Microstructure and geochemistry of plagioclase and microcline in naturally deformed granite

Naturally deformed feldspars from foliated granites in a shear zone in Newfoundland exhibit transitional brittle-ductile behaviour. Brittle failure is subordinate to dynamic recrystallization, microcracking, strain enhanced diffusion and reaction enhanced ductility during the deformation. Both plagioclase (An₂₈) and K-feldspar are transformed to albite with increasing strain. Interaction of metamorphic and structural processes at the grain scale is emphasised. This is illustrated with examples of quartz-filled veins (segregation bands) in plagioclase and recrystallized polycrystalline aggregates in plagioclase and K-feldspar. The role of microcracking in plagioclase and of pre-existing internal growth structures in the formation of initially coarse grained recrystallized aggregates from large single crystals is suggested.     

Experimental hydrogen isotope studies—I. Systematics of hydrogen isotope fractionation in the systems epidote-H2O,zoisite-H2O and AlO(OH)-H2O

$\text{H}\text{D}$ Fractionation factors between epidote minerals and water, and between the AlO(OH) dimorphs boehmite and diaspore and water, have been determined between 150 and 650°C. Small water mineral ratios were used to minimise the effect of incongruent dissolution of epidote minerals. Waters were extracted and analysed directly by puncturing capsules under vacuum. Hydrogen diffusion effects were eliminated by using thick-walled capsules.$\text{H}\text{D}$ Exchange rates are very fast between epidote and water (and between boehmite and water), complete exchange taking only minutes above 450°C but several months at 250°C. Exchange between zoisite and water (and between diaspore and water) is very much slower, and an interpolation method was necessary to determine fractionation factors at 450 and below.For the temperature range 300–650°C, the $\text{H}\text{D}$ equilibrium fractionation factor (α^e) between epidote and water is independent of temperature and Fe content of the epidote, and is given by 1000 In α_epidote-H2O^e = ?35.9 ± 2.5, while below 300°C 1000 In , with a ‘cross-over’ estimated to occur at around 185°C. By contrast, zoisite-water fractionations fit the relationship 1000 In .All studied minerals have hydrogen bonding. Fractionations are consistent with the general relationship: the shorter the O-H -- O bridge, the more depleted is the mineral in D.On account of rapid exchange rates, natural epidotes probably acquired their H-isotope compositions at or below 200°C, where fractionations are near or above 0%.; this is in accord with the observation that natural epidotes tend to concentrate D relative to other coexisting hydrous minerals.     

Isotopic geochemistry (O,Sr, Pb) of the Golda Zuelva and Mboutou anorogenic complexes,North Cameroun: mantle origin with evidence for crustal contamination

The annular (6–8 km diameter) Golda Zuelva and Mboutou anorogenic complexes of North Cameroun are composed of a suite of alkaline plutonic rocks ranging from olivine gabbro to amphibole and biotite granite. For the Mboutou complex there are two overlapping centres. In the Golda Zuelva complex the plutonic rocks are associated with a later hawaiite to rhyolite volcanic suite. A Rb/Sr whole rock isochron gives an age of 66±3 Ma for the Golda Zuelva granites, with initial⁸⁷Sr/⁸⁶Sr ratio of 0.7020, and demonstrates that plutonism and volcanism were essentially contemporaneous and probably cogenetic. For Golda Zuelva and the north Mboutou centre¹⁸O/¹⁶O (5.6–6.2),⁸⁷Sr/⁸⁶Sr (0.7030–0.7045) and Pb isotopic ratios (²⁰⁷Pb/²⁰⁴Pb: 15.60–15.64) support a mantle origin for the initial magmas. Unlike Sr isotopes, the O isotopic ratios of the granitic end members at Golda Zuelva (～7.5) indicate crustal contamination. Post-magmatic alteration was not significant.For the younger south Mboutou centre the O-, Sr- and Pb-isotopic data indicate more extensive magma-crust interaction and in a different (higher level?) crustal environment with δ¹⁸O granite=3.3‰,⁸⁷Sr/⁸⁶Sr ratios up to 0.706 and Pb isotopic ratios more markedly displaced from the oceanic volcanic field. The low-¹⁸O granites probably record, at least in part, a magmatic process with subsequent minor post-magmatic alteration effects. The major and trace element systematics between the north and south Mboutou centres are directly comparable. The evolution of the magmas were dominated by fractional crystallisation and progressive crustal contamination processes.     

The use of soil geochemistry in outlining phosphate deposits, northern and southern Venezuela

Phosphate deposits have been outlined in Falcón State (Northern Venezuela) and Táchira State (Southwestern Venezuela) using geochemical soil methods.The phosphate deposits located in Falcón State constitute lenses and masses interbedded with Tertiary limestone and shales. The area is covered by a thick soil with few outerops and the region is characterized by typical tropical rain forest. Soil samples taken every 1000 m across complete stratigraphic sequences were analyzed for P₂O₅ content. An anomalous area with a P₂O₅ content ranging from 3.19% to 9.04% was outlined accompanied by areas with less than 0.83% of P₂O₅. More than 11 million metric tons of commercial phosphatic rock were associated with this anomaly.In Táchira State several stratigraphic sequences of potentially phosphatic rocks with a thick cover of black soil were geochemically investigated. Soil samples taken each 10 m were analyzed for P₂O₅. A sequence of phosphatic rock was outlined showing a P₂O₅ content varying between 7.3% and 9.2%. Apparently the sequence is interbedded with phosphate-poor siliceous rocks showing a P₂O₅ content below 2%.As result of this preliminary investigation, expensive trenching, pitting and drilling works can be carefully planned.     

On the black cotton soils of North Cameroon

During detailed geotechnical prospecting in North Cameroon, extensive black cotton soil deposits were encountered. Based on classification tests, three samples were selected for mineralogical analysis. The results indicated that the predominant clay mineral was the halloysite governing the geotechnical properties and behaviour of the cotton soils. New correlations were established between clay mineral content and Atterberg limits of the investigated materials.     

Use of lateritic soils for road construction in North Dahomey

Due to the deterioration of the Parakou—Malanville highway, the preparation of a rehabilitation program was necessary. The related geotechnical exploration provided an excellent opportunity to study the properties of the encountered lateritic soils. The mineralogical analysis proved that the lateritic overburden originates from the local rocks. However, the analyses also indicated that the soils can only be identified as lateritic by virtue of their hematite content. The soils were classified according to the AASHO-system and their geotechnical properties were thoroughly investigated. The results revealed that the overwhelming majority of the available soils was unsuitable for highway construction due to their high plasticity. In order to improve them, cement stabilization was suggested. The laboratory tests resulted in an economically feasible solution.     

Emission lines in the spectra of southern long-period variables

Quantitative measures are presented for the intensity of emission features in the spectra of 32 southern red variables.     

Applications of graph theory to gross error detection for GPS geodetic control networks

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Geochronological constraints on Paleoarchean thrust-nappe and Neoarchean accretionary tectonics in southern West Greenland

Major regional deformation and metamorphic events in the Godthåbsfjord region, southern West Greenland, occurred at 3650 and 2820–2720 Ma (e.g. Precambrian Res. 78 (1996) 1). New geochronological constraints (U–Pb zircon, Sensitive High Resolution Ion Microprobe [SHRIMP] and thermal ionisation mass spectrometry [TIMS]) have been obtained from a stack of mylonitic, crystalline thrust-nappes in the footwall of the western part of the Paleoarchean (3.8–3.7 Ga) Isua Greenstone Belt, Isukasia. A mylonitic tonalite sheet, interpreted to have intruded synkinematically with respect to mylonitisation, yields a magmatic crystallisation age of 3640±3 Ma. A cross-cutting pegmatite and a post-kinematic tonalite pluton yield magmatic crystallisation ages of 2948±8 and 2991±2 Ma, respectively. Accordingly, we interpret the thrust-nappe stack to have formed during the Paleoarchean (3640 Ma), making it the oldest example known on Earth. The similarity of this structural regime to that of modern mountain belts suggests that Paleoarchean and modern continental crust were comparable in terms of mechanical strength and constitution.Southern West Greenland has been interpreted in terms of Neoarchean accretion, comparable with modern plate tectonics (e.g. Earth Planet. Sci. Lett. 142 (1996) 353). Isukasia lies just east of a purported Neoarchean accretionary boundary between the Akia terrane to the Northwest and the Akulleq terrane to the Southeast. The Akia terrane was previously considered to overthrust the Akulleq terrane at 2820–2720 Ma. Our geochronological and geological data indicate (i) that the two “terranes”, as presently defined, were stitched at 2991±2 Ma and (ii) that thrusting across the boundary was directed toward the Akia terrane. Therefore, we suggest that the Akia–Akulleq interface was not a fundamental tectonic structure during the Neoarchean, and we question its identification as an accretionary boundary.     

Geology and timing of mineralization at the Cangshang gold deposit,north-western Jiaodong Peninsula,China

Mineralium Deposita - The Cangshang gold deposit of the north-western Jiaodong Peninsula contains reserves of greater than 50&;nbsp;tonnes (t) and is developed by the largest open pit gold mine...