Distinguishing extensive and intensive properties for meaningful geocomputation and mapping

A most fundamental and far-reaching trait of geographic information is the distinction between extensive and intensive properties. In common understanding, originating in Physics and Chemistry, extensive properties increase with the size of their supporting objects, while intensive properties are independent of this size. It has long been recognized that the decision whether analytical and cartographic measures can be meaningfully applied depends on whether an attribute is considered intensive or extensive. For example, the choice of a map type as well as the application of basic geocomputational operations, such as spatial intersections, aggregations or algebraic operations such as sums and weighted averages, strongly depend on this semantic distinction. So far, however, the distinction can only be drawn in the head of an analyst. We still lack practical ways of automation for composing GIS workflows and to scale up mapping and geocomputation over many data sources, e.g. in statistical portals. In this article, we test a machine-learning model that is capable of labeling extensive/intensive region attributes with high accuracy based on simple characteristics extractable from geodata files. Furthermore, we propose an ontology pattern that captures central applicability constraints for automating data conversion and mapping using Semantic Web technology.     

Gold partitioning in melt-vapor-brine systems

We used laser-ablation inductively coupled plasma mass spectrometry to measure the solubility of gold in synthetic sulfur-free vapor and brine fluid inclusions in a vapor + brine + haplogranite + magnetite + gold metal assemblage. Experiments were conducted at 800°C, oxygen fugacity buffered at Ni-NiO (NNO), and pressures ranging from 110 to 145 MPa. The wt% NaCl eq. of vapor increases from 2.3 to 19 and that of brine decreases from 57 to 35 with increasing pressure. The composition of the vapors and brines are dominated by NaCl + KCl + FeCl₂ + H₂O. Gold concentrations in vapor and brine decrease from 36 to 5 and 50 to 28 μg/g, respectively, and the calculated vapor:brine partition coefficients for gold decrease from 0.72 to 0.17 as pressure decreases from 145 to 110 MPa. These data are consistent with the thermodynamic boundary condition that the concentration of gold in the vapor and brine must approach a common value as the critical pressure is approached along the 800°C isotherm in the NaCl-KCl-FeCl₂-HCl-H₂O system.We use the equilibrium constant for gold dissolution as AuOH⁰, extrapolated from lower temperature and overlapping pressure range, to calculate expected concentrations of AuOH⁰ in our experimental vapors. These calculations suggest that a significant quantity of gold in our experimental vapors is present as a non-hydroxide species. Possible chloridogold(I) species are hypothesized based on the positively correlated gold and chloride concentrations in our experimental vapors. The absolute concentration of gold in our synthetic vapor, brine, and melt and calculated mass partition coefficients for gold between these physicochemically distinct magmatic phases suggests that gold solubility in aqueous fluids is a function of aqueous phase salinity, specifically total chloride concentration, at magmatic conditions. However, though we highlight here the effect of salinity, the combination of our data with data sets from lower temperatures evinces a significant decrease in gold solubility as temperature drops from 800°C to 600°C. This decrease in solubility has implications for gold deposition from ascending magmatic fluids.     

基于GPlates平台的“深时”板块构造重建：数据库现状与应用实例

板块构造重建是大地构造领域一项关键的研究工作,是构建"深时数字地球"(Deep-time Digital Earth, DDE)的重要途径。板块重建工作需要整合地球科学多个研究领域、海量的数据,同时又是地球动力学和气候模拟等研究的重要约束条件。因此,追踪目前国际主流的板块重建所需的数据库以及板块重建工具的最新进展和应用为了解板块重建研究的前沿提供全面的信息。文章系统介绍了支持板块构造重建研究的多个主流数据库,着重描述数据库的数据格式、数据获取方式及数据如何支持基于GPlates平台的板块构造重建。为了阐述大地构造研究相关数据库在板块重建研究中的应用,此次研究从板块构造重建的三个不同层次出发,列举了多个最新的板块重建模型及其在探索地球系统演化方面的意义。最后,结合DDE项目的相关任务,对250 Ma以来全球板块构造和变形的演化、量化大地构造在地球系统演化中的作用、超大陆旋回中的古大陆和古海洋构造重建以及前中生代(250 Ma)全球板块运动模型重建这四个关键科学问题作出了新的展望。     

Formation of refractory inclusions by evaporation of condensate precursors

Berman’s (1983) activity-composition model for CaO-MgO-Al₂O₃-SiO₂ liquids is used to calculate the change in bulk chemical and isotopic composition during simultaneous cooling, evaporation, and crystallization of droplets having the compositions of reasonable condensate precursors of Types A and B refractory inclusions in CV3 chondrites. The degree of evaporation of MgO and SiO₂, calculated to be faithfully recorded in chemical and isotopic zoning of individual melilite crystals, is directly proportional to evaporation rate, which is a sensitive function of P_H2, and inversely proportional to the droplet radius and cooling rate. When the precursors are partially melted in pure hydrogen at peak temperatures in the vicinity of the initial crystallization temperature of melilite, their bulk chemical compositions evolve into the composition fields of refractory inclusions, mass-fractionated isotopic compositions of Mg, Si, and O are produced that are in the range of the isotopic compositions of natural inclusions, and melilite zoning profiles result that are similar to those observed in real inclusions. For droplets of radius 0.25 cm evaporating at P_H2 = 10⁻⁶ bar, precursors containing 8 to 13 wt.% MgO and 20 to 23% SiO₂ evolve into objects similar to compact Type A inclusions at cooling rates of 2 to 12 K/h, depending on the precise starting composition. Precursors containing 13 to 14 wt.% MgO and 23 to 26% SiO₂ evolve into objects with the characteristics of Type B1 inclusions at cooling rates of 1.5 to 3 K/h. The relatively SiO₂-poor members of the Type B2 group can be produced from precursors containing 14 to 16 wt.% MgO and 27 to 33% SiO₂ at cooling rates of <1 K/h. Type B2’s containing 27 to 35 wt.% SiO₂ and <12% MgO require precursors with higher SiO₂/MgO ratios at MgO > 15% than are found on any condensation curve. The characteristics of fluffy Type A inclusions, including their reversely zoned melilite, can only be understood in the context of this model if they contain relict melilite.     

The geochemistry of primary and weathered oil shale and coquina across the Julia Creek vanadium deposit (Queensland, Australia)

A significant resource of vanadium and molybdenum exists near Julia Creek, Australia, where the middle Cretaceous organic-rich Toolebuc Formation lies between 0 and 25 m of the surface. We present and discuss a comprehensive geochemical study of the Toolebuc Formation and its enclosing stratigraphy near Julia Creek to understand this ore deposit. V and Mo contents in fresh facies are strongly associated with total organic carbon (TOC) contents, but not with Al or CaCO₃; this suggests that V and Mo were originally concentrated in the organic fraction. However, chemical extractions using H₂O₂ indicate that Mo was originally concentrated in pyrite. The data also suggest that V was mobilised from organic matter during early diagenesis and became associated with clays as little V was extracted by H₂O₂ in the fresh samples. TOC contents in the Toolebuc Formation were removed during weathering, residually enriching trace metals including V and Mo, and as a result, the TOC relationship with V and Mo disintegrates. With weathering, both V and Mo predominantly became associated with iron oxide/hydroxide phases (and possibly other unidentified phases) as these elements in the weathered facies were highly soluble in the sodium citrate–sodium dithionite digestion. Large shale-hosted V and Mo deposits such as Julia Creek offer a potentially viable alternative to the currently mined magnetite-hosted deposits. A thorough understanding of the formation and host mineral phases for V and Mo of these shale deposits, however, is critical to ensure that these valuable metals can be feasibly extracted.     

Pn arrivals and lateral variations of Moho geometry beneath the Kaapvaal craton

Pn arrivals from mining-induced earthquakes on the edge of the Witwatersrand basin show that the P wavespeeds in the uppermost mantle are almost constant throughout most of the Kaapvaal craton. The presence of only small wavespeed variations allows the use of a simple method of estimating crustal thicknesses below the stations of the Kaapvaal broad-band network using Pn times that has been compared with results from receiver functions. One thousand three hundred thirty-seven Pn arrivals were used to derive crustal thicknesses at 46 stations on the Kaapvaal craton. The average crustal thicknesses for 19 centrally located stations on each of the northern and southern regions of the craton that yielded well-constrained thicknesses were 50.52±0.88 km and 38.07±0.85 km, respectively. In contrast, the corresponding average thicknesses determined from receiver functions were 43.58±0.57 km and 37.58±0.70 km, respectively. The systematically lower values for receiver functions in the northern part of the Kaapvaal craton that was affected by the Bushveld magmatism at 2.05 Ga, suggest that the receiver functions do not enable the petrological crust mantle boundary to be reliably resolved due to variations in composition and metamorphic grade in a mafic lower crust. The Pn times also suggest pervasive azimuthal anisotropy with maximum wavespeeds of about 8.40 km/s at azimuths of about 15° and 217° in the northern and southern regions of the craton, respectively, and minimum wavespeeds of about 8.25 km/s.     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

Estimates for the luminosity function of galaxies and its evolution

A new method is presented to obtain a non-parametric maximum likelihood estimate of the luminosity function and the selection function of a flux-limited redshift survey. The method parametrizes the selection function as a series of stepwise power laws and allows possible evolution of the luminosity function. We also propose a new technique to estimate the rate of evolution of the luminosity function. This is based on a minimization of the observed large-scale power with respect to the evolutionary model. We use an ensemble of mock surveys extracted from an N -body simulation to verify the power of this method. We apply our estimators to the 1.2-Jy survey of IRAS galaxies. We find a far-infrared luminosity function in good agreement with previously published results and evidence for rather strong evolution. If the comoving number density of IRAS galaxies is assumed to scale ∝ (1 +  z ) ^P , we estimate P  = 4.3 ± 1.4.     

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.     

Paleoceanographic evolution of the SW Svalbard margin (76°N) since 20,000 C yr BP

Two cores from the southwestern shelf and slope of Storfjorden, Svalbard, taken at 389 m and 1485 m water depth have been analyzed for benthic and planktic foraminifera, oxygen isotopes, and ice-rafted debris. The results show that over the last 20,000 yr, Atlantic water has been continuously present on the southwestern Svalbard shelf. However, from 15,000 to 10,000 ¹⁴C yr BP, comprising the Heinrich event H1 interval, the Bølling-Allerød interstades and the Younger Dryas stade, it flowed as a subsurface water mass below a layer of polar surface water. In the benthic environment, the shift to interglacial conditions occurred at 10,000 ¹⁴C yr BP. Due to the presence of a thin upper layer of polar water, surface conditions remained cold until ca. 9000 ¹⁴C yr BP, when the warm Atlantic water finally appeared at the surface. Neither extensive sea ice cover nor large inputs of meltwater stopped the inflow of Atlantic water. Its warm core was merely submerged below the cold polar surface water.