Magnetic,geochemical and mineralogical properties of sediments from karstic and flysch rivers of Croatia and Slovenia

The aim of the present work was to investigate links between the low-field magnetic susceptibility (MS) and chemical and mineral composition of sediments from several Croatian and Slovenian rivers, as well as to determine possible anthropogenic influence on these sediments. MS measurements are a fast and simple method, which serves as a proxy for the estimation of pollution in different environmental systems. The investigated rivers are predominantly unpolluted rivers from Croatian and Slovenian karstic and flysch areas, which belong to the Adriatic or the Black Sea watersheds: the Dragonja, the Mirna, the Ra?a, the Ri?ana, the Reka, the Rak, the Cerkni?nica, the Unec and the Ljubljanica rivers. It was assumed that, due to their mostly unpolluted status, they could serve as a database for natural MS background values for this region. For comparison, several rivers and a lake from the Celje old metallurgic industrial area (Slovenia) were also investigated: the Savinja, the Hudinja, the Voglajna rivers and Slivni?ko Lake. They form a sub-basin of the Sava River drainage basin. Sediments of the clean karstic and flysch rivers showed extremely low MS values, with mass susceptibility values ranging from 0.58 × 10^?7 to 5.11 × 10^?7 m³/kg, and isothermal remanent magnetism (IRM) values ranging from 0.71 to 7.88 A/m. In the Celje industrial area, river sediments showed much higher MS values, with mass susceptibility values ranging from 1.31 × 10^?7 to 38.3 × 10^?7 m³/kg, and IRM values ranging from 0.91 to 100.42 A/m. The highest MS value was found in the Voglajna River at Teharje-?tore, a point which showed a significant number of anomalies of toxic metals in earlier investigations. Semiquantitative determination of relations between grain size and concentration of magnetite was performed using the Thompson-Oldfield method. X-ray diffraction (XRD) mineralogical analysis showed that sediments of the Celje area have mostly quartz as major mineral, with relatively small amount of carbonate minerals, while in sediments of karstic rivers carbonate minerals prevail. Statistically significant correlations were obtained between MS and Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd and Ba in the Slovenian karstic region and between MS and Cr, Fe, Co, Ni and Zn in flysch drainage basins. On the contrary, no correlation of MS and Hg content was obtained.     

Modeling the electric structures of two thunderstorms and their contributions to the global circuit

This study examines the electricity in two thunderstorms, typical for their respective locales (the Great Plains and the New Mexico mountains), by modeling them as a set of steady-state horizontal layers of external currents. The model electric sources, corresponding to the charge separation processes in the thundercloud, are embedded in an exponential conducting atmosphere. The source parameters are determined by fitting the model electric field to measured profiles. The resulting currents to the ionosphere (i.e., the Wilson current) from the two storms are 0.53 A and 0.16 A, while the calculated electrical energies of the storms are 2.3 × 10¹⁰ J and 2.8 × 10⁹ J, respectively. The more vigorous storm is estimated to transfer 16 000 C in the global circuit during 8.5 h of its lifetime, while the weaker mountain storm transferred about 1200 C in its entire 2-h lifetime. Removal of the screening charge layer from above the updraft region in one modeled storm leads to only a small increase in the net Wilson current of less than 3%, while it provides a substantial local disturbance of the electric field. Overall, the model findings indicate that differences in the Wilson currents and electrical energies of the two storms result from differences in their internal dynamical and electrical structures as well as their geographical locations.     

Weathering fluxes of arsenic from a small catchment in Slovak Republic

Inputs of As to a small catchment due to chemical weathering of bedrock, mechanical weathering of bedrock, and atmospheric precipitation were 71.53, 23.98 and 0.02 g ha⁻¹ year⁻¹, respectively. The output fluxes of As due to mechanical erosion of soil, biological uptake, stream discharge, and groundwater flow were 6.32, 4.77, 0.37 and 0.02 g ha⁻¹ year⁻¹, respectively. The results indicate that arsenic accumulates in soil and regolith with a very high rate. This is attributed to the selective weathering and erosion with respect to arsenic and fixation of arsenic in the secondary solids produced by weathering. The output fluxes of As in stream and groundwater in Vydrica catchment in Slovak Republic (0.39 g ha⁻¹ year⁻¹) based on muscovite–biotite granites and granodiorites were much lower compared to catchments in a gold district in the Czech Republic. These results may be ascribed to the low levels of arsenic pollution measured in Vydrica catchment. The arsenic fluxes were estimated by calculation of mechanical and chemical weathering rates of the bedrocks in Vydrica catchment from mass balance data on sodium and silica. The justification of the steady state of Na and Si is that neither of the elements is appreciably accumulated in plants and in exchangeable pool of ions in soil.     

Study of variable stars associated with maser sources: G025.65+1.05

We report variation of K-band infrared(IR) emission in the vicinity of the G025.65+1.05 water and methanol maser source. New observational data were obtained with the 2.5 m telescope at the Caucasian Mountain Observatory(CMO) of Moscow State University on 2017–09–21 during a strong water maser flare. We found that the IR source situated close to the maser position had decreased brightness in comparison to archive data. This source is associated with a massive young stellar object(MYSO) corresponding to the compact IR source IRAS 18316–0602(RAFGL 7009 S). A similar decrease in K-brightness of the IR source close to the maser position was observed in March 2011 when the water maser experienced a period of increased activity. The dips in MYSO brightness can be related to the maser flare phases. Maser flares that are concurrent with dips in the IR emission can be explained if the lower IR radiation field enables a more efficient sink for the pumping cycle by allowing IR photons to escape the maser region.     

X-ray Emission from the Pre-Main Sequence Systems FU Orionis and T Tauri

We present new results from recent X-ray observations of the accreting pre-main sequence stars FU Orionis and T Tauri. XMM-Newton observations of the close binary system FU Ori reveal an unusual X-ray spectrum consisting of a cool moderately-absorbed component and a hot component viewed through much higher absorption. The two components thus originate in physically distinct regions. The double absorption spectrum is qualitatively different than observed in typical coronal sources and may signal either non-coronal emission or separate unresolved X-ray contributions from more than one star in the system. High-resolution Chandra imaging of the T Tau triple system shows that its X-ray emission is dominated by the optically-revealed northern component T Tau N. X-ray spectra of T Tau obtained with XMM can be acceptably fitted with a moderately absorbed two-temperature thermal plasma model. Its spectral properties are similar to those seen in coronal X-ray sources.     

Computation of the heat function connected with short-wave radiation fluxes

Summary A report is presented on the use of the method, suggested by H. and K. Lettau, for the purposes of computing short-wave radiation fluxes and the heat function, connected with them, in atmospheric models, used for short-range numerical weather forecasting.Dedicated to 90th Birthday of Professor Frantiek Fiala     

Barium anomaly in Kupa River drainage basin

The objective of this work is to present an example of environmental impact of barite waste management observed in stream sediments of the western part of the Kupa River drainage basin. It is a significant water resource for Croatia and a part of Slovenia. In addition, it is for both countries a region of tourism, sport and fishing. Sediments (fraction < 63 μm) collected within the whole drainage basin have shown a significant barium anomaly in the western part. The highest concentration of total barium (5790 mg/kg) was determined in Kupica, a tributary of Kupa River. The barium anomaly was traced in Kupa River about 120 km downstream. Looking for the contamination source it was found that the anomaly originates from uncareful waste disposal into an abyss, after barite separation in Homer (Lokve), Gorski Kotar, Croatia. From there barite entered Kupica River subterraneous. Barite and albite were identified by XRD near the source of Kupica River as minor minerals, while quartz and dolomite ferroan were major minerals. This preliminary report does not give yet an answer about barium solubility in river water, about its bioavailability and consequently about barium pollution in the western part of the Kupa River drainage basin, however the possibility is highlighted and discussed.     

Optimization of interpolation parameters when deriving DEM from contour lines

Digital elevation models (DEMs) are still an important and current source of information for digital soil mapping and the modeling of soil processes. The grid DEM is often interpolated from contour lines. The contour sampling step becomes an additional interpolation parameter which can play an important role. The objective of this paper is to optimize the interpolation parameters of the Regularized spline with tension (RST) method, in order to prepare a DEM suitable as an input for erosion modeling. Two contrasting cases, with and without a reference DEM, were investigated. If a reference DEM was available, good results of interpolation were reached both by small and larger sampling steps. In the second case, it was found that small sampling steps should be avoided. The influence of the sampling was demonstrated by topographic potential for erosion and deposition.     

Perpotassic granulites from southern Bohemia

Garnetiferous, perpotassic granulites associated with voluminous, felsic calc-alkaline garnet-kyanite granulites in the Blanský les massif are described as a new rock type. A K₂O content near 13 wt%, Zr content ranging from 17 to 5877 ppm, primary Ca-Mg-Fe garnet (pyrope up to 33 mol %), and the absence of primary plagioclase and quartz characterize the new type of granulite. Calcium is incorporated only in garnet and apatite. Owing to the content of garnet the bulk syenitic compositions are metaaluminous to peraluminous. The perpotassic granulites are accompanied by subordinated melanocratic perpotassic granulite and alkali-feldspar melanocratic granulite containing up to 20 vol % quartz. These rock types also contain highly variable amounts of zircon. High-pressure, noneutectic partial melting of crustal rocks and crystallization under upper mantle conditions is suggested as the main process in generation of perpotassic granulites. A polyphase, ductile to brittle deformation and recrystallization in pyroxene granulite and later in amphibolite facies accompanied obduction of the granulite massif which carries numerous enclaves of pyrope peridotite. Euhedral equant zircon crystals up to 4 mm long enclosed in large garnet crystals and in the alkali feldspar matrix of perpotassic granulite represent a uniform, high-temperature population with a nearly concordant U-Pb system (Aftalion et al. 1989). The Hercynian age of this zircon indicates the role of the Hercynian anatexis of crustal rocks under upper mantle conditions in generation of granulites in the Moldanubian zone of the Bohemian massif.