Determination of first-order degradation rate constants from monitoring networks

In this article, different strategies for estimating first-order degradation rate constants from measured field data are compared by application to multiple, synthetic, contaminant plumes. The plumes were generated by numerical simulation of contaminant transport and degradation in virtual heterogeneous aquifers. These sites were then individually and independently investigated on the computer by installation of extensive networks of observation wells. From the data measured at the wells, that is, contaminant concentrations, hydraulic conductivities, and heads, first-order degradation rates were estimated by three 1D centerline methods, which use only measurements located on the plume axis, and a two-dimensional method, which uses all concentration measurements available downgradient from the contaminant source. Results for both strategies show that the true rate constant used for the numerical simulation of the plumes in general tends to be overestimated. Overestimation is stronger for narrow plumes from small source zones, with an average overestimation factor of about 5 and single values ranging from 0.5 to 20, decreasing for wider plumes, with an average overestimation factor of about 2 and similar spread. Reasons for this overestimation are identified in the velocity calculation, the dispersivity parameterization, and off-centerline measurements. For narrow plumes, the one- and the two-dimensional strategies show approximately the same amount of overestimation. For wider plumes, however, incorporation of all measurements in the two-dimensional approach reduces the estimation error. No significant relation between the number of observation wells in the monitoring network and the quality of the estimated rate constant is found for the two-dimensional approach.     

Impact of systematic errors on precise long-baseline kinematic GPS positioning

Many kinematic GPS applications rely on high accuracy, which usually requires the ambiguities to be fixed. Normally, a reference station in the rover’s vicinity is needed for successful ambiguity resolution. Alternatively, a network surrounding the rover and allowing one to derive area correction parameters is needed. Unfortunately, both approaches are not feasible in certain situations. This paper is a contribution to precise kinematic positioning over long baselines. Atmospheric refraction becomes critical in the error budget, but progress has been made to use numerical weather models to derive tropospheric corrections, for instance. The spatial correlation of both ionospheric and tropospheric propagation delays is investigated in this paper and special attention is paid on the systematic error behavior of tropospheric refraction. The principles developed are applied to an extended reliability test of the ambiguities. Finally, it is demonstrated in positioning experiments that kinematic positioning retrieval with fixed ambiguities is actually possible for baselines between 150 and 300 km with an accuracy of approximately 2 cm in post-mission processing.

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Towards an Open Information Infrastructure for Disaster Research and Management: Data Management and Information Systems Inside DFNK

The development of new and better methods for preventing and managing natural disasters requires a variety of different data sets, covering the range from referenced data, e.g. topographic data and digital elevation models, to various kinds of thematic data, e.g. data about soil, vegetation and land usage as well as monitoring data like precipitation and water levels. So a well-organised data and information management and the implementation of a modern processing environment to acquire, store, analyse and visualise data were decisive for the success of the German Research Network Natural Disasters (DFNK). An information infrastructure was established to support data management and information flows inside the network. A web-based portal offers general information to the public and internal documents, data and software tools to the project community. A catalog service allows the overview of existing but distributed data scombined with flexible data retrieval. Based on internet technology and global standards these concepts contribute to a superior information infrastructure and finally substantiate to the development of Spatial Data Infrastructures (SDI). SDIs aim is to improve availability and usability of spatial data for the manifold application areas. Disaster management is one field depending on a very high level on high-quality data equipment, and on a working SDI.     

Eclogite-facies rocks in the Saxonian Erzgebirge,Germany: high pressure metamorphism under contrasting P-T conditions

The metamorphic sequences of the Saxonian Erzgebirge were thoroughly overprinted by a Variscan medium-pressure event under amphibolite facies conditions. However, eclogitic relics documenting an older high-pressure event are widespread. P-T conditions of the eclogite-facies metamorphism systematically decrease, over a distance of 50 km, from about >29 kbar/850°C, in the central part, to 20–24 kbar/650°C, in the westernmost part of the Erzgebirge crystalline complex. A distinct gap in P-T conditions exists between the central and the western Erzgebirge coinciding with the fault zone of the Flöha syncline. Therefore, the eclogitebearing sequences are assumed to represent at least two different nappe units. The lower-grade eclogite assemblages in the western Erzgebirge display a continuous metamorphic zonation with a gradual decrease of peak metamorphic temperatures towards the west. Assemblages formed in the stability field of coesite and thus indicating a regional ultra-high pressure metamorphism, are restricted to the central Erzgebirge, where they are widespread in the eclogites, but also present in metaacidic country rocks. The same high-temperature/high-pressure conditions, testifying to a burial of at least 100 km, were independently recorded for the ultramafic garnet pyroxenites associated with the eclogites of the central Erzgebirge. Mineral relics included in the eclogite phases and mineral assemblages formed by retrograde reactions permit reconstruction of the prograde and retrograde P-T paths in the different parts of the Erzgebirge crystalline complex.     

Spatial dispersion of Faraday rotation and its connexion with mode coupling

It is shown that the lack of linear polarization in the microwave radiation of solar bursts (reported in a earlier paper) may be explained by spatial dispersion of Faraday rotation. The maximum source diameter s without noticeable destruction of linear polarization is determined by the electron density and the magnetic field strength in the volume, where the linear polarization is generated. In the case where linear polarization is produced by the radiation source, s is smaller than only 20 km. In the other case where linear polarization is produced by mode coupling in a quasi-transverse magnetic field in the corona, the s-values are found to range from 10 to 6000 km, which is still much smaller than the generally adopted sizes of microwave burst sources. The second case has been investigated for several models of magnetic fields.     

Towards an integrated arid zone water management using simulation-based optimisation

For ensuring both optimal sustainable water resources management and long-term planning in a changing arid environment, we propose an integrated Assessment-, Prognoses-, Planning- and Management tool (APPM). The new APPM integrates the complex interactions of the strongly nonlinear meteorological, hydrological and agricultural phenomena, considering the socio-economic aspects. It aims at achieving best possible solutions for water allocation, groundwater storage and withdrawals including saline water management together with a substantial increase of the water use efficiency employing novel optimisation strategies for irrigation control and scheduling. To obtain a robust and fast operation of the water management system, it unites process modeling with artificial intelligence tools and evolutionary optimisation techniques for managing both water quality and quantity. We demonstrate some key components of our methodology by an exemplary application to the south Al-Batinah region in the Sultanate of Oman which is affected by saltwater intrusion into a coastal aquifer due to excessive groundwater withdrawal for irrigated agriculture. We show the effectiveness and functionality of a new simulation-based water management system for the optimisation and evaluation of different irrigation practices, crop pattern and resulting abstraction scenarios. The results of several optimisation runs indicate that due to contradicting objectives, such as profit-oriented agriculture versus aquifer sustainability only a multi-objective optimisation can provide sustainable solutions for the management of the water resources in respect of the environment as well as the socio-economic development.     

Numerical simulations of collisions in Keplerian systems

Computer simulations which were carried out for Keplerian collisional systems of 250 frictionless particles with a ratio of particle radius to mean semi-major axis of 0.001, confirm the theoretically predicted evolution very well until the thickness of the system is a few times the particle radius and the mass-point approximation becomes invalidated. Before this happens, the collisional contraction of denserregions can be observed. The local dispersions of the perihelia and ascending nodes diminish if the local mean orbit is not too close to a circle with zero inclination. When the mass-point approximation ceases to be valid, the system begins to expand, but with parameter values of our standard system this process is much slower than the simultaneously observed evolution toward grazing collisions which do not affect the orbital elements. Therefore, such systems are not dispersed into the space. If the ratio of particle radius to semi-major axis is larger, the expansion becomes faster and the contraction ceases earlier. In late evolutionary phases the thickness of the system remains essentially constant. At the end of the longest simulation (70 000 impacts) the centres of the particles were in a layer of thickness twice the radius of the particles. The cross-section of the system is often wave-like or irregular and may even include detached parts with their own mean plane. Accordingly the thickness as derived from the root-mean-square inclination of the whole system exceeds the true local thickness. The local dispersion of eccentricities may also be considerably smaller than the root-mean-square eccentricity of the whole system.     

A revision of soft proton scattering at grazing incidence and its implementation in the <Emphasis Type="SmallCaps">geant</Emphasis>4 toolkit

The scattering of soft protons inside the Wolter-type optics of X-ray observatories has been proven to concentrate these particles onto the focal plane instruments. The funneling of these protons increases the instrumental background and can also contribute to the degrading of the detectors. The instrumental background and degradation of the detector’s performance experienced by Chandra and XMM-Newton is significantly larger than what was expected on the basis of previous Monte Carlo simulations. For Chandra the main issue is the degradation of the energy resolution due to lattice displacements in the detectors. For XMM the contribution to the instrumental background is more significant. In between, new laboratory measurements as well as a revision of the theory are needed to correctly assess the impact of the environmental radiation for future missions. In this publication we present a Geant4 class that will allow future users to select between either theoretical models or measured data to simulate the scattering of soft protons at grazing angles. To develop this method, we revisit the theory of elastic scattering of protons on polished surfaces and implement these approaches into Geant4. We also implemented recently performed measurements using parts of eROSITA (extended ROentgen Survey with an Imaging Telescope Array) mirror shells as scattering targets as another scattering model to be used within the Geant4 toolkit.