U-Pb ages of uraniferous opals and implications for the history of beryllium,fluorine, and uranium mineralization at Spor Mountain,Utah

The U-Pb isotope systematics of uraniferous opals from Spor Mountain, Utah, were investigated to determine the suitability of such material for geochronologic purposes, and to estimate the timing of uranium and associated beryllium and fluorine mineralization. The results indicate that uraniferous opals can approximate a closed system for uranium and uranium daughters, so that dating samples as young as ～1 m.y. should be possible. In addition, the expected lack of initial²³⁰Th and²³¹Pa in opals permits valuable information on the initial²³⁴U/²³⁸U to be obtained on suitable samples of ?10 m.y. age. The oldest²⁰⁷Pb/²³⁵U apparent age observed, 20.8 ± 1m.y., was that of the opal-fluorite core of a nodule from a beryllium deposit in the Spor Mountain Formation. This age is indistinguishable from that of fission-track and K-Ar ages from the host rhyolite, and links the mineralization to the first episode of alkali rhyolite magmatism and related hydrothermal activity at Spor Mountain. Successively younger ages of 13 m.y. and 8–9 m.y. on concentric outer zones of the same nodule indicate that opal formed either episodically or continuously for over 10 m.y. Several samples of both fracture-filling and massive-nodule opal associated with beryllium deposits gave²⁰⁷Pb/²³⁵U apparent ages of 13–16 m.y., which may reflect a restricted period of mineralization or perhaps an averaging of 21?and<13?m.y. periods of opal growth. Several samples of fracture-filling opal in volcanic rocks as young as 6 m.y. gave²⁰⁷Pb/²³⁵U ages of 3.4–4.8 m.y. These ages may reflect hot-spring activity after the last major eruption of alkali rhyolite.     

A detailed study of the distribution of heat flow and radioactivity in New Hampshire (U.S.A.)

We present a set of 39 new determinations of heat flow and radiogenic heat production for several different geological environments in the State of New Hampshire (U.S.A.). With the extensive data set now available for the state, the linear relation of heat flow and heat production appears as a very useful generalization for the study of the heat flow field of a geological province. Our measurements indicate that the vertical distribution of radiogenic heat production is similar in plutonic and metasedimentary rocks. Our data are compatible with the linear relationship established earlier by F. Birch and his co-workers in 1968. Young granites are markedly enriched in radioactive elements and those which do not outcrop are revealed by anomalies in the general relation of heat flow versus radioactivity.Heat flow is high for plutons by low elsewhere. The mean heat flow through metasedimentary formations is 1.15 μcal/cm² s (48 mW/m²), a value near the mean heat flow for old cratons. The lowest heat flow measured is 0.76 μcal/cm² s (32 mW/m²) for a unit poor in radioactivity. The heat flow field grades smoothly into the low heat flow regions of the Canadian Shield.The New Hampshire region is in thermal equilibrium: its heat flow is in secular equilibrium with the heat generated by crustal sources and that supplied from the mantle. In this area, the thermal perturbations due to orogenic events decrease below the detection level in less than 200–275 Ma. The thickness of the layer which is thermally affected during continent-continent collision-type orogenies cannot be greater than about 190 km.     

Kapati Island,a natural area in demand: Assessing social impacts

Kapiti Island Nature Reserve is an example of a fully protected natural area that is under pressure for increasing visitor access. Present restrictions on visitor numbers to this bird sanctuary provided for a controlled setting which was used as a case study in social impact assessment. The aim was to develop methods of monitoring visitors' perceptions of social impacts, and to establish an appropriate carrying capacity. Visitor experiences were first explored by using qualitative methods. Second, items based on these qualitative data were then used to define quantitative data and validate measures and procedures. The wider application of this research is the development of methods of assessment relevant to other natural areas which are also coming under pressure from growing domestic and international visitation.     

Sedentary urchins influence benthic community composition below the macroalgal zone

Sea urchins are important ecosystem engineers in subtidal ecosystems worldwide, providing biogenic structure and altering nutrient dynamics through intensive grazing and drift algal capture. The current work evaluates red urchin (Strongylocentrotus franciscanus) density on fixed transects through time, individual displacement, and urchin‐associated benthic community composition using a field‐based approach at multiple depths (in and outside of the macroalgal zone) and replicated across sites in the San Juan Archipelago, Washington. Urchins exhibited no large‐scale, temporal or directional changes in density among depths. Furthermore, 87% of individual urchins observed in repeated small‐scale surveys over 3 weeks exhibited no change in position. Individual displacement was negatively correlated to drift algal capture. Evidence of sedentary behavior from the displacement surveys was supported by the sessile and mobile community composition in areas directly under versus adjacent to (control) urchins. The benthos under urchins had a higher percentage of bare space, crustose coralline algae, and increased density of snails, crabs and shrimp relative to associated control plots. Abundance of mobile organisms associating with urchins increased relative to control plots at the deepest survey depth (30 m), indicating a greater strength of interaction with distance from macroalgal production. This work presents evidence of food availability‐related behavior in red urchins and indicates that even when sedentary, urchins have a strong influence on ecosystem structure through increasing availability of shelter and macroalgal detritus to the benthos.     

Evidence of free convection in groundwater: Field-based measurements beneath wind-tidal flats

Free convection caused by salinity differences had not been conclusively detected or measured in the field. A field experiment at wind-tidal flats on Padre Island National Seashore, Texas, documents salinity-driven free convection with both direct (head and salinity data) and indirect (time-lapse 3-D resistivity) methods. Evaporative concentration of groundwater near the water table created unstable inverted density gradients, reduced groundwater levels, and reversed hydraulic gradients. These factors allowed plumes or fingers of more saline, denser fluid to flow downward into less-dense fluid as observed in monitoring wells and 3-D surveys. The development of density inversions can overcome the dissipating forces of dispersion and diffusion to create a sufficiently large unstable gradient to induce free convection. The development of free convective flow of variable-density fluids in groundwater can be detected and monitored through field techniques.     

U–Pb dating of zircon in hydrothermally altered rocks as a correlation tool: Application to the Mangakino geothermal field,New Zealand

Recognition and correlation of rock units within geothermal fields is often hampered by high degrees of alteration that obscure primary mineralogies and lithological boundaries, and preclude direct dating by radiometric techniques. Magmatic zircons are commonly present in silicic volcanic rocks, where zircon saturation was achieved and zircons crystallized up to the point of eruption. Young zircons are highly resistant to hydrothermal alteration and can yield a record of their crystallization ages in otherwise heavily altered rocks. Zircon crystallization-age spectra have been obtained by SIMS techniques (SHRIMP-RG) from three samples of cuttings and a core sample from ignimbrite penetrated in 3 drillholes up to ~ 3.2 km deep at the Mangakino geothermal field in New Zealand. The crystallization ages are similar between the drillcore and cutting samples, indicating that downhole mixing of cuttings has not been important, and showing collectively that volcanic units of closely similar ages are represented between ~ 1.4 and ~ 3.2 km depth. This is despite apparent changes in the inferred primary volcanic lithology that had led to earlier inferences that multiple ignimbrites of contrasting age were present in this depth interval. Comparisons of zircon crystallization-age spectra and inferred primary mineralogical characteristics from the drillhole samples with surficial ignimbrites that crop out west of Mangakino suggest that the boreholes have entered a > 1.8-km-thick intracaldera fill of ignimbrite generated in the closely-spaced Kidnappers and Rocky Hill eruptions at ~ 1 Ma.     

Radium and radon radioisotopes in regional groundwater, intertidal groundwater, and seawater in the Adelaide Coastal Waters Study area: Implications for the evaluation of submarine groundwater discharge

The input of groundwater-borne nutrients to Adelaide's (South Australia) coastal zone is not well known but could contribute to the ongoing decline of seagrass in the area. As a component of the Adelaide Coastal Waters Study (ACWS), the potential for using the radium quartet (²²³Ra, ²²⁴Ra, ²²⁶Ra and ²²⁸Ra) and ²²²Rn to evaluate submarine groundwater discharge (SGD) was evaluated. Potential isotopic signatures for SGD were assessed by sampling groundwater from three regional aquifers potentially contributing SGD to the ACWS area. In addition, intertidal groundwater was sampled at two sand beach sites. In general, the regional groundwaters were enriched in long-lived Ra isotopes (²²⁶Ra and ²²⁸Ra) and in ²²²Rn relative to intertidal groundwater. Radium activity (but not ²²²Rn activity) was positively correlated to salinity in groundwater from one of the regional aquifers and in intertidal groundwater. Radium isotope ratios (²²³Ra/²²⁶Ra, ²²⁴Ra/²²⁶Ra and ²²⁸Ra/²²⁶Ra) were less variable than individual Ra isotope activities within potential SGD sources. Recirculated seawater (estimated from the intertidal groundwater samples with seawater-like salinities) also had distinctly higher Ra isotope ratios than the regional groundwaters. The activities for all radioisotopes were relatively low in seawater. The activity of the short-lived ²²³Ra and ²²⁴Ra were highest at the shoreline and declined exponentially with distance offshore. In contrast, ²²⁸Ra and ²²⁶Ra activities had a weak linear declining trend with distance offshore. Rn-222 activity was at or near background in all seawater samples. The pattern of enrichment in short-lived Ra isotopes and the lack of ²²²Rn in seawater suggest that seawater recirculation is the main contributor to SGD in the ACWS area. Preliminary modeling of the offshore flux of ²²⁸Ra and ²²⁶Ra suggest that the SGD flux to the ACWS area ranges between 0.2 and 3 · 10^− 3 m³ (m of shoreline)^− 1 s^− 1.     

Genesis of yellow manganese-rich elbaite from the Canary mining area,Lundazi, Zambia

The most important source of yellow gem elbaite is the Canary mining area in the Lundazi District of eastern Zambia. The tourmaline has been mined since 1983 from both pegmatite and eluvial/alluvial deposits, in colors typically ranging from yellow-green to yellow to orange and brown; much of the orange-to-brown material is heated to attain a ‘golden’ or ‘canary’ yellow color. The elbaite is Mn-rich (up to 9.18 wt% MnO documented in the literature) and contains small amounts of Ti and little or no Fe. The distinctive composition of this tourmaline is probably the result of the early crystallization of abundant schorl from an unusual B-rich, Li-poor pegmatite melt, which depleted Fe while conserving Mn until the late-stage crystallization of gem pockets. The simple mineralogy of the pegmatite consists of feldspars, quartz, and tourmaline; the lack of micas, phosphates, or Li minerals, and the presence of very little garnet, allowed Mn to fractionate to high levels during pegmatite crystallization. The presence of abundant gem tourmaline in a Li-poor pegmatite is highly unusual.