Monitoring study of the mine pond reclamation of Mina Concepción, Iberian Pyrite Belt (Spain)

Mining of massive (Cu, Pb and Zn) sulphide bodies in the Iberian Pyrite Belt (SW Spain) has generated a great number of abandoned waste deposits such as mine ponds. These represent large accumulations of reactive minerals and subsequently, emission sources of trace elements and formation of acid drainage. Even if they have been restored, monitoring studies are required to evaluate the corrective effects and how they may change over time. This work presents the results of a monitoring study carried out at Mine Concepción mine pond, based on mineralogical (XRD), geochemical (INAA, X-ray fluorescence, ICP-MS) and geophysical (electrical resistivity tomography) techniques. In it, a series of relevant parameters have been well delimited, such as the infilling thickness and its variation and, the position, geometry and absence of water leakages through the base of the mine pond. Additionally, the existence of an internal, remnant flow of acid waters that tends to come out through the pond dyke has been identified. Chemistry of these waters indicates that oxidation processes affecting the Mina Concepción mine tailings are generating acid drainage waters which could potentially release substantial amounts of trace elements to the river Odiel. Thus, giving that not complete sealing is accomplished by the restoration capping and rainfall water infiltrates into the pond materials, at least the sealing of the dyke through which leakages occur should be revised.     

Tectonic and climatic control on the Late Messinian sedimentary evolution of the Nijar Basin (Betic Cordillera,Southern Spain)

The Late Messinian fill of the Nijar Basin (Betic Cordillera, southeastern Spain) mainly consists of clastic deposits of the Feos Formation that at basin margins rest unconformably above the primary evaporites of the Yesares Formation, the local equivalent of the Mediterranean Lower Gypsum. The Feos Fm. records the upward transition towards non‐marine environments before the abrupt return to fully marine conditions at the base of the Pliocene. The Feos Fm. is clearly two‐phase, with ‘lower’ and ‘upper’ members, which exhibit substantial differences in terms of facies, thickness, depositional trends and cyclical organization. These members record two distinct sedimentary and tectonic stages of Nijar Basin infilling. A high‐resolution, physical‐stratigraphic framework is proposed based on key beds and stratigraphic cyclicity and patterns that differ largely from those of most previously published studies. The predominant influence on stratigraphic cyclicity is interpreted to be precessionally driven climate changes, allowing their correlation to the Late Messinian astronomically calibrated chronostratigraphic framework. Detailed correlations suggest a phase of enhanced tectonic activity, possibly related to the Serrata‐Carboneras strike‐slip fault zone, during the first stage (‘lower’ member), resulting in a strongly articulated topography with structural lows and highs controlling sediment thickness and facies variation. Tectonic activity decreased during the second stage (‘upper’ member), which is characterized by (1) a progressively dampened and homogenized, (2) overall relative base‐level rise and (3) gradual establishment of hypohaline environments. Facies characteristics, overall stacking patterns and depositional trends of the Feos Fm. are analogous with uppermost Messinian successions of the Northern Apennines, Piedmont Basin and Calabria. Despite minor differences related to the local geodynamic setting, these basins experienced a common Late Messinian history that supports the development of a single, large Mediterranean water body characterized by high‐frequency, climatically‐driven changes in sediment flux and base‐level.     

Cambro-Ordovician Magmatism in SE Brazil: U-Pb and Rb-Sr Ages, Combined with Sr and Nd Isotopic Data of Charnockitic Rocks from the Varzea Alegre Complex

In the central-southern region of Espírito Santo State, southeastern Brazil, several granitoids with a variable composition intruded high-grade metamorphic rocks, in the northern segment of the Ribeira fold belt. A close relationship between hydrous and anhydrous facies is present in some of the plutons, including the Varzea Alegre Igneous Complex, which has an inner domain formed by gabbro, diorite and granite, and an irregular outer ring of charnockitic rocks. These green megaporphyritic charnockites have primary anhydrous mineral assemblage, I-type and metaluminous character, and high-K calc-alkaline signature. U-Pb zircon single crystal ages obtained by TIMS indicate crystallization at about 500 Ma, similar to other late tectonic plutons of this part of the Ribeira belt. Sr and Nd isotopic ratios ranging from 0.7078 to 0.7096 and 0.5114 to 0.5116 respectively, are interpreted to be indicative of a hybrid origin from crustal and mantle-derived magmas. A binary diagram using Sr isotope ratios also demonstrates that the genesis of the charnockites probably included both magma mixing and fractional crystallization processes.     

Design,test and analysis of a light‐weight dissipative bracing system for seismic protection of structures

The paper deals with the proposal and the experimental validation of a novel dissipative bracing system for the seismic protection of structures; compared with other similar systems, it is characterized by smaller size and weight, which makes it easier to move and to install, as well as particularly suitable to be inserted in light‐framed structures (e.g. steel structures of industrial plants). The proposed system consists of an articulated quadrilateral with steel dissipaters inserted, to be connected by tendons to frame joints; the prototypes have been designed and realized for the seismic protection of a two‐storey, large‐scale, steel frame, specially designed for shaking‐table tests. The paper, after an illustration of the system, and of its design and behaviour, presents the shaking‐table tests carried out. The experimental results have fully validated the proposed system, showing its good performance in controlling the seismic response of framed structures. A numerical non‐linear model, set up and validated on the basis of the physical tests, has been used to help interpreting the experimental results, but also to perform parametrical studies for investigating the influence of the design parameters on the performance of the control system. Copyright © 2006 John Wiley & Sons, Ltd.     

Enrichment of redox-sensitive trace metals (U,V, Mo,As) associated with the late Hauterivian Faraoni oceanic anoxic event

The Faraoni Level is a short-lived oxygen-deficient event that took place during the latest Hauterivian. In order to improve our understanding of the palaeoenvironmental conditions that occurred during this event, we have analysed the contents of several redox-sensitive trace elements (U, V, Mo, As, Co, Cd, Cu, Zn, Ni, Pb, Cr) from bulk limestone samples of late Hauterivian–early Barremian age from three reference sections. U, V, Mo and As show consistent and significant enrichments during the Faraoni event whereas the other redox-sensitive trace elements analysed here are not systematically enriched. In order to explain this discrepant behaviour, we propose that the Faraoni Level was deposited during a period of anoxic conditions near the sediment–water interface. The distinctive peaks in U, V, Mo and As contents are traceable throughout the three studied sections and represent a good correlation tool which helps to identify the Faraoni Level and its equivalents in the western Tethyan realm and outside of the Tethys. For example, a peak in U contents in upper Hauterivian sediments of the northwestern Pacific realm (ODP leg 185, site 1149) may well be an expression of the Faraoni event in this particular basin.     

B,V, and DDO photometric observations of red variable stars

Light curves of the red variables L₂ Puppis, R Carinae, and S Carinae in the region of the spectrum covered by theB, V, and DDO photometry are presented. The behavior of the DDO color indices and their meaning for this type of star are discussed. S Carinae shows a different behavior from the other two stars that seems to be due to a population effect.     

Le domaine Tariquide (arc de Gibraltar,Espagne et Maroc) : succession et hiatus de la sédimentation du Jurassique supérieur au Paléocène

The originality of the Malm–Cretaceous series of the Tariquides (Gibraltar arc), as compared to those of the Rifian–Betic ‘Dorsale’ (Alboran domain), and especially with the Penibetic (Iberia) domain, is emphasized. In the Los Pastores Group, near Algeciras, Upper Tithonian nodular limestones directly lie on the Dogger and are followed by Aptychus-bearing limestones (Late Berriasian to Barremian). In the Musa Group, Rif, radiolarites are followed by siliceous limestones (Kimmeridgian–Tithonian), then by karst and massflow breccias connected to a Berriasian tectonics, by Aptychus-bearing marly limestones, then by karst filled by Turonian limestones, and finally by Maastrichtian–Palaeocene polychrome pelites, whose micropalaeontological and mineral compositions (clay minerals, FeMn nodules) refer to a deep-sea, probably infra-CCD, sedimentation. To cite this article: M. Durand-Delga et al., C. R. Geoscience 337 (2005).     

Application of biomarkers for assessing the biological impact of dredged materials in the Mediterranean: the relationship between antioxidant responses and susceptibility to oxidative stress in the red mullet (Mullus barbatus)

In the period 1997-2000, approximately 1,800,000 m3 of material dredged from the Port of Leghorn was discharged into a sea dumping site located 14 miles from the coast. The red mullet (Mullus barbatus) was used as a bioindicator species for monitoring the biological impact of these discharges on a geographical and temporal scale. Organisms were sampled over three years (1998-2000) at different stations and several biomarkers, both of exposure and effect, were analyzed. Bioavailability of specific classes of pollutants was evaluated by analyzing levels of metallothioneins, the activity of cytochrome P450 1A (CYPIA) and of glutathione S-transferases. Among biomarkers of effect, special attention was paid to the balance between prooxidant challenge and antioxidant defenses, and to the appearance of damage caused by oxidative stress. The analyses of the main components of the antioxidant system included superoxide dismutase, catalase, glutathione peroxidases, glutathione reductase, glyoxalase I and II, and total glutathione. These data were integrated with the measurement of total oxyradical scavenging capacity (TOSC) as an indication of the overall biological resistance to toxicity of different forms of oxyradicals (peroxyl radicals, hydroxyl radicals and peroxynitrite). Results indicated a biological impact in organisms sampled near the disposal site; the impact was particularly evident during 1999 and mainly related to organic chemicals such as PAH. Exposure to these pollutants also caused variations in the levels and activity of several antioxidants. The analysis of TOSC, however, revealed that the overall capacity of specific tissues of organisms to absorb various oxidants was not seriously compromised when challenged with increased prooxidant pressures. Variations of single antioxidants were useful in revealing early warning "biological responses", while integration with TOSC analyses indicated if such changes also reflect a more integrated and functional "biological effect" with possible consequences at the organisms level. The red mullet appears to be a useful sentinel species for a biomarker approach to monitoring impact caused by dredged materials.