Strong ground motion record selection for the reliable prediction of the mean seismic collapse capacity of a structure group

How to select a limited number of strong ground motion records (SGMRs) is an important challenge for the seismic collapse capacity assessment of structures. The collapse capacity is considered as the ground motion intensity measure corresponding to the drift‐related dynamic instability in the structural system. The goal of this paper is to select, from a general set of SGMRs, a small number of subsets such that each can be used for the reliable prediction of the mean collapse capacity of a particular group of structures, i.e. of single degree‐of‐freedom systems with a typical behaviour range. In order to achieve this goal, multivariate statistical analysis is first applied, to determine what degree of similarity exists between each selected small subset and the general set of SGMRs. Principal Component analysis is applied to identify the best way to group structures, resulting in a minimum number of SGMRs in a proposed subset. The structures were classified into six groups, and for each group a subset of eight SGMRs has been proposed. The methodology has been validated by analysing a first‐mode‐dominated three‐storey‐reinforced concrete structure by means of the proposed subsets, as well as the general set of SGMRs. The results of this analysis show that the mean seismic collapse capacity can be predicted by the proposed subsets with less dispersion than by the recently developed improved approach, which is based on scaling the response spectra of the records to match the conditional mean spectrum. Copyright © 2010 John Wiley & Sons, Ltd.     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

Pennsylvanian carbonate platforms adjacent to deltaic systems in an active marine foreland basin (Escalada Fm., Cantabrian Zone,NW Spain)

The Pennsylvanian marine foreland basin of the Cantabrian Zone (NW Spain) is characterized by the unique development of kilometre‐size and hundred‐metre‐thick carbonate platforms adjacent to deltaic systems. During Moscovian time, progradational clastic wedges fed by the orogen comprised proximal alluvial conglomerates and coal‐bearing deltaic sequences to distal shelfal marine deposits associated with carbonate platforms (Escalada Fm.) and distal clay‐rich submarine slopes. A first phase of carbonate platform development (Escalada I, upper Kashirian‐lower Podolskian) reached a thickness of 400 m, nearly 50 km in width and developed a distal high‐relief margin facing a starved basin, nearly 1000‐m deep. Carbonate slope clinoforms dipped up to 30° and consisted of in situ microbial boundstone, pinching out downslope into calciturbidites, argillaceous spiculites and breccias. The second carbonate platform (Escalada II, upper Podolskian‐lower Myachkovian) developed beyond the previous platform margin, following the basinward progradation of siliciclastic deposits. Both carbonate platforms include: (1) a lower part composed of siliciclastic‐carbonate cyclothems characterized by coated‐grain and ooid grainstones; and (2) a carbonate‐dominated upper part, composed of tabular and mound‐shaped wackestone and algal‐microbial boundstone strata alternating at the decametre scale with skeletal and coated‐grain grainstone beds. Carbonate platforms initiated in distal sectors of the foreland marine shelf during transgressions, when terrigenous sediments were stored in the proximal part, and developed further during highstands of 3rd‐order sequences in a high‐subsidence context. During the falling stage and lowstand systems tracts, deltaic systems prograded across the shelf burying the carbonate platforms. Key factors involved in the development of these unique carbonate platforms in an active foreland basin are: (1) the large size of the marine shelf (approaching 200 km in width); (2) the subsidence distribution pattern across the marine shelf, decreasing from proximal shoreline to distal sectors; (3) Pennsylvanian glacio‐eustacy affecting carbonate lithofacies architecture; and (4) the environmental conditions optimal for fostering microbial and algal carbonate factories.     

Phase equilibria modelling of retrograde amphibole and clinozoisite in mafic eclogite from the Tso Morari massif,northwest India: constraining the P–T–M(H2O) conditions of exhumation

Phase equilibria modelling of post‐peak metamorphic mineral assemblages in (ultra)high‐P mafic eclogite from the Tso Morari massif, Ladakh Himalaya, northwest India, has provided new insights into the potential behaviour and source of metamorphic fluid during exhumation, and constrained the P–T conditions of hydration. A series of P–M(H₂O) pseudosections constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system show that a number of petrographically distinct hydration episodes occurred during exhumation from peak P–T conditions (~640 °C, 27–28 kbar), resulting in the formation of abundant compositionally zoned amphibole and minor clinozoisite poikiloblasts at the expense of a peak assemblage dominated by garnet and omphacite. Initial hydration is interpreted to have occurred as a result of the destabilization of talc following isothermal decompression to ~23 kbar, which led to the formation of barroisite–winchite amphibole core domains. An episode of fluid infiltration from an external source at ~19 kbar, with or without syn‐decompressional cooling to ~560 °C, resulted in further barroisitic–winchitic amphibole growth, followed by the formation of clinozoisite poikiloblasts. Continued buoyancy‐driven exhumation to the base of the lower crust is constrained to have taken place with no additional fluid input. A final hydration event is characterized by the formation of magnesiohornblende rims on the barroisite–winchite cores, with the former interpreted to have formed during later prograde overprinting in the middle crust associated with the final stages of exhumation. Notably, the vast majority of externally sourced H₂O, comprising just over half of the current bulk rock fluid content, was added during this later hydration event. In a middle crustal setting, this is interpreted as the result of devolatilization reactions occurring in migmatitic host orthogneiss and/or metasedimentary units, or following the crystallization of partial melt.     

Simulation of less‐mobile porosity dynamics in contrasting sediment water interface porous media

Considering heterogeneity in porous media pore size and connectivity is essential to predicting reactive solute transport across interfaces. However, exchange with less‐mobile porosity is rarely considered in surface water/groundwater recharge studies. Previous research indicates that a combination of pore‐fluid sampling and geoelectrical measurements can be used to quantify less‐mobile porosity exchange dynamics using the time‐varying relation between fluid and bulk electrical conductivity. For this study, we use macro‐scale (10 s of cm) advection–dispersion solute transport models linked with electrical conduction in COMSOL Multiphysics to explore less‐mobile porosity dynamics in two different types of observed sediment water interface porous media. Modeled sediment textures contrast from strongly layered streambed deposits to poorly sorted lakebed sands and cobbles. During simulated ionic tracer perturbations, a lag between fluid and bulk electrical conductivity, and the resultant hysteresis, is observed for all simulations indicating differential loading of pore spaces with tracer. Less‐mobile exchange parameters are determined graphically from these tracer time series data without the need for inverse numerical model simulation. In both sediment types, effective less‐mobile porosity exchange parameters are variable in response to changes in flow direction and fluid flux. These observed flow‐dependent effects directly impact local less‐mobile residence times and associated contact time for biogeochemical reaction. The simulations indicate that for the sediment textures explored here, less‐mobile porosity exchange is dominated by variable rates of advection through the domain, rather than diffusion of solute, for typical low‐to‐moderate rate (approximately 3–40 cm/day) hyporheic fluid fluxes. Overall, our model‐based results show that less‐mobile porosity may be expected in a range of natural hyporheic sediments and that changes in flowpath orientation and magnitude will impact less‐mobile exchange parameters. These temporal dynamics can be assessed with the geoelectrical experimental tracer method applied at laboratory and field scales.     

Delimiting the eastern extent of the Altyn Tagh Fault: Insights from structural analyses of seismic reflection profiles

The Altyn Tagh Fault (ATF) serves as a key continental‐scale controlling structural element of the Tibetan Plateau. However, its eastward extent remains controversial. Here we use high‐resolution seismic reflection profiles to investigate the subsurface structures of the easternmost ATF and use these to delimit the easternmost extent of the fault. The structural analyses show an eastward geometric change from transpressional positive flower structures to compressional thrusts, with transpression‐induced shortening magnitudes decreasing eastwards from a maximum of ~5.3 km to being absent. Stratigraphic controls indicate that the deformation took place over the last ~<1.2 Ma. Our wider findings lead us to: (a) reject the suggestion that the ATF previously extended beyond the Kuantan Shan‐Hei Shan to link with the Alxa‐East Mongolia Fault; and (b) propose that the rigid block model used to describe the Tibetan Plateau crust is not consistent with the extent and structural details of the easternmost ATF.     

A luminescence‐based chronology for the Harletz loess sequence,Bulgaria

The Harletz loess‐palaeosol sequence is located in northwestern Bulgaria and represents an important link between well‐studied loess sequences in eastern Romania and further sites to the west of the Carpathians (e.g. Serbia and Hungary). The aim of this study was to establish a chronostratigraphy of the deposits, using various methods of luminescence dating, together with basic stratigraphical field observations as well as magnetic properties. Luminescence dating was carried out using the quartz fine grain fraction and a SAR protocol, and the feldspar coarse grain fraction, applying the MET‐pIRIR protocol. Due to underestimation of the quartz fine grain fraction in the lower parts of the sequence, the resulting chronology is mainly based on the feldspar ages, which are derived from the stimulation temperature at 150 °C. A comparison with nearby sequences from Serbia, Hungary and Romania, and interpretations obtained through the stratigraphical and sedimentological signature of the sequence, supports the established chronology. Our data suggest that the prominent palaeosol (soil complex) in the upper quarter of the sequence was formed during MIS 5. It would follow that large parts of the Last Glacial loess overlying this palaeosol were probably eroded, and that the thick loess accumulation underlying this soil complex can be allocated to the penultimate glacial (MIS 6). A prominent MIS 6 tephra, which has been reported from other sequences in the area, is also present at Harletz.     

Subduction metamorphism of serpentinite‐hosted carbonates beyond antigorite‐serpentinite dehydration (Nevado‐Filábride Complex,Spain)

At sub‐arc depths, the release of carbon from subducting slab lithologies is mostly controlled by fluid released by devolatilization reactions such as dehydration of antigorite (Atg‐) serpentinite to prograde peridotite. Here we investigate carbonate–silicate rocks hosted in Atg‐serpentinite and prograde chlorite (Chl‐) harzburgite in the Milagrosa and Almirez ultramafic massifs of the palaeo‐subducted Nevado‐Filábride Complex (NFC, Betic Cordillera, S. Spain). These massifs provide a unique opportunity to study the stability of carbonate during subduction metamorphism at P–T conditions before and after the dehydration of Atg‐serpentinite in a warm subduction setting. In the Milagrosa massif, carbonate–silicate rocks occur as lenses of Ti‐clinohumite–diopside–calcite marbles, diopside–dolomite marbles and antigorite–diopside–dolomite rocks hosted in clinopyroxene‐bearing Atg‐serpentinite. In Almirez, carbonate–silicate rocks are hosted in Chl‐harzburgite and show a high‐grade assemblage composed of olivine, Ti‐clinohumite, diopside, chlorite, dolomite, calcite, Cr‐bearing magnetite, pentlandite and rare aragonite inclusions. These NFC carbonate–silicate rocks have variable CaO and CO₂ contents at nearly constant Mg/Si ratio and high Ni and Cr contents, indicating that their protoliths were variable mixtures of serpentine and Ca‐carbonate (i.e., ophicarbonates). Thermodynamic modelling shows that the carbonate–silicate rocks attained peak metamorphic conditions similar to those of their host serpentinite (Milagrosa massif; 550–600°C and 1.0–1.4 GPa) and Chl‐harzburgite (Almirez massif; 1.7–1.9 GPa and 680°C). Microstructures, mineral chemistry and phase relations indicate that the hybrid carbonate–silicate bulk rock compositions formed before prograde metamorphism, likely during seawater hydrothermal alteration, and subsequently underwent subduction metamorphism. In the CaO–MgO–SiO₂ ternary, these processes resulted in a compositional variability of NFC serpentinite‐hosted carbonate–silicate rocks along the serpentine‐calcite mixing trend, similar to that observed in serpentinite‐hosted carbonate‐rocks in other palaeo‐subducted metamorphic terranes. Thermodynamic modelling using classical models of binary H₂O–CO₂ fluids shows that the compositional variability along this binary determines the temperature of the main devolatilization reactions, the fluid composition and the mineral assemblages of reaction products during prograde subduction metamorphism. Thermodynamic modelling considering electrolytic fluids reveals that H₂O and molecular CO₂ are the main fluid species and charged carbon‐bearing species occur only in minor amounts in equilibrium with carbonate–silicate rocks in warm subduction settings. Consequently, accounting for electrolytic fluids at these conditions slightly increases the solubility of carbon in the fluids compared with predictions by classical binary H₂O–CO₂ fluids, but does not affect the topology of phase relations in serpentinite‐hosted carbonate‐rocks. Phase relations, mineral composition and assemblages of Milagrosa and Almirez (meta)‐serpentinite‐hosted carbonate–silicate rocks are consistent with local equilibrium between an infiltrating fluid and the bulk rock composition and indicate a limited role of infiltration‐driven decarbonation. Our study shows natural evidence for the preservation of carbonates in serpentinite‐hosted carbonate–silicate rocks beyond the Atg‐serpentinite breakdown at sub‐arc depths, demonstrating that carbon can be recycled into the deep mantle.