Isotope and trace element geochemistry of sediments from the Barbados Ridge-Demerara Plain region,Atlantic Ocean

Twenty-four piston core sediment samples and 13 sediments and 3 basalts from DSDP Leg 78 Site 543 were analyzed for Sr, Nd and Pb isotopic compositions. The results show sediment with highly radiogenic Pb${}^{206}\text{Pb}{}^{204}\text{Pb}$ up to 19.8) and rather radiogenic Sr and unradiogenic Nd has been deposited in the region since the Cretaceous. The source of this sediment is probably the Archean Guiana Highland, which is drained by the Orinoco River. Pb and Sr isotopic compositions and sediment thickness decrease and${}^{143}\text{Nd}{}^{144}\text{Nd}$ increases northward due to a decrease in turbiditic component. This decrease is partly due to the damming action of basement ridges. Rare earth concentrations in the sediments are somewhat low, due to the abundance of detrital and biogenic components in the sediment and rapid sedimentation rates. Both positive and negative Ce anomalies occur in the surface sediments, but only positive Ce anomalies occur in the Site 543 sediments. It is unlikely that sediment subducted to the source region of Lesser Antilles arc magmas could be the cause of negative Ce anomalies in those magmas.Isotopic compositions of Site 543 basalts show some effect of contamination by seawater-basalt reaction products and sediments. Beyond this, however, they are typical of “normal” depleted MORB.     

Monthly and daily precipitation trends in the Mediterranean (1950–2000)

Summary The aim of the paper lies in the identification of possible significant linear trends at monthly, seasonal and annual timescales in the Mediterranean during the second half of the 20th century. Monthly and daily records of 63 stations have been used to elaborate several precipitation indices: sum of daily precipitation (SDP) for rainfall >0.1 mm, >10 mm and >95^th percentile, of number of rainy days (RD) >0.1 mm and >10 mm and of mean daily precipitation (MDP) >0.1 mm and >10 mm. For each index the stations have been gathered together by Rotated Principal Component Analyses to determine 8 sub-areas which can be considered as identical for all the timescales at the spatial scale of the research. Trends have been estimated from the scores of each eigenvector retained in all RPCAs. They are mainly non existant or non significant decreasing, even if a few monthly trends appear to be significantly diminishing, primarily during winter months, March in the Atlantic region, October in the Mediterranean Spain, December in the Lions and Genoa Gulfs, January, winter and the year in Greece, winter and the year in Italy and winter in the Near East and increasing in April in the two gulfs. Correlation coefficients between SDP>0.1 mm and other indices have been computed: the significant trends seem mainly related to RD>10 mm, which represents a high percentage of the total rainfall amount. Greece is remarkable: SDP>0.1 mm and >10 mm decrease significantly during January, winter, the rainy season and the entire year whereas SDP>95^th percentile increases significantly, in accordance with the climatic change scenarios for the end of this century as does the decreasing of the total monthly and seasonal rainfall.     

Radiocarbon dates and late-Quaternary stratigraphy from Mamontova Gora,unglaciated central Yakutia,Siberia, U.S.S.R.

A fine exposure of perennially frozen ice-rich silt and associated flora and vertebrate fauna of late-Quaternary age exists at Mamontova Gora along the Aldan River in central Yakutia, Siberia, U.S.S.R. The silt deposit caps a 50-m-high terrace and consists of three units. An upper layer 1–2 m thick overlies a 10–15-m-thick brownish to black silt layer. The lower silt layer is greenish to gray and about 15 m thick. All the silt is well sorted with 60% of the particles falling between 0.005 and 0.5 mm in diameter and is generally chemically and mineralogically homogeneous. The middle unit contains may extinct vertebrate mammal remains and ice wedges. The lower unit contains little vegetation and no ice wedges. The silt is widespread and exists as a loamy blanket on terraces at various elevations on both sides of the lower Aldan River. The origin of the silt blanket of late-Quaternary age in central Yakutia has long been controversial. Various hypotheses have been suggested, including lacustrine and alluvial, as well as frost-action origins. It is sometimes referred to as loess-like loam. Péwé believes the silt at Mamontova Gora is loess, some of which has been retransported very short distances by water. The silt probably was blown from wide, braided, unvegetated flood plains of rivers draining nearby glaciers. The silt deposits are late Quaternary in age and probably associated with the Maximum glaciation (Samarov) and Sartan and Syryan glaciations of Wisconsinan age. On the basis of biostratigraphy, 10 radiocarbon dates, and their relation to the nearby glacial record, it is felt that the upper unit at Mamontova Gora is Holocene and the middle unit is Wisconsinan. The youngest date available from the middle unit at this particular location is 26,000 years. Dates greater than 56,000 years were obtained in the lower part of the middle unit. The lower unit is definitely beyond the range of radiocarbon dating and probably is older than the last interglacial. The sediment, fauna, ice wedges, stratigraphy, and age of perennially frozen slit deposits in central Alaska are remarkably similar to those of the deposits exposed in central Yakutia. Both areas consist of unglaciated rolling lowlands and river terraces surrounded by high mountains that were extensively glaciated in Pleistocene time. The glaciers extended from the high mountains to the edges of the ranges. In both regions, extensively braided, silt-charged rivers drained the mountains and flowed through the lowlands on their way to the sea. It follows that there should be a similar late-Quaternary history.     

Funding low-carbon investments in the absence of a carbon tax

Introducing a carbon tax is difficult, partly because it suggests that current generations have to make sacrifices for the benefit of future generations. However, the climate change externality could be corrected without such a sacrifice. It is possible to set a carbon value, and use it to create ‘carbon certificates’ that can be accepted as part of commercial banks’ legal reserves. These certificates can be distributed to low-carbon projects, and be exchanged by investors against concessional loans, reducing capital costs for low-carbon projects. As the issuance of carbon certificates would increase the quantity of money, it will either lead to accelerated inflation or induce the Central Bank to raise interest rates. Low-carbon projects will thus have access to cheaper loans at the expense of either ‘regular’ investors (in case of higher interest rates) or of lenders and depositors (in case of accelerated inflation). Within this scheme, mitigation expenditures are compensated by a reduction in regular investments, so that immediate consumption is maintained. It uses future generation wealth to pay for a hedge against climate change. This framework is not as efficient as a carbon tax but is politically easier to implement and represents an interesting step in the trajectory towards a low-carbon economy.     

Modulation of soil moisture–precipitation interactions over France by large scale circulation

How soil moisture affects precipitation is an important question—with far reaching consequences, from weather prediction to centennial climate change—, albeit a poorly understood one. In this paper, an analysis of soil moisture–precipitation interactions over France based on observations is presented. A first objective of this paper is to investigate how large scale circulation modulates soil moisture–precipitation interactions, thanks to a weather regime approach. A second objective is to study the influence of soil moisture not only on precipitation but also on the difference between precipitation and evapotranspiration. Indeed, to have a total positive soil moisture–precipitation feedback, the potential decrease in precipitation associated with drier soils should be larger than the decrease in evapotranspiration that drier soils may also cause. A potential limited impact of soil moisture on precipitation is found for some weather regimes, but its sign depends on large scale circulation. Indeed, antecedent dry soil conditions tend to lead to smaller precipitation for the negative phase of the North Atlantic Oscillation (NAO) regime but to larger precipitation for the Atlantic Low regime. This differential response of precipitation to soil moisture anomalies depending on large scale circulation is traced back to different responses of atmospheric stability. For all circulation regimes, dry soils tend to increase the lifted condensation level, which is unfavorable to precipitation. But for the negative phase of the NAO, low soil moisture tends to lead to an increase of atmospheric stability while it tends to lead to a decrease of stability for Atlantic Low. Even if the impact of soil moisture anomalies varies depending on large scale circulation (it is larger for Atlantic low and the positive phase of the NAO), dry soils always lead to a decrease in evapotranspiration. As the absolute effect of antecedent soil moisture on evapotranspiration is always much larger than its effects on precipitation, for all circulation regimes dry soil anomalies subsequently lead to positive precipitation minus evapotranspiration anomalies i.e. the total soil moisture feedback is found to be negative. This negative feedback is stronger for the Atlantic Low and the positive phase of the NAO regimes.     

Contribution of a Dense Population of the Brittle Star <Emphasis Type="Italic">Acrocnida brachiata</Emphasis> (Montagu) to the Biogeochemical Fluxes of CO<Subscript>2</Subscript> in a Temperate Coastal Ecosystem

The production of organic matter and calcium carbonate by a dense population of the brittle star Acrocnida brachiata (Echinodermata) was calculated using demographic structure, population density, and relations between the size (disk diameter) and the ash-free dry weight (AFDW) or the calcimass. During a 2-year survey in the Bay of Seine (Eastern English Channel, France), organic production varied from 29 to 50 g_AFDW m⁻² year⁻¹ and CaCO₃ production from 69 to 104 g_CaCO3 m⁻² year⁻¹. Respiration was estimated between 1.7 and 2.0 mol_CO2 m⁻² year⁻¹. Using the molar ratio (ψ) of CO₂ released: CaCO₃ precipitated, this biogenic precipitation of calcium carbonate would result in an additional release between 0.5 and 0.7 mol_CO2 m⁻² year⁻¹ that represented 23% and 26% of total CO₂ fluxes (sum of calcification and respiration). The results of the present study suggest that calcification in temperate shallow environments should be considered as a significant source of CO₂ to seawater and thus a potential source of CO₂ to the atmosphere, emphasizing the important role of the biomineralization (estimated here) and dissolution (endoskeletons of dead individuals) in the carbon budget of temperate coastal ecosystems.     

Performance enhancement of a GIS-based facility location problem using desktop grid infrastructure

This paper presents the integration of desktop grid infrastructure with GIS technologies, by proposing a parallel resolution method in a generic distributed environment. A case study focused on a discrete facility location problem, in the biomass area, exemplifies the high amount of computing resources (CPU, memory, HDD) required to solve the spatial problem. A comprehensive analysis is undertaken in order to analyse the behaviour of the grid-enabled GIS system. This analysis, consisting of a set of the experiments on the case study, concludes that the desktop grid infrastructure is able to use a commercial GIS system to solve the spatial problem achieving high speedup and computational resource utilization. Particularly, the results of the experiments showed an increase in speedup of fourteen times using sixteen computers and a computational efficiency greater than 87 % compared with the sequential procedure.     

Sites occupancy of Fe3+ in Garfield Nontronite: A spectroscopic study

New data on the structure of Garfield nontronite have been produced by the use of different spectroscopic techniques: Mössbauer spectroscopy, optical spectroscopy, X-ray absorption edges and EXAFS and NMR. The tetrahedral iron content is found to be no higher than 1 percent. All iron atoms belong to the octahedral sheet excluding the possibility of the presence of non crystallized phases. Some ambiguities remain about the coherence of the octahedral sheet because of the presence of two doublets in the Mössbauer spectrum and at least two lineshapes in NMR spectra of OH which correspond to different environments.