Estimation of the normal geomagnetic field and geological interpretation of the normal field anomalies over middle-northern Croatia

Based on the ground survey of total-field magnetic data at 53 sites, which recorded a time-series over the interval 2003–2005, the core field + long wavelength lithospheric field over the middle-northern Croatia region was calculated. The area of the survey was 18900 km², an average distance between the neighbouring sites being 12 km. The results were reduced to 2004.5 epoch. This “normal” total-field was estimated using the firstorder Taylor polynomial as a function of geographic coordinates, and the polynomial coefficients were calculated with three methods of adjustment: simple and weighted least squares fits and adjustment according to the most frequent value. The stability of the normal field was tested using the Monte Carlo-type test, by decreasing the input data set in each adjustment (up to 90%). All obtained field residuals (measured-“normal”) were mutually compared, as well as fit coefficients of the Taylor polynomials. The residual values indicate the presence of shorter-wavelength anomalies, specifically three major residual anomalies were found (−106 nT, 74 nT and 57 nT). The geostatistical analysis of the ground survey data and the normal field residuals (respectively), using the median absolute deviation method, was further conducted in order to evaluate the calculated anomalies. The geological situation around the anomalies derived by the median absolute deviation method, and around the normal field residual anomalies, is given. The correlation was found between higher value anomalies of the normal field residuals, and shallow volcanic rocks and oil field, respectively.     

Rječina River sediments (Croatia): from captured spring to polluted prodelta

Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.     

Fe2+, Mg-distribution among non-equivalent structural sites M1 and M2 in natural olivines: an optical spectroscopy study

Analysis of E||X-polarized optical absorption spectra of natural olivines of various origin in the range of electronic spin-allowed dd-transitions of Fe²⁺ evidences that in some crystals, there is a weak ordering of Fe²⁺ as in M1, as in M2 structural sites. The samples of three different depth facies seem showing a vague tendency of lowering of k _D -values from spinel-pyroxene (Sp-Px) through graphite-pyrope (G-Py) to diamond-pyrope (D-Py) facies, but the statistics are too poor (24 samples only) to be certain of it. Weak relations between Mg, Fe²⁺-distribution and iron content were found for the samples of Sp-Px- and G-Py-facies, while there is practically no one for those of the deepest D-Py facie.     

The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds

The crystal structure of ilinskite, NaCu₅O₂(SeO₃)₂Cl₃, a rare copper selenite chloride from volcanic fumaroles of the Great fissure Tolbachik eruption (Kamchatka peninsula, Russia), has been solved by direct methods and refined to R ₁?=?0.044 on the basis of 2720 unique observed reflections. The mineral is orthorhombic, Pnma, a?=?17.769(7), b?=?6.448(3), c?=?10.522(4) Å, V?=?1205.6(8) ų, Z?=?4. The The CuO_mCl_n coordination polyhedra share edges to form tetramers that have 'additional' O1 and O2 atoms as centers. The O1Cu₄ and O2Cu₄ tetrahedra share common Cu atoms to form [O₂Cu₅]⁶⁺ sheets. The SeO₃ groups and Cl atoms are adjacent to the [O₂Cu₅]⁶⁺ sheets to form complex layers parallel to (100). The Na⁺ cations are located in between the layers. A review of mixed-ligand CuO_mCl_n coordination polyhedra in minerals and inorganic compounds is given. There are in total 26 stereochemically different mixed-ligand Cu-O-Cl coordinations.     

Surficial deposits on salt diapirs (Zagros Mountains and Persian Gulf Platform, Iran): Characterization, evolution, erosion and the influence on landscape morphology

The surfaces of salt diapirs in the Zagros Mountains are mostly covered by surficial deposits, which significantly affect erosion rates, salt karst evolution, land use and the density of the vegetation cover. Eleven salt diapirs were selected for the study of surficial deposits in order to cover variability in the geology, morphology and climate in a majority of the diapirs in the Zagros Mountains and Persian Gulf Platform. The chemical and mineralogical compositions of 80 selected samples were studied mainly by X-ray powder diffraction and X-ray fluorescence. Changes in salinity along selected vertical profiles were studied together with the halite and gypsum distribution. The subaerial residuum formed from minerals and rock detritus released from the dissolved rock salt is by far the most abundant material on the diapirs. Fluvial sediments derived from this type of residuum are the second most common deposits found, while submarine residuum and marine sediments have only local importance. The mineralogical/chemical composition of surficial deposits varies amongst the three end members: evaporite minerals (gypsum/anhydrite and minor halite), carbonates (dolomite and calcite) and silicates-oxides (mainly quartz, phyllosilicates, and hematite). Based on infiltration tests on different types of surficial deposits, most of the rainwater will infiltrate, while overland flow predominates on rock salt exposures. Recharge concentration and thick accumulations of fine sediment support relatively rich vegetation cover in some places and even enable local agricultural activity. The source material, diapir relief, climatic conditions and vegetation cover were found to be the main factors affecting the development and erosion of surficial deposits. A difference was found in residuum type and landscape morphology between the relatively humid NW part of the studied area and the arid Persian Gulf coast: In the NW, the medium and thick residuum seems to be stable under current climatic conditions. Large sinkholes and blind valleys with sinking streams are common. On other diapirs, the original thick residuum is undergoing erosion and the new morphology is currently represented by salt exposures and badland-like landscapes or by fields of small sinkholes developed in the thin residuum. Models for evolution of the subaerial residuum and the diapir landscape/morphology are described in this paper. While the thick residuum with vegetation has very low erosion rates, the salt exposures and thin residuum are eroded rapidly. During wet periods (e.g. early Holocene), the diapirs rose and salt glaciers expanded as the influx of salt mass was much faster compared to erosion. After the onset of an arid climate, c. 6 ka BP, the rising of the some diapir surfaces decreased or even reversed due to acceleration of erosion thanks to vegetation degradation and changes in the residuum type and thickness.     

Permafrost occurrence during the Last Permafrost Maximum in the Western Carpathian Mountains of Slovakia as inferred from cryogenic cave carbonate

Coarse crystalline cryogenic cave carbonate (CCC) forms during the slow freezing of standing water pools and represents indirect proof of freezing temperature in the past. The dating by U‐series of CCC deposits from nine caves in the Western Carpathians Mountains of Slovakia suggests that freezing conditions, and possible permafrost conditions, occurred during the Last Permafrost Maximum (LPM, c. 20–18 ka BP). The CCC deposits occur in caves at elevations of between 800 and 1800 m a.s.l. They point to widespread alpine permafrost, the lower limit of discontinuous/sporadic permafrost being approximately 800 m a.s.l. The thickness of permafrost probably varied between 30 and 180 m. In the Vysoké Tatry Mountains at altitudes of ～1800 m a.s.l., one occurrence of CCC suggests that subzero temperatures may have penetrated to a depth of over 285 m.     

Aspects of the long-term cosmic-ray modulation

To investigate the long-term modulation of galactic cosmic rays at the ground-based detector energies, the monthly values of the neutron monitor (Climax, Mt. Washington, Deep River, and Huancayo) and ionization chamber (Cheltenham/Fredericksburg, Huancayo, and Yakutsk) intensities have been correlated with the sunspot numbers (used as a proxy index for transient solar activity) for each phase of sunspot cycles 18 to 22. Systematic differences are found for results concerning odd and even sunspot cycles. During odd cycles (19 and 21) the onset time of cosmic-ray modulation is delayed when compared with the onset time of the sunspot cycle, while they are more similar during even (18, 20, and 22) cycles. Checking the green corona data, on a half-year basis, we found typical heliolatitudinal differences during ascending phases of consecutive sunspot cycles. This finding suggests a significant role of the latitudinal coronal behaviour in the heliospherical dynamics during a Hale cycle. Such effectiveness concerns not only the transient interplanetary perturbations but also the recurrent ones. In fact, when lag between cosmic-ray data and sunspot numbers is considered, the anticorrelation between both parameters is very high (correlation coefficient |r| > 0.9) for all the phases considered, except for the declining ones of cycles 20 and 21, when high-speed solar wind streams coming from coronal holes affect the cosmic-ray propagation, and theRz parameter is no longer the right proxy index for solar-induced effects in the interplanetary medium.     

Determination of origin of NASA stratospheric particles

Paper presents a reanalysis of four stratospheric particles registered in the Cosmic Dust Catalogs (CDC). Two particles have been classifed in the NASA Johnson Space Centre (JSC) in Houston as natural, terrestrial contaminants and the origin of the other two particles was found questionable, probably cosmic. Present study has confirmed these conclusions; however some new additional features in the chemical analysis have been found which can finally determine the classification of the particles with unclear origin.     

Analysis of the time profile of type III bursts at meter wavelengths

The time profile of two sets of isolated type III bursts, observed in the meter wavelength range at the Trieste Astronomical Observatory, was analyzed using a Fourier transform technique in order to accurately determine the decay constant of the exponential phase and to derive the exciter time profile. The decay constant () was found to be correlated with the exciter duration (D _e ), suggesting that the damping of plasma waves is not of collisional origin and confirming results obtained by previous authors at lower frequencies. In particular, two distributions can be identified in the ( – D _e ) plane and fitted by two nearly parallel lines, which could be the signature of different decay processes. Moreover, the damping constant observed at higher frequencies (327 and 408 MHz) has the same dependence on exciter duration as that at the lower frequency (237 MHz), also in disagreement with the collisional hypothesis.