CdTe量子点荧光猝灭法测定赤泥中痕量镍

Cd Te量子点具有荧光强度高和稳定性好的优点,应用Cd Te量子点荧光猝灭法分析基体复杂的样品,需要有效分离对测定干扰的金属元素和高效富集待测元素。本文以巯基乙酸(TGA)作稳定剂,采用水相合成法制备了巯基乙酸修饰的Cd Te量子点,基于镍离子在p H=10.0硼砂缓冲溶液中对Cd Te量子点的荧光具有较强猝灭作用,建立了一种测定赤泥中痕量镍的荧光光度方法。荧光猝灭反应的最佳实验条件为:Cd Te量子点的浓度3.0×10-4mol/L,反应温度为室温,反应时间10 min,在此条件下镍离子浓度在2.0×10-7~7.8×10-5mol/L范围内与Cd Te量子点的相对荧光强度呈良好的线性关系;方法检出限为1.5×10-7mol/L。本方法针对Fe3+、Co2+、Cu2+等主要基体金属元素允许量低的问题,采用25%的2-羟基-4-仲辛氧基二苯甲酮肟(N530)磺化煤油萃取回收滤液中的Ni2+,镍回收率达到99%以上;赤泥中痕量镍的测定结果与催化光度法相符,加标回收率为98.3%-104.2%。     

Study on the Fracturing Parameters and Productivity of Horizontal Wells

<正>1 Introduction Hydraulic fracturing refers to the parting of geomaterials due to excessively high fluid pressure.The most common application of hydraulic fracturing is enhanced oil recovery,in which increase in functional permeability of the ground is achived by the formation of permeable     

Method on Pore Structure of Tight Reservoir

<正>1 Introduction The physical properties of tight reservoir depends largely on its micro and super-micro pore structures,which mainly includes the size of pores and throats and their distribution,the collection form of pores and throats space,the connectivity among pores and throats and so on.The size of     

Fine Geological Modeling of the Tight Oil Reservoir

<正>1 Introduction The study area of Northern Honggang is located in the Daan-Honggang terrace in the central depression of the southern Songliao basin,covering an area of 110km2.The oil field is categorized as an ultra-low permeability reservoir and the target horizon is the Fuyu oil layer.The reservoir is characterized as poor physical property,strong     

Exhumation History of the Xining Basin Since the Mesozoic and Its Tectonic Significance

The Xining Basin is located in the northeastern Qinghai–Tibetan Plateau, and its continuous Cenozoic strata record the entire uplift and outgrowth history of the Tibetan Plateau during the Cenozoic. The newly obtained apatite fission track data presented here shows that the Xining Basin and two marginal mountain ranges have experienced multiphase rapid cooling since the Jurassic, as follows. In the Middle–Late Jurassic, the rapid exhumation of the former Xining Basin resulted from collision between the Qiangtang Block and the Tarim Block. During the Early–Late Cretaceous, the former Xining Basin underwent a tectonic event due to marginal compression, causing the angular unconformity between the Upper and Lower Cretaceous. In the Late Cretaceous to the Early Cenozoic, collision between the Qiangtang Block and the Lhasa Block may have resulted in the rapid exhumation of the Xining Basin and the Lajishan to the south. In the Early Cenozoic(ca. 50–30 Ma), collision between the Indian and Eurasia plates affected the region that corresponds to the present northeastern Qinghai–Tibetan Plateau. During this period, the central Qilian Block rotated clockwise by approximately 24° to form a wedge-shaped basin(i.e., the Xining Basin) opening to the west. During ca. 17–8 Ma, the entire northeastern Qinghai–Tibetan Plateau underwent dramatic deformation, and the Lajishan uplifted rapidly owing to the northward compression of the Guide Basin from the south. A marked change in subsidence occurred in the Xining Basin during this period, when the basin was tectonically inverted.     

外生稀土矿床的分布、类型和成因概述

稀土是当今危机资源,勘探和研究稀土矿床是世界热点。外生矿床是重要的稀土来源之一。本文综述了残-坡积、(河流)冲积和海滨砂矿,碳酸盐岩风化壳型,花岗岩风化壳型等稀土矿床地质特征和成因认识。风化壳型稀土矿床是由富稀土的原岩经过地表机械和化学风化作用形成,母岩稀土的最初富集是形成风化壳型稀土矿床的前提,风化壳继承了母岩的稀土特征。目前世界对重稀土的需求最为突出,中国南岭花岗岩风化壳型重稀土矿床为世界之最。风化是后期稀土提炼富集过程,成矿关键在于花岗岩岩浆阶段重稀土矿物的形成。然而,何种因素形成南岭地区具有稀土成矿潜力的花岗岩,富稀土花岗岩表现出的轻重稀土分异是由于源区性质的差异还是源于岩浆演化过程中的分异作用,以及重稀土矿物的形成机制仍有待于研究。     

乌兰布和沙漠东南缘白沙蒿(Artemisia sphaerocphala)灌丛沙堆形态特征与固沙能力

白沙蒿(Artemisia sphaerocphala)灌丛沙堆是乌兰布和沙漠最为广泛分布的典型荒漠灌丛沙堆之一。本研究对白沙蒿灌丛的灌丛形态参数、沙堆形态参数进行了野外测定,探讨沙堆形态发育及固沙能力与白沙蒿灌丛形态的关系。结果表明:白沙蒿灌丛高度随着灌丛半径的增加而呈对数曲线增加,在灌丛较小时灌丛高度增长较快,随后渐趋于稳定,其水平方向发育速度大于垂直方向;白沙蒿灌丛沙堆半径及高度随灌丛半径和高度增加而增加,二者呈显著线性关系,沙堆水平方向发育受到灌丛冠幅的影响,沙堆垂直方向的发育水平取决于灌丛高度;随白沙蒿地上部分鲜重的增加,灌丛沙堆底面积、高度、沙堆体积和固沙效率均呈极显著线性增加(p0.01);白沙蒿灌丛越大其固积沙堆也越大,固沙率越高,不同大小灌丛白沙蒿间的固沙效率差异显著(p0.05);白沙蒿灌丛背风侧的积沙宽度(y)与积沙距离(x)显著相关(R2=0.9917),其线性回归方程为y=-19.654x+122.41,在距离灌丛背风面6~7倍高度的地方,积沙接近消失。     

Transition of Zonal Asymmetry of the Arctic Oscillation and the Antarctic Oscillation at the End of 1970s

In this study,the interdecadal changes in the zonal symmetry of both Arctic Oscillation(AO) and Antarctic Oscillation(AAO) were analyzed.To describe the zonal asymmetry,a local index of AO and AAO was defined using the normalized sea level pressure(SLP) differences between 40° and 65°(latitudes) in both hemispheres.The zonal covariability of local AO and AAO can well represent the zonal symmetry of AO and AAO.Results show that the zonal asymmetry of both AO and AAO significantly changed in the late 1970s.AO was less asymmetric in the zonal direction in the boreal winter season during the latter period,while in the boreal summer it became more asymmetric after 1979.The zonal symmetry of AAO in both austral summer and winter has also significantly decreased since the late 1970s.These changes may imply interdecadal transition in the atmospheric circulation at middle and high latitudes,which is of vital importance to understanding climate variability and predictability across the globe,including the African-Asian-Australian monsoon regions.     

热带气旋外眼墙形成机制研究综述

介绍了国内外关于热带气旋外眼墙形成和维持过程的相关研究进展,包括大尺度环境场和热带气旋涡旋内部动力学过程,如涡旋罗斯贝波理论、轴对称化过程、涡丝化作用、β-skirt轴对称化外眼墙形成假说和边界层非平衡动力过程等。随着对外眼墙形成机理研究的不断深入,当前存在多种外眼墙形成的机制理论,而这些机制均强调在外眼墙的形成阶段,热带气旋外围有大量对流及位势涡度扰动的发生发展。因此,热带气旋外眼墙的形成很有可能是多种机制相互作用导致的。最后,提出研究多种机制相互作用导致外眼墙处的对流和位势涡度扰动的发生发展过程具有重大意义。