Occurrence of hydroxylated polychlorinated biphenyls in the brain of cetaceans stranded along the Japanese coast

Levels of hydroxylated polychlorinated biphenyls (OH-PCBs) and PCBs were measured in the brain of melon-headed whales (MW: Peponocephala electra), striped dolphins (SD: Stenella coeruleoalba) and finless porpoises (FP: Neophocaena phocaenoides) stranded along the Japanese coast during 2002-2003. Levels of OH-PCBs (including identified and unknown OH-P(5)CB, -H(6)CB, -H(7)CB and O(8)CB congeners) in the brain of MW, SD and FP were in the range of 20-290, 21-330 and 170-240pg/g wet wt., respectively. Observed OH-PCB levels were 2-3 orders of magnitude lower than PCBs in the same individuals. OH-PCBs/PCBs ratios in MW, SD and FP brain were lower than those in blood of humans and wildlife and in the brain of polar bears reported previously. OH-PCBs were also detected in maternal and fetal brain of SD (1 pair), suggesting transfer of OH-PCBs into the fetal brain of odontocete cetaceans. When fetus/dam concentration ratios of OH-PCB congeners detected in maternal and fetal brain were estimated, the values were higher than those of PCB congeners, implying that OH-PCBs in maternal blood could be more easily transferred into fetal brain via placenta than PCBs.     

Spin Temperature of Ammonia Determined from NH2 in Comet C/2001 A2 (LINEAR)

The ortho-to-para ratio (OPR) of a cometary molecule is one of primordial character in comets. The OPR which is characterized by a spin temperature, is thought to reflect the formation conditions of the molecule. In this paper we show the high-dispersion spectrum of cometary NH₂ in Comet C/2001 A2 (LINEAR), from which the OPR of NH₂ is determined based on the fluorescence excitation model. Since the NH₂ is a photodissociation product of cometary ammonia, we applied the permutation group theory to the whole reaction system (i.e. the photodissociation reaction of ammonia to NH₂ and H) in order to derive the OPR of ammonia from that of NH₂. The derived OPR of ammonia is 1.12 ± 0.03 in Comet C/2001 A2 (LINEAR). This value corresponds to a spin temperature of 30⁺³ _-2 K. If this reflects the temperature where the comet formed in the protosolar nebula, our result indicates that thiscomet was formed in the region of the giant planets between Jupiter and Neptune.     

Near-Infrared Photometric And Polarimetric Observations Of Comet Hale-Bopp

Near-infrared photometric and polarimetric observations of comet Hale-Bopp (1995 O1) using KONIC (Kiso Observatory Near-Infrared Camera) are reported. Observations were carried out on March 18 UT and April 26 UT 1997, when the heliocentric distances of the comet were 0.94 and 1.02 AU, and the phase angles were 48.5 deg and 32.9 deg, respectively. In the J, H, and K′ bands, we obtained linear polarization of the near-nucleus region of 16.4 ± 1.2, 18.8 ± 1.3, and 15.1 ± 0.9 percent on March 18UT and 7.1 ± 1.1, 8.9 ± 1.0, and 6.9 ± 0.6 percent on April 26, respectively. These values were higher than those observed for 1P/Halley. The maximum polarization was found at H band on both dates. Polarization maps showed higher polarization regions toward the anti-solar direction in the J and H bands. No distinct correlation was found between high polarization regions and bright regions. The projected expansion velocity of the arc structure of the dust jet was 375 ± 35.7 m/s on 17–19 March. The periodicity was found to be 11.1 ± 2.8 hours. This revised version was published online in July 2006 with corrections to the Cover Date.     

Monitoring temporal and spatial trends of legacy and emerging contaminants in marine environment: results from the environmental specimen bank (es-BANK) of Ehime University, Japan

The Environmental Specimen Bank (es-BANK) for Global Monitoring at the Center for Marine Environmental Studies, Ehime University, Japan has more than four decades of practical experience in specimen banking. Over the years, es-BANK has archived specimens representing a wide range of environmental matrices, i.e. fishes, reptiles, birds, aquatic mammals, terrestrial mammals, human, soils, and sediments. The samples have been collected as part of the various monitoring programs conducted worldwide. The current review is a summary of selected studies conducted at the Center for Marine Environmental Studies, on temporal and spatial trends of legacy and emerging contaminants in the marine environment. One of the major conclusions drawn from the studies is that environmental problems are no more regional issues and, thus, environmental specimen banking should not be limited to national boundaries, but should have a global outlook.     

Models for the Origin of the Quadrantids

We present two scenarios for production of the Quadrantid stream based on two different models for its origin: the extinct model in which 2003EH1 was an active comet that released the dust particles during past 5000 years, stopping its activity abruptly in AD 1488; and the split model; in which a catastrophic disruption of an asteroid at AD 1488 released a large number of dust particles in a single event. We calculate the orbital evolution of test particles released in both cases and derive the resulting size distribution of surviving meteoroids in the current Quadrantid stream in the form of s ^−α ds, where s denotes the radius of a meteoroid. We find α = 3.1 in the extinct model and 2.0 in the split model. In addition, the radius of the surviving meteoroids is derived as s >10 μm in the both models. We propose, based on our estimation of the infrared color ratio for the Quadrantid stream derived from both models, that infrared observations of the Quadrantid stream may determine which origin model is more reasonable.     

Small-scale topography of 25143 Itokawa from the Hayabusa laser altimeter

The surface topography of Asteroid 25143 Itokawa is explored using the LIght Detection And Ranging instrument (LIDAR). The data confirm the presence of a rough highland and a smooth lowland. The highland is dominated by boulders, but also possesses topography associated with surface lineaments and broad surface facets. The boulders ensure that the roughness of the highlands over short distances is typically greater relative to most surfaces on 433 Eros. Over larger distances, Itokawa is always smoother than Eros possibly because of its smaller size and weak rubble-pile structure. The lowlands of Itokawa are very smooth, and are typically devoid of boulders. Some transitional regions midway between the highlands and lowlands also exist. In these areas, craters that retain their regolith fill possess flat floors and resemble “ponds” seen on 433 Eros. Analyses of surface elevation, imagery and a quantitative measure of surface roughness are consistent with regolith flowing downhill from the highlands to fill in the low areas of Itokawa, probably covering up any pre-existing rough terrain. Using this interpretation, we find a minimum 2.3±0.4 m thick layer of regolith in the lowlands, which, if spread evenly across the entire asteroid, corresponds to a 42±1 cm thick layer. It is very difficult to generate this amount of regolith with the population of craters seen on Itokawa. However, an Itokawa composed of several large masses may have retained this regolith during its formation. The presence of such large masses could account for the observed lineaments and what appear to be exposures of bedrock on the largest steep slope observed.     

Regional variations in trace element concentrations in tissues of black tiger shrimp Penaeus monodon (Decapoda: Penaeidae) from South Vietnam

The goal of the present study was to examine the specific bioaccumulation of 22 trace elements in muscle, exoskeleton and hepatopancreas of black tiger shrimp Penaeus monodon from the Mekong River Delta (MRD), and the South Key Economic Zone (SKEZ), South Vietnam. The general tendency in most trace element concentrations among different tissues were hepatopancreas>exoskeleton>muscle. Comparisons of trace element levels in tissues between the two regions showed that concentrations of Se in muscle and As in all three tissues were higher in SKEZ; whereas in MRD, the higher concentrations of most elements such as Mn, Cu, Cd, Ba, Hg, were observed in tissues. These geographical variations in trace element levels may reflect the differences in human activities between the two regions of South Vietnam. The target hazard quotient (THQ) values for trace elements (<1) indicate that local residents are not exposed to potential health risks via the consumption of shrimp.