Shock compression of zirconia ZrO2 and zircon ZrSiO4 in the pressure range up to 150 GPa

The shock compression state of zirconia ZrO₂ and zircon ZrSiO₄ in the pressure range up to 150 GPa (1.5 Mbar) are studied on the basis of the measurements of shock velocities, particle-velocity histories, free surface motions, and electrical conductivities. Zircon transforms, and zirconia probably does, to high pressure phases up to 90 GPa. The shock velocity (U _s ) — particle velocity (U _p ) Hugoniots can be described as U _s =4.38+1.37 U _p km/s above 90 GPa for ZrO₂, and U _s =6.50+0.49 U _p km/s (mixed phase region), and U _s =1.54+2.30 U _p km/s (high pressure phase region) for ZrSiO₄. The corrected isothermal densities of the high pressure phase ZrSiO₄ are roughly consistent with the isothermal ones of mixtures of ZrO₂ and SiO₂. Bulk sound velocities in the high-pressure phase region of these oxides are discussed in comparison with other dioxides. Electrical conductivities of these oxides increase from lower than 10^?12 S/m to greater than 10⁰ S/m in the shock-stress range up to 70 GPa, and remain as constant values up to higher than 100 GPa.     

A study on particle breakage behavior during pile penetration process using acoustic emission source location

Particle breakage is a common occurrence in granular systems when the external stress exceeds the individual particle strength.A large number of experimental evidences suggested that particle breakage may significantly influence the soil behavior.In the case of pile foundations,the subsoil below the pile tip experiences considerable high stress and consequently prone to break.Due to the lack of sufficient understanding on particle breakage mechanism,there is currently no consentaneous theoretical background for particle breakage analysis during the pile penetration process.This study aims to clarify the location of particle breakage and its evolving characteristics with the aid of acoustic emission(AE)source location method.The spatial distribution of AE hypocenters is interpreted to be associated with the mechanism of particle breakage.Results showed that the AE sources were not uniformly distributed,but concentrated within certain zones below the pile tip.This AE concentration zone was pushed downward with the advancing pile tip,and its distance from the real time pile tip position decreased after certain depth of pile penetration.The location of particle breakage interpreted from AE source location was verified with posttest excavations and the insights on the particle breakage evolution zone were further discussed.     

Survivability of presolar oxygen isotopic signature of amorphous silicate dust in the protosolar disk

Oxygen isotope exchange experiments between tens of nanometer‐sized amorphous enstatite grains and water vapor were carried out under a condition of protoplanetary disk‐like low water vapor pressure in order to investigate the survivability of distinct oxygen isotope signatures of presolar silicate grains in the protosolar disk. Oxygen isotope exchange between amorphous enstatite and water vapor proceeded at 923–1003 K and 0.3 Pa of water vapor through diffusive isotope exchange in the amorphous structure. The rate of diffusive isotope exchange is given by D (m² s^–1) = (5.0 ± 0.2) × 10^–21 exp[–161.3 ± 1.7 (kJ mol^–1) R^–1 (1/T–1/1200)]. The activation energy for the diffusive isotope exchange for amorphous enstatite is the same as that for amorphous forsterite within the analytical uncertainties, but the isotope exchange rate is ~30 times slower in amorphous enstatite because of the difference in frequency factor of the reaction. The reaction kinetics indicates that 0.1–1 μm‐sized presolar amorphous silicate dust with enstatite and forsterite compositions would avoid oxygen isotope exchange with protosolar disk water vapor only if they were kept at temperatures below ~500–650 K within the lifetime of the disk gas.     

亚太地区环境综合监测的研究方法--APEIS项目研究综述

为了对亚太地区的环境灾害、环境破坏和环境退化及其影响进行监测和评估,由日本环境省发起的亚太地区环境革新战略项日（APEIS)环境综合监测子项（IEM)自2001年开始,建立了一个以MODIS卫星数据和地面观测资料为基础的综合环境监视网络系统。该网络系统起初是由日本国立环境研究所(NIES)和中国科学院地理科学与资源研究所(IGSNRR)共同合作建成的。之后,新加坡国立大学和澳大利亚联邦科学产业研究组织(CSIRO)地球观测中心也正式宣布加入,该系统覆盖整个亚太地区。美国宇航局(NASA)提供了一套MCDIS的高级数据产品,然而,这些产品没能在亚洲地区利用当地的实测资料进行充分地比较和验证。APEIS项目旨在提供利用该地区精确地面观测数据进行了比较验证的高质量数据集。利用该数据集可以推导出水分亏缺指数、沙尘暴指数、地表面温度、土地覆盖变化,以及净第一性生产量等一系列生态环境指标,从而埘环境破坏、环境退化和生态脆弱区进行长期有效的监测。为了评价水资源、食物生产等生态系所提供的产品与服务的现状和变化特征,本研究还开发了一个可利用M0DIS数据的流域环境综合管理模型。该模型已经被用于对流域规模的水、热、碳循环、泥沙转移以及农业生产等生态要素的模拟和评估,并利用高精度的观测资料对其进行了验证。利用该模式可以对流域生态系统所提供的产品与服务的有效利用,以及流域的可持续发展提供一系列战略性的政策选项。     

Occurrence and chemical composition of the Eoarchean carbonate rocks of the Nulliak supracrustal rocks in the Saglek Block of northeastern Labrador,Canada

The Eoarchean Nulliak supracrustal rocks in the Saglek Block of northeastern Labrador, Canada, contain some of the world's oldest carbonate rocks. This work attempted to reveal the origin of the carbonate rocks and estimate the surface environmental conditions of the early Earth based on their occurrence and geochemistry. They occur together with mafic and ultramafic rocks in Pangertok Inlet and St. John's Harbour South, whereas they are interlayered with pelitic rock layers with quartzofeldspathic mineral assemblages in St. John's Harbour East and Big Island. The geological occurrence suggests that the formers were formed around hydrothermal fields, whereas the latters were deposited near a continental margin. Some carbonate rocks have high SiO₂, Al₂O₃, and Zr contents, indicating that the silicification and involvement of detrital materials influenced their composition; thus, pure carbonate rocks were selected using a combined filter of the SiO₂, TiO_2, Al₂O₃, Zr, and Ba contents. The selected carbonate rocks have positive La, Eu, Gd, Y, U, Pb, and Sr anomalies, negative Nb, Zr, and Hf anomalies, and relatively small enrichment in heavy rare earth elements (HREEs). The La and Y anomalies suggest that they originated from chemical sediments precipitated from seawater. On the other hand, the small HREE-enrichment suggests that REEs were mainly dissolved as REE-carbonate complexes in seawater or that the riverine influxes were dominated by the detritus of Eoarchean continental crusts, presumably composed of HREE-depleted TTG. The U anomaly suggests that uranium was more dissolved than Th as U-bearing carbonate complexes in seawater. The Nulliak carbonate rocks also show a positive correlation between Y and Eu anomaly values, suggesting that the precipitation of iron-oxyhydroxide causing the Y anomaly was more significant near the hydrothermal fields than the continental margin, consistent with an alkaline hydrothermal model.     

Post-collapse evolution of small-N clusters

N-body simulations were made to study post-collapse evolution of small-N clusters. The qualitative behaviour of the dynamical evolution is the same as in the Fokker-Planck approximation. The flatter is the mass spectrum, the more violent is the activity of binaries and so are the expansion and contraction of the cluster core.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.