of changing external forcing conditions on the functioning of estuarine ecosystems. In densely populated areas, anthropogenic nutrient enrichment and consequent alteration of nutrient biogeochemical cycles have already had a big impact on these ecosystems. The average yearly discharge of the upper Schelde estuary increased nearly threefold over the period 1996–2000, from 28 m³ s⁻¹ in 1996 to 73 m³ s⁻¹ in 2000. The continuously rising discharge conditions over the five-year period were used as a reference situation for possible future effects of climate on ecological functioning through increase of discharge. At high discharges, nutrient (NH₄⁺, NO₃⁻, dissolved silica and PO₄³⁻) concentrations in the tidal fresh- and brackish water showed a decrease of up to 50% while total discharged nutrient loadings increased up to 100%. Opposite effects of increasing discharge on NH₄⁺, NO₃⁻ and dissolved silica concentrations in summer and winter, resulted in the flattening out of seasonal cycles for these nutrients. Under high discharge conditions, silica uptake by diatom communities was lowered. Dissolved silica loadings to the coastal area increased concurrently with total silica loadings upstream. Salt intrusion to the marine parts of the estuary decreased. This resulted in a downstream shift of the salinity gradient, with lower salinity observed near the mouth. As a result, TDIN, NO₃⁻ and dissolved silica concentrations doubled at the mouth of the estuary.     

Ein Vorkommen von Lorandit (T1AsS 2) in der Schweiz

A new find of the thallium-arsenic-sulphosalt mineral lorandite in the Triassic dolomite of the famous Lengenbach quarry in Binnatal, Ct. Wallis (Switzerland) is described. Herewith the Lengenbach is, up to now, only the third locality, where lorandite has been found at all. The d-values for X-ray powder pattern, morphological data, and a microprobe analysis are given. Reflection percentage (for green light of 5300 Å) is 32.6%, Vickers hardness number (with load of 30 g) is 38.9. Relations to the different thallium-sulphosalts of the Lengenbach are discussed.

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Zum Schluß möchte ich noch meinem Freunde Herrn Dr. H. A. Stalder, Konservator an der Mineralogischen Abteilung des Naturhistorischen Museums Bern, herzlich danken für die Überlassung einer Vergleichsprobe von Lorandit aus Allchar.     

On lipid surface films on the sea. I. A simple method for sampling and studies of composition

A method for collection of surface films on the sea has been developed and tested at various places along the Swedish West Coast. Considerable amounts of lipids on the sea surface were found even when no seaslicks were observed. Triglycerides, free fatty acids, and wax esters are the dominating constituents, and there are characteristic deviations in the fatty-acid patterns compared to the corresponding lipids dissolved in the sub-surface water. Organochlorine residues, phthalic acid esters and heavy metals also occur in considerable amounts.     

Spatial and Temporal Distribution of Oxidation Events Occurring Below the Sediment-Water Interface

Abstract. Irrigation and bioturbation lead to transport of dissolved oxygen into anoxic sediments. The depthdistribution of local oxygen input and the total time of oxygen presence was measured at randomly sampled locations within anoxic sediments, originating from the North Sea.
In the laboratory, continuous redox potential records, displaying a transient increase and decrease when in contact with oxygen for a limited time, were used to record oxidation events'. Oxygen microelectrodes were used to confm the presence of oxygen. Measurements were performed for 180 d at 230 locations in the top 6 cm of sediment cores containing the natural macrofauna community.
4783 oxidation events m^-2· d^-1 were recorded within the upper 6 cm of the sediment. The number and duration of oxidation events declined with sediment depth below the oxic zone. Oxygen was present in the anoxic sediment, as determined from redox potential measurements, ≥ 6 h per day at 10% of the randomly chosen locations within the upper 3 cm. The overall distribution of oxidation events and their duration suggest that local, pulsed additions of oxygen by irrigation may be sufficient to maintain an oxidised sediment layer ( sensu J orgensen amp; R evsbech , 1989). Oxic environments along burrow walls rapidly fluctuate between oxic and anoxic conditions. Using oxygen microelectrodes the presence of oxygen (oxic conditions) in these halos was found to range from 2 to 12 h per day. Continuous redox measurements show that oxidised conditions fluctuate with the oxygen pulses and display the same durations, although these may range up to 21 h per day. Oxic and oxidised sediment volumes are estimated to represent < 1% and 3.7%. respectively, of the anoxic sediment to 6 cm depth. Recognition of temporal variability and spatial heterogeneity of sedimentary conditions may prove valuable for future conclusions drawn in other research fields.     

An east–west‐trending Quaternary tunnel valley in the south‐eastern North Sea and its seismic–sedimentological interpretation

A combination of a dense reflection seismic grid and up to 50‐m‐long records from sediment cores and cone penetration tests was used to study the geometry and infill lithology of an E–W‐trending buried tunnel valley in the south‐eastern North Sea. In relation to previously known primarily N–S‐trending tunnel valleys in this area, the geometry and infill of this 38‐km‐long and up to 3‐km‐wide valley is comparable, but its E–W orientation is exceptional. The vertical cross‐section geometry may result from subglacial sediment erosion of advancing ice streams and secondary incision by large episodic meltwater discharges with high flow rates. The infill is composed of meltwater sands and reworked till remnants on the valley flanks that are overlain by late Elsterian rhythmic, laminated, lacustrine fine‐grained sediments towards the centre of the valley. A depression in the valley centre is filled with sediments most likely from the Holsteinian transgression and a subsequent post‐Holsteinian lacustrine quiet‐water setting. The exceptional axis orientation of this tunnel valley points to a regional N–S‐oriented ice front during the late Elsterian. Copyright © 2012 John Wiley & Sons, Ltd.     

A new temperature based method to separate rain and snow

This paper presents the development and testing of a new method to estimate daily snowfall from precipitation and associated temperature records. The new method requires two variables; the threshold mean daily air temperature at which 50% of precipitation is considered snow, and the temperature range within which mixed precipitation can occur. Sensitivity analyses using 15 climate stations across south‐western Alberta, Canada, and ranging from prairie to alpine regions investigates the sensitivity of those two variables on mean annual snowfall (MAS), the coefficient of determination, and the MAS‐weighted coefficient of determination. Existing methods, including the static threshold method, one linear transition method used by Quick and Pipes, and the Leavesley method employed in the PRMS hydrological modelling system are compared with the new method, using a total of 963 years of daily data from the 15 climate stations used for the sensitivity analyses. Four different approaches to using the two input variables (threshold temperature and range) were tested and statistically compared: mean annual variables based on the 15 stations, mean annual variables for each station, mean monthly variables for each station, and a sine curve representing seasonal variation of the variables. In almost all cases the proposed new method resulted in higher MAS‐weighted coefficients of determination, and, on average, they were significantly different from those of other methods. The paper concludes with a decision tree to help decide which method and approach to apply under a variety of data availabilities. Copyright © 2008 John Wiley & Sons, Ltd.