Wetlands with controlled drainage and sub‐irrigation systems—modelling of the water balance

Over the past centuries, the agricultural use of wetlands in Central Europe has required interference with the natural wetland water balance. Often this has consisted of drainage measures alone. In low‐precipitation areas, it has also involved the operation of combined drainage and sub‐irrigation systems. Model studies conducted as part of planning processes, or with a view to finding out the impact of changing climate conditions on the water balance of wetlands, must take these facts into account. For this reason, a water balance model has been devised for wetlands whose water balance is governed by water resources management systems. It is based on the WBalMo model system. Special modules were integrated into WBalMo to calculate the water balance of wetland areas (WABI module) and to regulate inflow partitioning within the wetland (REGINF module). When calculating the water balance, the WABI module takes into account precipitation and potential evapotranspiration, groundwater levels below surface, soil types, land‐use classes, inflows via the running water system, and data for target water levels. It provides actual evapotranspiration, discharge into the running water system, and groundwater levels in the area. The example of the Spreewald, a major wetland area in north‐eastern Germany, was used to design and test the WBalMo Spreewald model. The comparison of measured and calculated water balance parameters of the wetland area confirms the suitability of the model for water balance studies in wetlands with complex water resources management systems. The results reveal the strong influence of water management on the water balance of such areas. The model system has proved to be excellently suited for planning and carrying out water management measures aimed at the sustainable development of wetlands. Furthermore, scenario analyses can be used to assess the impact of global change on the water balance of wetlands. Copyright © 2006 John Wiley & Sons, Ltd.     

A reexamination of the valley wind system in the Alpine Inn Valley with numerical simulations

Summary This paper presents idealized numerical simulations of the valley wind circulation in the Alpine Inn Valley, which are compared with existing data and are used to improve our dynamical understanding of the valley wind. The simulations have been performed with the Penn State/NCAR mesoscale model MM5. They use a high-resolution realistic topography but idealized large-scale conditions without any synoptic forcing to focus on the thermally induced valley wind system. The comparison with the available observations shows that this simplified set-up is sufficient to reproduce the essential features of the valley wind.The results show that the tributaries of the Inn Valley have a considerable impact on the along-valley mass fluxes associated with the valley wind circulation. The upvalley mass flux is found to increase where tributaries enter the Inn Valley from the north, that is, from the direction where the Alpine foreland is located. On the other hand, the upvalley mass flux is reduced at the junctions with southern tributaries because part of the upvalley flow is deflected into these tributaries. For the downvalley flow, the situation is essentially reversed, but the influence of the valley geometry on the flow structure is larger than for the upvalley flow. The most important feature is a lateral valley contraction near the valley exit into the Alpine foreland. It reduces the downvalley mass flux at low levels, so that the wind maximum in the interior of the valley is shifted to a fairly large distance from the ground. North of the valley contraction, however, the downvalley flow strongly accelerates and forms a pronounced low-level jet. A dynamical analysis indicates that this acceleration can be interpreted as a transition from subcritical to supercritical hydraulic flow. Another interesting feature is that the low-level jet maintains its structure for several tenths of kilometres into the Alpine foreland. This appears to be related to the fact that the lateral wind shear on the flanks of the jet is associated with a strong dipole of potential vorticity (PV). Due to the conservation properties of the PV, the downstream advection of the PV dipole leads to the formation of a band-like feature that decays fairly slowly.     

Evaluation of trace element availability from secondary metallurgical slag generated in steelmaking by sequential chemical extraction

During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg^?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg^?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.     

Seasonal residence and counterurbanization: the role of second homes in population redistribution in Finland

Since the late twentieth century, many developed countries have experienced population deconcentration, labelled as counterurbanization. There has been an academic discussion on the meaning, validity and universality of this concept, drivers of counterurbanization and its impacts on rural areas. To date, research on counterurbanization mostly apply static and discrete definitions of residence, migration and population, which is an increasingly simplistic view in the contemporary reality of a growing multitude of forms of mobility, often related to dual residence. Particularly large-scale quantitative studies on counterurbanization are confined by existing statistical practices. This paper attempts to overcome this obstacle and describe the transformation of the settlement system in Finland acknowledging the role of second home mobility. To achieve this goal, it introduces two alternative measures of population, seasonal and average population, and analyses their spatial dynamics between the years 1990 and 2010 based on georeferenced grid statistical data. The study finds that although registered population has been concentrating during the period in analysis, seasonal population has been increasingly dispersed due to the growing number of second homes. It shows that the counterurbanization process, though not noticed by conventional statistics, does occur in Finland, manifested by seasonal rather than permanent moves. The article concludes that various forms of mobility should be taken into account when analysing the urban–rural population dynamics and transformations of settlement systems as well as in rural development planning.     

Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge

In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes. Received: 4 January 1999 / Accepted: 20 April 2000     

Using ocean quahog (<Emphasis Type="Italic">Arctica islandica</Emphasis>) shells to reconstruct palaeoenvironment in Öresund,Kattegat and Skagerrak,Sweden

Shells of Arctica islandica collected between 1884 and 2004 from Öresund, Kattegat and Skagerrak (Swedish West Coast) were used to monitor local climate variations and the influence of human activities on the local environment. For this purpose, we analysed the growth, structure and chemical composition of these shells and compared them with shells collected from Kiel Bay, Norway and Iceland. The growth rate of the studied shells registers an NAO periodicity of ca 8 years. However, the observed signal is weak because of other environmental interferences that are either of natural or anthropogenic origin. For example, the oxygen isotope ratios show temperature fluctuation, but also the influx of low salinity water. Higher contents of S, N, Cu, Zn, As, Cd and P in shell portions formed during the last century are related to human activities such as mining and industrial development. Our study indicates that in order to use Arctica shells as archives of climate change it is necessary to study the full range of environmental data that is recorded in the shells by using a multi element and isotope approach in combination with different analytical techniques including investigation of growth rates and shell structure.