Determination of Bismuth in Eighty-Three Geochemical Reference Samples by Atomic Absorption Spectrometry

The bismuth content of eighty-three geochemical reference samples has been determined by atomic absorption spectrometry using either a hydride generation and heated quartz cell atomizer or a solvent extraction and carbon tube atomizer. The agreement between the present results and published data is generally good.     

Origin of the metamorphosed clasts in the CV3 carbonaceous chondrite breccias of Graves Nunataks 06101, Vigarano,Roberts Massif 04143, and Yamato‐86009

We observed metamorphosed clasts in the CV3 chondrite breccias Graves Nunataks 06101, Vigarano, Roberts Massif 04143, and Yamato‐86009. These clasts are coarse‐grained polymineralic rocks composed of Ca‐bearing ferroan olivine (Fa_24–40, up to 0.6 wt% CaO), diopside (Fs_7–12Wo_44–50), plagioclase (An_52–75), Cr‐spinel (Cr/[Cr + Al] = 0.4, Fe/[Fe + Mg] = 0.7), sulfide and rare grains of Fe‐Ni metal, phosphate, and Ca‐poor pyroxene (Fs₂₄Wo₄). Most clasts have triple junctions between silicate grains. The rare earth element (REE) abundances are high in diopside (REE ~3.80–13.83 × CI) and plagioclase (Eu ~12.31–14.67 × CI) but are low in olivine (REE ~0.01–1.44 × CI) and spinel (REE ~0.25–0.49 × CI). These REE abundances are different from those of metamorphosed chondrites, primitive achondrites, and achondrites, suggesting that the clasts are not fragments of these meteorites. Similar mineralogical characteristics of the clasts with those in the Mokoia and Yamato‐86009 breccias (Jogo et al. 2012 ) suggest that the clasts observed in this study would also form inside the CV3 chondrite parent body. Thermal modeling suggests that in order to reach the metamorphosed temperatures of the clasts of >800 °C, the clast parent body should have accreted by ~2.5–2.6 Ma after CAIs formation. The consistency of the accretion age of the clast parent body and the CV3 chondrule formation age suggests that the clasts and CV3 chondrites could be originated from the same parent body with a peak temperature of 800–1100 °C. If the body has a peak temperature of >1100 °C, the accretion age of the body becomes older than the CV3 chondrule formation age and multiple CV3 parent bodies are likely.     

The Southern Annular Mode and opposite-phased Basin Mode of the Southern Ocean circulation

Over the Southern Ocean the dominant modes of the atmospheric field are known as the Southern Annular Mode (SAM) or Antarctic Oscillation, and the Pacific South American (PSA) pattern. Statistical analysis of sea surface wind (SSW) from satellite observation revealed two leading modes of SAM-like and PSA patterns. In the high latitudes, the SAM-like pattern of the SSW had a large amplitude over the Bellingshausen Basin and Australian-Antarctic Basin, with opposite phase between the two basins. On the intraseasonal time scale, large-scale sea surface height (SSH) also had notable variability, showing a basin-scale anti-phase mode over the two basins. To explain the response of oceanic variations to these atmospheric modes, we analyzed the relationship between the dominant modes of wind stress and large-scale SSH on the intraseasonal time scale. The SAM-like pattern of wind stress was correlated with the SSH variation over the two basins. The SSH basin mode was most simply explained by a simple barotropic response to the SAM-like mode of wind stress, with the curl of opposite phase between the two basins. We conclude that the zonal asymmetry of the wind field of the SAM plays an important role in driving the antiphase SSH basin modes.     

Low-grade metamorphism of the Mikabu and northern Chichibu belts in central Shikoku, SW Japan: implications for the areal extent of the Sanbagawa low-grade metamorphism

In central Shikoku, SW Japan, the Mikabu belt is bounded to the north by the Sanbagawa belt, and to the south by the northern (N) Chichibu belt. The N-Chichibu belt can be further subdivided into northern and southern parts. There is no apparent difference in the overall geology, structure, or fossil and radiometric ages between the Mikabu belt and the northern part of the N-Chichibu belt. Greenstones from the Mikabu belt and the northern part of the N-Chichibu belt show evidence for similar low-grade metamorphism, and include the following mineral assemblages with albite+chlorite in excess: metamorphic aragonite, sodic pyroxene+quartz, epidote+actinolite+pumpellyite, glaucophane+ pumpellyite+quartz, and lawsonite (not with actinolite or glaucophane). These similarities suggest that the Mikabu belt and the northern part of the N-Chichibu belt belong to the same geological unit (the MB-NNC complex). The mineral assemblages also indicate that the MB-NNC complex belongs to a different metamorphic facies from the low-grade part of the Sanbagawa belt, that is, the former represents lower temperature/higher pressure conditions than the latter. Structural and petrological continuity between the MB-NNC complex and Sanbagawa belt has not yet been confirmed, but both have similar radiometric ages. It is therefore most likely that the MB-NNC complex and Sanbagawa belt belong to the same subduction complex, and were metamorphosed under similar but distinct conditions. These two units were juxtaposed during exhumation. In contrast, the southern part of the N-Chichibu belt is distinct in lithology and structure, and includes no mineral assemblages diagnostic of the MB-NNC complex and the Sanbagawa belt. Thus, the southern part of the N-Chichibu belt may represent a different geological unit from the MB-NNC complex and Sanbagawa belt.     

Holocene East Asian monsoon variation inferred from species assemblage and shell chemistry of the ostracodes from Hulun Lake, Inner Mongolia

A sediment core from Hulun Lake, Inner Mongolia was analyzed for species assemblages and shell chemistry of ostracodes to investigate changes in the hydrology and climate of the East Asian summer monsoon margin during the Holocene. Darwinula stevensoni was abundant, Ilyocypris spp. scarce, littoral ostracodes absent and Mg/Ca, Sr/Ca and δ¹⁸O were low 11,100 to 8300 yr ago, indicating high lake levels and cool/fresh waters. Darwinula stevensoni declined largely, Ilyocypris spp. throve, littoral ostracodes were rare and chemical indicators remained in low values 8300 to 6200 yr ago, suggesting that the lake continued high stands but water became warm. The lake then contracted and water became cool/brackish 6200 to 4300 yr ago. Littoral ostracodes flourished 4300 to 3350 yr ago, marking the lowest lake levels of the entire Holocene. The lake level recovered and water salinity decreased 3350 to 1900 yr ago. From 1900 to 500 yr ago, the lake maintained the preceding status albeit lowered stands and increased salinities 1100 to 800 yr ago. During the recent 500 yr, the lake expanded and water salinity decreased. The data imply that the East Asian summer monsoon did not intensify until 8300 yr ago and weakened dramatically 4300 to 3350 yr ago.     

Obliquity variations of terrestrial planets in habitable zones

We have investigated obliquity variations of possible terrestrial planets in habitable zones (HZs) perturbed by a giant planet(s) in extrasolar planetary systems. All the extrasolar planets so far discovered are inferred to be jovian-type gas giants. However, terrestrial planets could also exist in extrasolar planetary systems. In order for life, in particular for land-based life, to evolve and survive on a possible terrestrial planet in an HZ, small obliquity variations of the planet may be required in addition to its orbital stability, because large obliquity variations would cause significant climate change. It is known that large obliquity variations are caused by spin-orbit resonances where the precession frequency of the planet's spin nearly coincides with one of the precession frequencies of the ascending node of the planet's orbit. Using analytical expressions, we evaluated the obliquity variations of terrestrial planets with prograde spins in HZs. We found that the obliquity of terrestrial planets suffers large variations when the giant planet's orbit is separated by several Hill radii from an edge of the HZ, in which the orbits of the terrestrial planets in the HZ are marginally stable. Applying these results to the known extrasolar planetary systems, we found that about half of these systems can have terrestrial planets with small obliquity variations (smaller than 10°) over their entire HZs. However, the systems with both small obliquity variations and stable orbits in their HZs are only 1/5 of known systems. Most such systems are comprised of short-period giant planets. If additional planets are found in the known planetary systems, they generally tend to enhance the obliquity variations. On the other hand, if a large/close satellite exists, it significantly enhances the precession rate of the spin axis of a terrestrial planet and is likely to reduce the obliquity variations of the planet. Moreover, if a terrestrial planet is in a retrograde spin state, the spin-orbit resonance does not occur. Retrograde spin, or a large/close satellite might be essential for land-based life to survive on a terrestrial planet in an HZ.     

Radar observations of asteroid 25143 Itokawa (1998 SF36)

Abstract— We observed 25143 Itokawa, the target of Japan's Hayabusa (MUSES‐C) sample‐return mission, during its 2001 close approach at Arecibo on twelve dates during March 18‐April 9 and at Goldstone on nine dates during March 20‐April 2. We obtained delay‐Doppler images with range resolutions of 100 ns (15 m) at Arecibo and 125 ns (19 m) at Goldstone. Itokawa's average circular polarization ratio at 13 cm, 0.26 ± 0.04, is comparable to that of Eros, so its cm‐to‐m surface roughness probably is comparable to that on Eros. Itokawa's radar reflectivity and polarization properties indicate a near‐surface bulk density within 20% of 2.5 g cm^?3. We present a preliminary estimate of Itokawa's shape, reconstructed from images with rather limited rotation‐phase coverage, using the method of Hudson (1993) and assuming the lightcurve‐derived spin period (12.132 hr) and pole direction (ecliptic long., lat. = 355°, ?84°) of Kaasalainen et al. (2003). The model can be described as a slightly asymmetrical, slightly flattened ellipsoid with extents along its principal axes of 548 times 312 times 276 m ± 10%. Itokawa's topography is very subdued compared to that of other asteroids for which spacecraft images or radar reconstructions are available. Similarly, gravitational slopes on our Itokawa model average only 9° and everywhere are less than 27°. The radar‐refined orbit allows accurate identification of Itokawa's close planetary approaches through 2170. If radar ranging planned for Itokawa's 2004 apparition succeeds, then tracking of Hayabusa during its 2005 rendezvous should reveal Yarkovsky perturbation of the asteroid's orbit.     

Recent insights into analytical precision and modelling of DDA and NMM for practical problems

This paper discussed the analytical precision on equations of motion in some practical studies that use 2-D DDA, 2D-Coupled analysis of NMM & DDA, and 3D-DDA. We point out the main reason for numerical instability in DDA is loss of the effective digits when superposing the global stiffness matrix under the variable conditions of large and the small blocks. Categories of analyses are distributed in 2D-DDA static masonry structures such as the Great Pyramid and the Pont du Gard, 2D-DDA dynamic rock fall problems and the sensitivity of its analysis on the velocity ratio and the penalty, earthquake response analysis of rock slopes, 2D-NMM, 2D-coupled analysis of DDA and NMM and 3D-DDA rock fall problem. The selected examples on the Great Pyramid, Pont du Gard and Bayon Temple at Angkor Thom are located in Egypt, France and Cambodia respectively as UNESCO world heritages sites. The authors evaluated the applicability of the methods and the reliability of the results by comparing different methods and site observations from the practical problems.     

Solidification depth and crystallization age of the Shiaidani Granodiorite: Constraints to the average denudation rate of the Hida Range,central Japan

Solidification pressure and crystallization age of the ~5 Ma Shiaidani Granodiorite (Hida Mountain Range, central Japan) are determined based on Al-in-hornblende geobarometry and U–Pb zircon dating. Al-poor patchy replacements developed in amphiboles are common in this granite and petrographic study revealed that the replacements include chloritized biotite and albitic plagioclase. These are probably the hydrothermally recrystallized domains, and should not be used for solidification pressure estimates. Magmatic rim of amphibole is characterized by Si < 7.3 a.p.f.u. (Al_IV > 0.7 a.p.f.u.), and utilized in solidification pressure estimate that yielded 0.17–0.29 GPa. The solidification age of the granite is estimated as ~5.6–5.2 Ma using U–Pb zircon dating. From these data, the lower limit of an average denudation rate after ~5.6–5.2 Ma for the area where Shiaidani Granodiorite is exposed is estimated as 0.93–2.5 mm/year.     

Permian Peri‐glacial Deposits from Central Mongolia in Central Asian Orogenic Belt: A Possible Indicator of the Capitanian Cooling Event

A dropstone‐bearing, Middle Permian to Early Triassic peri‐glacial sedimentary unit was first discovered from the Khangai–Khentei Belt in Mongolia, Central Asian Orogenic Belt. The unit, Urmegtei Formation, is assumed to cover the early Carboniferous Khangai–Khentei accretionary complex, and is an upward‐fining sequence, consisting of conglomerates, sandstones, and varved sandstone and mudstone beds with granite dropstones in ascending order. The formation was cut by a felsic dike, and was deformed and metamorphosed together with the felsic dike. An undeformed porphyritic granite batholith finally cut all the deformed and metamorphosed rocks. LA‐ICP‐MS, U–Pb zircon dating has revealed the following ²⁰⁶Pb/²³⁸U weighted mean igneous ages: (i) a granite dropstone in the Urmegtei Formation is 273 ± 5 Ma (Kungurian of Early Permian); (ii) the deformed felsic dike is 247 ± 4 Ma (Olenekian of Early Triassic); and (iii) the undeformed granite batholith is 218 ± 9 Ma (Carnian of Late Triassic). From these data, the age of sedimentation of the Urmegtei Formation is constrained between the Kungurian and the Olenekian (273–247 Ma), and the age of deformation and metamorphism is constrained between the Olenekian and the Carnian (247–218 Ma). In Permian and Triassic times, the global climate was in a warming trend from the Serpukhovian (early Late Carboniferous) to the Kungurian long and severe cool mode (328–271 Ma) to the Roadian to Bajocian (Middle Jurassic) warm mode (271–168 Ma), with an interruption with the Capitanian Kamura cooling event (266–260 Ma). The dropstone‐bearing strata of the Urmegtei Formation, together with the glacier‐related deposits in the Verkhoyansk, Kolyma, and Omolon areas of northeastern Siberia (said to be of Middle to Late Permian age), must be products of the Capitanian cooling event. Although further study is needed, the dropstone‐bearing strata we found can be explained in two ways: (i) the Urmegtei Formation is an autochthonous formation indicating a short‐term expansion of land glacier to the central part of Siberia in Capitanian age; or (ii) the Urmegtei Formation was deposited in or around a limited ice‐covered continent in northeast Siberia in the Capitanian and was displaced to the present position by the Carnian.