Geochemical characterization and heavy metal contamination of groundwater in Satluj River Basin

Groundwater, a renewable and finite natural resource, vital for man’s life, social and economic development and a valuable component of the ecosystem, is vulnerable to natural and human impacts. The aim of present study is to evaluate hydrogeochemical parameters and heavy metals in groundwater and to study their spatial distribution in the Rupnagar District of Punjab. The spatial distribution of physico-chemical parameters were studied using Arc GIS 9.2. It was observed that the concentration of parameters, such as NO₃, Cd, Cr, Mn and Pb was above permissible limit (World Health Organization, WHO) in southern part of the study area. The heavy metal pollution index (HPI) was calculated for all sampling locations and it was found much above the critical limit of pollution. Geochemical reaction models of selected water groups were constructed using Phreeqc. Geochemical modeling suggests that sodium has source other than halite-albite and calcium has alternate source other than gypsum-carbonate or silicates. It also suggests that evaporites, ion exchange, dissolution along with anthropogenic activities are controlling the hydro-geochemistry of groundwater in the region. Various indices, such as heavy metal pollution index, permeability index, sodium adsorption ratio, were studied to verify suitability of groundwater for drinking and irrigation.     

The Air-Coastal Sea Chemical Exchange: A Case Study on the New Jersey Coast

The coastal marine atmosphere adjacent to large urban and industrial centers is in general strongly impacted by pollution emissions, resulting in high loading of pollutants in the ambient air. Among the airborne substances are certain trace elements from a variety of emission sources that can serve as micronutrients to marine organisms in coastal waters. High concentrations of such elements in coastal air can result in enhanced air-to-sea deposition fluxes to coastal waters. They could also be transported over the open ocean, affecting the composition of the remote marine atmosphere and then ocean ecosystems. To provide better understanding of the extent of air-to-sea deposition processes on the New Jersey coast, a heavily polluted coastal region on the US East Coast, a synthesis of observation data was carried out for selected trace elements, including Fe, Cd, Cr and Cu, derived from measurements of both size-segregated and bulk aerosol particles, as well as precipitation around the New Jersey coast. The atmospheric input of Hg was also estimated based on measurement data. Results indicated that the total deposition fluxes of most trace elements were higher in Northern coastal NJ compared to Southern coastal NJ, reflecting the differences in the source strengths of these element emissions between the two coastal regions. Dry deposition processes were more significant for common dust-derived elements, particularly Fe and Al, compared with their wet deposition fluxes. However, the processes of precipitation scavenging appeared to be more important for the elements that were often enriched in fine particles including Zn, Cu, Pb and Ni. The removal of Hg from the ambient air was overwhelmingly dominated by atmospheric wet deposition. In the future, atmospheric measurements at more sites on the NJ coast should be performed simultaneously to reduce the spatial and temporal uncertainties associated with atmospheric deposition fluxes estimated in this study.     

Nature and origin of arsenic carriers in shallow aquifer sediments of Bengal Delta,India

Sediments from shallow aquifers in Bengal Delta, India have been found to contain arsenic. Rivers of Ganga-Brahmaputra system, responsible for depositing these sediments in the delta, have created a store of arsenic. Geomorphological domains with different depositional styles regulate the pattern of distribution of zones with widely different content of groundwater arsenic. The high arsenic zones occur as narrow sinuous strips confined to channel deposits. A few iron-bearing clastic minerals and two post-depositional secondary products are arsenic carriers. Secondary siderite concretions have grown on the surface of the clastic carriers in variable intensity. The quantity of arsenic in all clastic carriers is in excess of what is generally expected. Excess arsenic is contributed by the element adsorbed on the concretion grown on the surface of the carriers, which adds up to the arsenic in the structure of the minerals. Variable abundance of concretions is responsible for the variable quantity of arsenic in the carriers and the sediment samples. Fe²⁺ for the growth of siderite concretions is obtained from the iron-bearing clastic carriers. The reaction involves reduction of trivalent iron to bivalent and the required electron is obtained by transformation of As³⁺ to As⁵⁺. It is suggested that oxidation of As³⁺ to As⁵⁺ is microbially mediated. In the Safe zone arsenic is retained in the carriers and groundwater arsenic is maintained below 0.05 mg/l. In the Unsafe zone sorbed arsenic is released from the carriers in the water through desorption and dissolution of concretion, thereby elevating the groundwater arsenic level to above 0.05 mg/l.     

Groundwater discharge along a channelized Coastal Plain stream

In the Coastal Plain of the southeastern USA, streams have commonly been artificially channelized for flood control and agricultural drainage. However, groundwater discharge along such streams has received relatively little attention. Using a combination of stream- and spring-flow measurements, spring temperature measurements, temperature profiling along the stream-bed, and geologic mapping, we delineated zones of diffuse and focused discharge along Little Bayou Creek, a channelized, first-order perennial stream in western Kentucky. Seasonal variability in groundwater discharge mimics hydraulic-head fluctuations in a nearby monitoring well and spring-discharge fluctuations elsewhere in the region, and is likely to reflect seasonal variability in recharge. Diffuse discharge occurs where the stream is incised into the semi-confined regional gravel aquifer, which is comprised of the Mounds Gravel. Focused discharge occurs upstream where the channel appears to have intersected preferential pathways within the confining unit. Seasonal fluctuations in discharge from individual springs are repressed where piping results in bank collapse. Thereby, focused discharge can contribute to the morphological evolution of the stream channel.     

Assessment of climate variability and trend on wheat productivity in West Bengal,India: crop growth simulation approach

Wheat is the second important cereal crop after rice in West Bengal. During last three decades, due to climate fluctuations and variability, the productivity of this crop remains almost constant, bringing the threat of food security of this State. The objectives of the present study were to assess the trend of climatic variables (rainfall, rainy days, and temperature) over six locations covering five major agro-climatic sub-zones of West Bengal and to estimate the variability of potential, simulated yield using crop simulation model (DSAATv4.5) and the yield gap with actual yield. There were no significant change of rainfall and rainy days in annual, seasonal and monthly scale at all the study sites. In general, the maximum temperature is decreasing throughout West Bengal. Except for Birbhum, the minimum temperature increased significantly in different study sites. District average yield of wheat varied from 1757 kg ha^?1 at Jalpaiguri to 2421 kg ha^?1at Birbhum. The actual yield trend ranged from ??4.7 kg ha^?1 year^?1 at Nadia to 32.8 kg ha^?1 year^?1 at Birbhum. Decreasing trend of potential yield was observed in Terai (Jalpaiguri), New Alluvial Zone (Nadia) and Coastal saline zone (South 24 Parganas), which is alarming for food security in West Bengal.     

Investigation of dominant modes of monsoon ISO in the northwest and eastern Himalayan region

This study investigates the altitudinal variation of dominant modes of summer monsoon intra-seasonal oscillation (ISO) over the Northwest (NWH) and Eastern Himalayan (EH) region using (i) spatially scattered 133 number of station rainfall observations and (ii) latitudinal transect-wise (LT) rainfall variation, obtained from an observed interpolated gridded rainfall data for the period 1995–2004. The altitudinal variation of dominant modes of monsoon ISO were investigated by exploring the strong and weak phases of the principal components of 10–90 days bandpass rainfall data of June to September with respect to location specific station height. Investigation of frequency of days for light and moderate rainfall along with the occurrence of total seasonal rainy days has revealed existence of a rainfall maximum around 2100 m height for the NWH region. Similarly, the total seasonal rainy days of EH region was found to have maxima between 1100 and 1400 m height. Analyses of the spatially scattered station rainfall observation for the NWH region showed that the strong periods of ISO modes exist around 747.9 (±131.7) m and 2227.2 (±100.2) m heights. Over the EH region, the dominant modes of the monsoon ISO were found to be centred around 1200 m. Significant alterations of strong and weak phases of monsoon ISO as a response to altitudinal variation in the mountain surface were observed when latitudinal transect-wise variation of monsoon ISO modes were investigated.     

Reproducing the Piper trilinear diagram in rectangular coordinates

Though several alternatives/modifications to the Piper diagram are available, the Piper diagram is still the most common way of representing chemical analyses. The present note shows how to reproduce the Piper trilinear diagram in rectangular coordinates retaining all the essential features of the trilinear diagram. In this form, it can be generated using commonly used graphics packages without requiring specialized software. A sample data set of six samples from Gurur watershed, Chhattisgarh, India, was used to illustrate the method. The patterns of points produced in the trilinear Piper diagram and the reproduced Piper diagram in rectangular coordinates are essentially identical.     

Fluoride enrichment in aquifers of the Thar Desert: controlling factors and its geochemical modelling

The groundwater is the only source of drinking water in the Jaisalmer district of Rajasthan, India. The study area is a part of the Thar Desert. It has low and scattered population and no industries; hence, the possibility of anthropogenic input of fluoride is almost negligible. Thus, the enrichment of fluoride is only possible due to geochemical processes taking place in the groundwater of the region. A total of 100 groundwater samples, 34 samples from Jaisalmer and 66 samples from the Pokharan administrative blocks, were collected. It was observed that the concentration of fluoride ranged from 0.08 mg/l to 4.56 mg/l in the groundwater of Jaisalmer and from 0.56 mg/l to 6.60 mg/l in the samples of the Pokharan block. The alkaline condition (average pH, 7.7 ± 0.22 and 8.01 ± 0.25 in Jaisalmer and the Pokharan administrative block, respectively) in the region favours fluorite dissolution. Ion exchange, dissolution of calcite, semi‐arid climate, alkaline conditions and weathering are responsible for fluoride enrichment in the groundwater of the study area. Copyright © 2012 John Wiley & Sons, Ltd.     

Geospatial and geostatistical approach for groundwater potential zone delineation

Over the past few decades, groundwater has become an essential commodity owing to increased demand as a result of growing population, industrialization, urbanization and so on. The water supply situation is expected to become more severe in the future because of continued unsustainable water use and projected change in hydrometeorological parameters due to climate change. This study is based on the integrated approach of remote sensing, geographical information system and multicriteria decision‐making techniques to determine the most important contributing factors that affect the groundwater resources and to delineate the groundwater potential zones. Ten thematic layers, namely, geomorphology, geology, soil, topographic elevation (digital elevation model), land use/land cover, drainage density, lineament density, proximity of surface water bodies, surface temperature and post‐monsoon groundwater depth, were considered for the present study. These thematic layers were selected for groundwater prospecting based on the literature; discussion with the experts of the Central Ground Water Board, Government of India; field observations; geophysical investigation; and multivariate techniques. The thematic layers and their features were assigned suitable weights on Saaty's scale according to their relative significance for groundwater occurrence. The assigned weights of the layers and their features were normalized by using the analytic hierarchy process and eigenvector method. Finally, the selected thematic maps were integrated using a weighted linear combination method to create the final groundwater potential zone map. The final output map shows different zones of groundwater potential, namely, very good (16%), good (35%), moderate (28%) low (17%) and very low (2.1%). The groundwater potential zone map was finally validated using the discharge and groundwater depth data from 28 and 98 pumping wells, respectively, which showed good correlation. Copyright © 2014 John Wiley & Sons, Ltd.