Electron spin-lattice relaxation of SO 3 − radical ion in a single crystal of barite

The electron spin-lattice relaxation time (T_1e) of the paramagnetic radical-ion center SO ₃ ^? in a naturally occurring single crystal of barite was studied in the temperature range 10–300 K by the pulse saturation recovery technique. The changes in T_1e from 30 K to 300 K are much smaller than those expected from usual Raman processes in solids. The results suggest a very weak connection between SO ₃ ^? center and lattice.     

Geochemistry of Renuka Lake and wetland sediments,Lesser Himalaya (India): implications for source-area weathering,provenance, and tectonic setting

The geochemical investigation of sediments deposited in the Renuka Lake basin and its adjoining wetland has shown variation in the distribution and concentration of major, trace and REEs. The major elements are depleted in the lake in relation to wetland and that of Post Archaean Australian, Shale (PAAS), except for CaO which is strikingly in excess and has a dilution effect on SiO₂ and other oxides and trace elements. The Wetland sediments, on the other hand, are enriched in Al₂O₃, Fe₂O₃, K₂O and TiO₂ and the latter three show a positive correlation with Al₂O₃ in both wetland and lake sediments suggesting their association with phyllosilicates and similar source rocks. The enrichment of Y, Zr, Ni, Th, U and Nb in wetland compared to lake and their similarity with PAAS in the former, suggests more clay fractions in the wetland. A high Zr/Hf ratio in wetland and lake sediments and a positive correlation of Zr with Y and HREE indicate Zr control on HREEs. However, higher Zr/Yb and Zr/Th ratios in wetland compared to lake indicate mineral sorting during the process of lighter particles (clays) being trapped in wetland soil. This is also reflected from negative correlation of Gd_N/Yb_N with Al₂O₃ and a strong positive correlation with SiO₂ in wetland sediments. The wetland in this context has a control on lake sediment chemistry. The chondrite normalized REE patterns are essentially the same for lake as well as wetland sediments but abundance decreases in the former. The similarity of pattern with that of PAAS and negative Eu anomaly indicates a cratonic source of sediments. In a plot of the individual samples, wetland samples cluster while lake samples are separated indicating fractionation of lake sediments. A strong positive correlation of La_N/Yb_N with Al₂O₃ and a positive correlation of Zr-∑LREE and Zr-La_N/Yb_N suggest that LREEs are controlled by both phyllosilicates and zircon. The chemical index of alteration (CIA) indices in lake sediments and in wetland are higher than PAAS indicating moderate chemical weathering in the source area. The petrography, lack of felsic magmatic rock fragments, and negative correlation between Zr-(Gd/Yb)_C indicate sedimentary source rocks for the detritus. This is in conformity with the Lesser Himalayan sedimentary sequence belonging to neo-Proterozoic–Proterozoic age and constituting lake catchment of Renuka. The tectonic delineation and discriminant function plots of lake and wetland sediments indicate their cratonic and/or quartzose sedimentary orogenic terrain source that has been deposited in a passive margin setting.     

Satellite detection of earthquake thermal infrared precursors in Iran

Stress accumulated in rocks in tectonically active areas may manifest itself as electromagnetic radiation emission and temperature variation through a process of energy transformation. Land surface temperature (LST) changes before an impending earthquake can be detected with thermal infrared (TIR) sensors such as NOAA-AVHRR, Terra/Aqua-MODIS, etc. TIR anomalies produced by 10 recent earthquakes in Iran during the period of Jun 2002–Jun 2006 in the tectonically active belt have been studied using pre- and post-earthquake NOAA-AVHRR datasets. Data analysis revealed a transient TIR rise in LST ranging 2–13°C in and around epicentral areas. The thermal anomalies started developing about 1–10 days prior to the main event depending upon the magnitude and focal depth, and disappeared after the main shock. In the case of moderate earthquakes (<6 magnitude) a dual thermal peak instead of the single rise has been observed. This may lead us to understand that perhaps pre-event sporadic release of energy from stressed rocks leads to a reduction in magnitude of the main shock. This TIR temperature increment prior to an impending earthquake can be attributed to degassing from rocks under stress or to p-hole activation in the stressed rock volume and their further recombination at the rock–air interface. A precise correlation of LST maps of Bam and Zarand with InSAR-generated deformation maps also provides evidence that the thermal anomaly is a ground-related phenomenon, not an atmospheric one.     

Remote Sensing and GIS Based Analysis of Geomorphic Evidences and Morphometry of Active Faults in Kachchh Area

Kachchh basin is a Mesozoic rift basin under the influence of many active faults. This in turn gives rise to marked structural complexity and associated seismicity. Remote Sensing study of geomorphic evidences of these faults has been carried out using satellite images and is validated using morphometric analysis and digital elevation model data. Satellite images not only help in identifying expression of active faults and active tectonics on a macroscopic scale, but also provide the image characteristics of active faults directly. A few faults along with nature of lateral displacement could be identified from the Kachchh area. Morphometric analysis viz., sinuosity, asymmetry factor and hypsometry indicated affected streams and drainage basins due to fault activity.     

Crop Evapotranspiration Estimation for Wheat (<Emphasis Type="Italic">Triticum aestivum</Emphasis> L.) Using Remote Sensing Data in Semi-Arid Region of Maharashtra

Penman–Monteith method adapted to satellite data was used for the estimation of wheat crop evapotranspiration during the entire growth period using satellite data together with ground meteorological measurements. The IRS-1D/IRS-P6 LISS-III sensor data at 23.5 m spatial resolution for path 096 and row 059 covering the study area were used to derive, albedo, normalized difference vegetation index, leaf area index and crop height and then to estimate wheat crop evapotranspiration referred to as actual evapotranspiration (ETact). The ETact varied from 0.86 to 3.41 mm/day during the crop growth period. These values are on an average 16.40 % lower than wheat crop potential evapotranspiration (ETc) estimated as product of reference crop evapotranspiration estimated by Penman–Monteith method and lysimetric crop coefficient (Kc). The deviation of ETact from ETc is significant, when both the values were compared with t test for paired two sample means. Though the observations on ETact were taken from well maintained unstressed experimental plot of 120 × 120 m size, there was significant deviation. This deviation could be attributed to, the satellite images representing the actual crop evapotranspiration as function crop canopy biophysical parameters, condition of the crop stand, climatic and soil conditions and the microclimate variation over area of one hectare. However, Penman–Monteith method represents a flat rate of specific growth stage of the crop.     

Regional climate changes drive increased scaled-chrysophyte abundance in lakes downwind of Athabasca Oil Sands nitrogen emissions

Several limnological and paleolimnological investigations have linked enhanced atmospheric nitrogen (N) deposition to nutrient enrichment and increased primary production. The Athabasca Oil Sands Region (AOSR) in northeast Alberta, Canada is a significant source of N emissions, particularly since development intensified during the 1990s, and recent paleolimnological investigations provide evidence of increased lake production in adjacent areas subject to enhanced N deposition. The AOSR, however, has also experienced atmospheric warming since ca. AD 1900, and therefore the relative effects of nutrient deposition and climate changes on lake production remain unclear. We undertook a factorial-design paleolimnological assessment of 16 lakes in northwest Saskatchewan to quantify changes in abundance and species composition of scaled chrysophytes over the past 100 years. Study sites included both N-limited and P-limited lakes within control regions, as well as lakes that receive enhanced N deposition from the AOSR. We hypothesized that a change in algal communities within N-limited AOSR-impacted lakes, without concurrent changes in the other lake groups, would suggest AOSR-derived N as a driver of enhanced primary production. Instead, marked increases in concentrations of scaled chrysophytes, mainly Mallomonas crassisquama, occurred in the recent sediments in cores from all four lake groups (N-limited vs. P-limited, impacted vs. control), suggesting that regional climate change rather than N deposition was the paramount process enhancing chrysophyte production. Because chrysophyte abundances tended to be higher in deep, lower-pH lakes, and chrysophyte time series were fit best by lake-specific generalized additive models, we infer that climate effects may have been mediated by additional catchment and/or lake-specific processes.     

Rice-acreage estimation for Orrisa using remotely sensed data

Rice is one of the most important foodgrains grown in India. Attempts have been made to estimate kharif rice acreage of Orissa state since 1986 using digital remote sensing data from Landsat MSS/TM and/or IRS-1A. Accuracies of the estimates obtained have been evaluated against BES (Bureau of Economics and Statistics) estimate. This paper describes the methodology adopted for rice acreage estimation of Orissa state, the results obtained for three years, i.e. 1986–87, 1988–89 and 1989–90, and their accuracy.     

Reaction enhanced channelised fluid-flux along mid- crustal shear zone: An example from Mesoproterozoic Phulad Shear Zone,Rajasthan, India

Fluid infiltration at great depth during regional metamorphism plays a major role in mass transport and is responsible for significant rheological changes in the rock. Calc-silicate rocks of the Kajalbas area of Delhi Fold Belt, Rajasthan, are characterised by foliation parallel alternate bands of amphibole-rich and clinopyroxene–plagioclase feldspar-rich layers of varying thicknesses (mm to decimetre thick). Textural relation suggests that the amphibole grains formed from clinopyroxene and plagioclase in the late phase of regional deformation. Algebraic analysis of the reaction textures and mineral compositions was performed with the computer program C-Space to obtain the balanced chemical reactions that led to the formation of amphibole-rich bands. The computed balanced reaction is 70.74 Clinopyroxene + 27.23 Plagioclase + 22.018 H₂O + 5.51 K⁺+ 1.00 Mg²⁺+ 27.15 Fe²⁺ = 22.02 Amphibole + 67.86 SiO₂ aqueous + 36.42 Ca²⁺+ 8.98 Na⁺. The constructed reaction suggests that aqueous fluid permeated the calc-silicate rock along mm to decimetre thick channels, metasomatized the clinopyroxene–plagioclase bearing rocks to form the amphibole-rich layers. The regional deformation presumably created the fluid channels thereby allowing the metasomatic fluid to enter the rock system. The above reaction has large negative volume change for solid phases indicating reaction-induced permeability. Thermodynamic calculations suggest that the fluid–rock interaction occurred at 665 ±05^°C and 6.6 ±0.25 kbar (corresponding to ～20 km depth). Textural modeling integrating the textural features and balanced chemical reaction of the calc-silicate rocks of Mesoproterozoic Phulad Shear Zone thus indicate that extremely channelled fluid flow was reaction enhanced and caused major change in the rock rheology.     

Thermogravimetric and model-free kinetic studies on CO<Subscript>2</Subscript> gasification of low-quality,high-sulphur Indian coals

Coal gasification with CO₂ has emerged as a cleaner and more efficient way for the production of energy, and it offers the advantages of CO₂ mitigation policies through simultaneous CO₂ sequestration. In the present investigation, a feasibility study on the gasification of three low-quality, high-sulphur coals from the north-eastern region (NER) of India in a CO₂ atmosphere using thermogravimetric analysis (TGA-DTA) has been made in order to have a better understanding of the physical and chemical characteristics in the process of gasification of coal. Model-free kinetics was applied to determine the activation energies (E) and pre-exponential factors (A) of the CO₂ gasification process of the coals. Multivariate non-linear regression analyses were performed to find out the formal mechanisms, kinetic model, and the corresponding kinetic triplets. The results revealed that coal gasification with CO₂ mainly occurs in the temperature range of 800^°–1400^°C and a maximum of at around 1100^°C. The reaction mechanisms responsible for CO₂ gasification of the coals were observed to be of the ‘nth order with autocatalysis (CnB)’ and ‘nth order (Fn) mechanism’. The activation energy of the CO₂ gasification was found to be in the range 129.07–146.81 kJ mol^?1.