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131.
David Völker Jacob Geersen Eduardo Contreras-Reyes Javier Sellanes Silvio Pantoja Wolfgang Rabbel Martin Thorwart Christian Reichert Martin Block Wilhelm Reimer Weinrebe 《International Journal of Earth Sciences》2014,103(7):1765-1787
The continental shelf and slope of southern Central Chile have been subject to a number of international as well as Chilean research campaigns over the last 30 years. This work summarizes the geologic setting of the southern Central Chilean Continental shelf (33°S–43°S) using recently published geophysical, seismological, sedimentological and bio-geochemical data. Additionally, unpublished data such as reflection seismic profiles, swath bathymetry and observations on biota that allow further insights into the evolution of this continental platform are integrated. The outcome is an overview of the current knowledge about the geology of the southern Central Chilean shelf and upper slope. We observe both patches of reduced as well as high recent sedimentation on the shelf and upper slope, due to local redistribution of fluvial input, mainly governed by bottom currents and submarine canyons and highly productive upwelling zones. Shelf basins show highly variable thickness of Oligocene-Quaternary sedimentary units that are dissected by the marine continuations of upper plate faults known from land. Seismic velocity studies indicate that a paleo-accretionary complex that is sandwiched between the present, relatively small active accretionary prism and the continental crust forms the bulk of the continental margin of southern Central Chile. 相似文献
132.
Silvio Mollo Pierdomenico Del Gaudio Guido Ventura Gianluca Iezzi Piergiorgio Scarlato 《Lithos》2010,118(3-4):302-312
The compositional variation of clinopyroxene and the partitioning of major elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from 1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H2O = 1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca, Mg, Fe2+ and Si and enriched in Na, Fe3+, Al (mainly AlIV), and Ti. Di and Hd versus CaTs and CaFeTs form a continuous binary solid solution characterized by higher amounts of tschermakitic components with increasing cooling rate. Two parameters (DH = Di + Hd and TE = CaTs + CaFeTs + En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions.Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of cpx–meltKdFe–Mg remain almost constant. Therefore, the Fe2–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic cooling magmas, giving rise to possible mismatches in the application of thermobarometers. The results of our study are consistent with that observed at the margin of dikes or in the exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found. 相似文献
133.
Pasquale Crea Concetta De Stefano Frank J. Millero Silvio Sammartano Virender K. Sharma 《Aquatic Geochemistry》2010,16(3):447-466
Oxidized glutathione (GSSG), which has four carboxylic and two amino groups, interacts with metal ions and may affect the
bioavailability and geochemistry of metals in natural waters. In the present paper, six stepwise protonation constants
K\textHi K^{\text{H}}_{i} for GSSG were measured as a function of salinity, S = 5–35‰ at t = 25°C (and in NaCl/MgCl2 mixtures at different ionic strengths), in order to provide thermodynamic data for their acid base properties, which are
useful for studying the interaction with metals in these media. The protonation enthalpies (ΔH
i
/kJ mol−1) were also determined at t = 25°C. The results were interpreted using the SIT model and Pitzer equations. The seawater model with the interaction parameters
accounts for the differences between the values in NaCl and seawater. The results suggest that it is important to consider
all of the ionic interactions in natural waters in examining the proton dissociation of GSSG. 相似文献
134.
The Serra da Graciosa Granites and Syenites comprise five distinct plutons in the Brasiliano/Pan-African Graciosa A-type Province, southern Brazil. Six petrographic series can be identified in these plutons: (1) Alkaline series 1, composed of amphibole-bearing alkali feldspar syenites with varied mafic mineralogy and quartz contents, from alkali feldspar syenites with calcic amphibole, clinopyroxene, olivine and allanite to alkali feldspar quartz syenites with sodic–calcic amphibole and chevkinite–perrierite and to alkali feldspar granites with sodic amphibole; (2) Alkaline series 2, characterized by amphibole-bearing alkali feldspar granites, with limited modal variations but amphibole compositions also varying from calcic to sodic; (3) Alkaline series 3, of limited occurrence, which includes alkali feldspar syenites with olivine and clinopyroxene and no amphibole; (4) Aluminous series 1, of widespread occurrence, with various petrographic facies of biotite granites with amphibole; (5) Aluminous series 2, characterized by alkali feldspar granites with biotite and only minor amphibole; (6) Monzodiorites, typically with biotite, calcic amphibole and augitic clinopyroxene, partially mingled with granitic magmas. The mafic minerals present are, in general, Fe-rich with correspondingly low Mg and Al contents. In Alkaline series 1, amphiboles crystallized in progressively more oxidizing and alkaline conditions, while in Alkaline series 2, the initial conditions were somewhat more oxidizing and shifted to reducing in the final stages. In Aluminous series 1 and Aluminous series 2, amphiboles are calcic and comparatively homogeneous. The amphiboles in the monzodioritic rocks, while also homogeneous, are more Mg-rich and show compositions quite distinct from the calcic varieties in the other associations, and this is also the case for clinopyroxene. Mg# in biotite decreases from the monzodioritic rocks to Aluminous series 1 and further to Aluminous series 2. Contrasting evolution of the various associations suggests that several coeval magmatic series are present in the Serra da Graciosa granites. 相似文献
135.
The global geological volatile cycle(H, C, N) plays an important role in the long term self-regulation of the Earth system. However, the complex interaction between its deep, solid Earth components(i.e. crust and mantle), Earth's fluid envelopes(i.e. atmosphere and hydrosphere) and plate tectonic processes is a subject of ongoing debate. In this study we want to draw attention to how the presence of primary melt(MI)and fluid(FI) inclusions in high-grade metamorphic minerals could help constrain the crustal component of the volatile cycle. To that end, we review the distribution of MI and FI throughout Earth's history, from ca. 3.0 Ga ago up to the present day. We argue that the lower crust might constitute an important, longterm, volatile storage unit, capable to influence the composition of the surface envelopes through the mean of weathering, crustal thickening, partial melting and crustal assimilation during volcanic activity.Combined with thermodynamic modelling, our compilation indicates that periods of well-established plate tectonic regimes at 0.85 Ga and 1.7–2.1 Ga, might be more prone to the reworking of supracrustal lithologies and the storage of volatiles in the lower crust. Such hypothesis has implication beyond the scope of metamorphic petrology as it potentially links geodynamic mechanisms to habitable surface conditions. MI and FI in metamorphic crustal rocks then represent an invaluable archive to assess and quantify the co-joint evolution of plate tectonics and Earth's external processes. 相似文献