http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

Searching for (un)sustainabilty in pangasius aquaculture: A political economy of quality in European retail

Drawing on a political economy of food quality, this paper investigates the main sources of uncertainty over the environmental sustainability of Vietnamese pangasius catfish in European markets and how retailers subsequently respond to these uncertainties. Based on media survey and interviews with supermarket retailers across Europe between 2008 and 2010, the analysis focuses on the claims and counterclaims over the sustainability of pangasius aquaculture, how retailers have dealt with the uncertainty these claims have engendered about the fish, and what effect this uncertainty has had on the potential of marketing ‘sustainable pangasius’ in European supermarkets. The paper concludes that successful claims around new food qualities like sustainability by retailers are dependent on the ability of regulatory networks to overcome any perceived illegitimacy of imported products in the face of continuing uncertainty and the wider politics of market protectionism.     

Gold solubility in oxidized and reduced, water-saturated mafic melt

We have performed experiments to evaluate Au solubility in natural, water-saturated basaltic melts as a function of oxygen fugacity. Experiments were carried out at 1000 °C and 200 MPa, and oxygen fugacity was controlled at the fayalite-magnetite-quartz (FMQ) oxygen fugacity buffer and FMQ + 4. All experiments were saturated with a metal-chloride aqueous solution loaded initially as a 10 wt% NaCl eq. fluid. The stable phase assemblage at FMQ consists of basalt melt, olivine, clinopyroxene, a single-phase aqueous fluid, and metallic Au. The stable phase assemblage at FMQ + 4 consists of basalt melt, clinopyroxene, magnetite-spinel solid solution, a single-phase aqueous fluid, and metallic Au. Silicate glasses (i.e., quenched melt) and their contained crystalline material were analyzed by using both electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Measured Au concentrations in the quenched melt range from 4.8 μg g⁻¹ to 0.64 μg g⁻¹ at FMQ + 4, and 0.54 μg g⁻¹ to 0.1 μg g⁻¹ at FMQ. The measured solubility of Au in olivine and clinopyroxene was consistently below the LA-ICP-MS limit of detection (i.e., 0.1 μg g⁻¹). These melt solubility data place important limitations on the dissolved Au content of water-saturated, Cl- and S-bearing basaltic liquids at geologically relevant fO₂ values. The new data are compared to published, experimentally-determined values for Au solubility in dry and hydrous silicate liquids spanning the compositional range from basalt to rhyolite, and the effects of melt composition, oxygen fugacity, pressure and temperature are discussed.     

Geochemical studies in the drainage basin of the Rio Vouga,Portugal. IV. Impact of land use on the hydrogeochemistry of natural waters in the Vouzela region

A hydrogeochemical study of the impact of land use on the composition of natural waters in the Vouzela region in northern Portugal was carried out during the summer of 1983. Water samples were collected from spring and major streams in the area and analyzed for major constituents and some trace elements. Analysis of variance and subsequent pairwise contrast tests demonstrated that waters from agricultural areas are significantly enriched in constiluents such as Na, K, Ca, Mg, Sr, Cl, SO₄, and NO₃. High concentrations of these ions in agricultural areas are the result of both the application of fertilizers and enhanced evaporation by the intensive irrigation of agricultural lands. Constitutents such as H₄SiO₄, HCO₃, F, and probably Li, which are typically related to mineral weathering, were not affected by land use. In waters from forested areas the concentration of most constituents was about 20% higher than in waters from uncultivated areas with mainly a grass cover. This reflects the difference in the evapotranspiration of these two vegetation types. The chemistry of the Rio Zela clearly reflects differences in land use in the Rio Zela valley.     

Regional modelling of permafrost thicknesses over the past 130 ka: implications for permafrost development in Great Britain

The greatest thicknesses of permafrost in Great Britain most likely occurred during the last glacial–interglacial cycle, as this is when some of the coldest conditions occurred during the last 1 000 000 years. The regional development of permafrost across Great Britain during the last glacial–interglacial cycle was modelled from a ground surface temperature history based on mean annual temperatures and the presence of glacier ice. To quantify the growth and decay of permafrost, modelling was undertaken at six locations across Great Britain that represent upland glaciated, lowland glaciated, upland unglaciated and lowland unglaciated conditions. Maximum predicted permafrost depths derived in this academic study range between several tens of metres to over 100 m depending upon various factors including elevation, glacier ice cover, geothermal heat flux and air temperature. In general, the greatest maximum permafrost thicknesses occur at upland glaciated locations, with minimum thickness at lowland sites. Current direct geological evidence for permafrost is from surface or shallow processes, mainly associated with the active layer. Further research is recommended to identify the imprint of freeze/thaw conditions in permanently frozen porous rocks from beneath the active layer.     

Temperature–composition–time (T–X–t) data from authigenic K-feldspar: An integrated methodology for dating fluid flow events

Integration of fluid inclusion analysis with high spatial resolution Ar–Ar dating of K-feldspar cements has been used to resolve and reconstruct palaeo-fluid flow. Fluid inclusion analysis allows discrimination of distinct cement phases, thereby identifying discrete episodes of fluid flow. Ar–Ar dating of the same cements via high spatial resolution laserprobe establishes absolute age constraints on the framework previously constructed. Integration of these two datasets yields temperature–composition–time data.     

Mo isotope fractionation during adsorption to Fe (oxyhydr)oxides

Molybdenum (Mo) isotopes have great potential as a paleoredox indicator, but this potential is currently restricted by an incomplete understanding of isotope fractionations occurring during key (bio)geochemical processes. To address one such uncertainty we have investigated the isotopic fractionation of Mo during adsorption to a range of Fe (oxyhydr)oxides, under variable Mo/Fe-mineral ratios and pH. Our data confirm that Fe (oxyhydr)oxides can readily adsorb Mo, highlighting the potential importance of this removal pathway for the global Mo cycle. Furthermore, adsorption of Mo to Fe (oxyhydr)oxides is associated with preferential uptake of the lighter Mo isotopes. Fractionations between the solid and dissolved phase (Δ⁹⁸Mo) increase at higher pH, and also vary with mineralogy, increasing in the order magnetite (Δ⁹⁸Mo = 0.83 ± 0.60‰) < ferrihydrite (Δ⁹⁸Mo = 1.11 ± 0.15‰) < goethite (Δ⁹⁸Mo = 1.40 ± 0.48‰) < hematite (Δ⁹⁸Mo = 2.19 ± 0.54‰). Small differences in isotopic fractionation are also seen at varying Mo/Fe-mineral ratios for individual minerals. The observed isotopic behaviour is consistent with both fractionation during adsorption to the mineral surface (a function of vibrational energy) and adsorption of different Mo species/structures from solution. The different fractionation factors determined for different Fe (oxyhydr)oxides suggests that these minerals likely exert a major control on observed natural Mo isotope compositions during sediment deposition beneath suboxic through to anoxic (but non-sulfidic) bottom waters. Our results confirm that Mo isotopes can provide important information on the spatial extent of different paleoredox conditions, providing they are used in combination with other techniques for evaluating the local redox environment and the mineralogy of the depositing sediments.     

Predisposition and cause of the catastrophic landslides of August 2005 in Brienz (Switzerland)

Very intensive rainfall in August 2005 (>300 mm/3 days) triggered moderately deep (2–10 m) landslides of about 50'000 m³ volume each in two mountain torrent catchments above the village of Brienz (Berner Oberland, Switzerland). These landslides – originating in Trachtbach and Glyssibach catchments – transformed into extremely rapid (>5 m/s) debris flows, which caused significant damage in inhabited areas; two persons lost their lives and about twenty-five families became homeless. The Brienz case was the most damaging one among many landslide disasters occurring during those rainy days in the Swiss Alps. In this paper we study in detail the predisposition and causes of the 2005 landslides in the Brienz area, based on field mapping, analysis of high resolution images and digital terrain models, derived from LIDAR and infrared measurements taken before and after the event. The features of these landslides are compared with past and dormant landslides in the mid-slope portion of the mountain chain north of Brienz, which has been the source of many catastrophic mass wasting events during the last centuries. Detailed field mapping shows that highly weathered series of strongly overconsolidated Mesozoic marls (Diphyoides Limestone & Vitznau Marls of Valanginian age) and their residual soils form the primary source for the sliding materials. The rupture surfaces of the moderately deep landslides often run at the transition from saprolite to weathered bedrock, with a dip angle of about 40o in the landslide depletion area. These landslides transform into debris flows, where debris slides into strongly convergent hillslopes or directly into headwater channels.