Estimation of pH optima and tolerances of diatoms in lake sediments by the methods of weighted averaging,least squares and maximum likelihood,and their use for the prediction of lake acidity

Ecological optima and tolerances with respect to autumn pH were estimated for 63 diatom taxa in 47 Finnish lakes. The methods used were weighted averaging (WA), least squares (LS) and maximum likelihood (ML), the two latter methods assuming the Gaussian response model.WA produces optimum estimates which are necessarily within the observed lake pH range, whereas there is no such restriction in ML and LS. When the most extreme estimates of ML and LS were excluded, a reasonably close agreement among the results of different estimation methods was observed. When the species with unrealistic optima were excluded, the tolerance estimates were also rather similar, although the ML estimates were systematically greater.The parameter estimates were used to predict the autumn pH of 34 other lakes by weighted averaging. The ML and LS estimates including the extreme optima produced inferior predictions. A good prediction was obtained, however, when prediction with these estimates was additionally scaled with inverse squared tolerances, or when the extreme values were removed (censored). Tolerance downweighting was perhaps more efficient, and when it was used, no additional improvement was gained by censoring. The WA estimates produced good predictions without any manipulations, but these predictions tended to be biased towards the centroid of the observed range of pH values.At best, the average bias in prediction, as measured by mean difference between predicted and observed pH, was 0.082 pH units and the standard deviation of the differences, measuring the average random prediction error, was 0.256 pH units.     

Monitoring of the nano-structure response of natural clay under mechanical perturbation using small angle X-ray scattering and digital image correlation

Acta Geotechnica - This paper introduces a new experimental method to monitor the evolving intra-particle, nanometre-scale response during hydro-mechanical tests on undisturbed wet clay samples...     

Turbulent viscosity and Λ-effect from numerical turbulence models

Homogeneous anisotropic turbulence simulations are used to determine off-diagonal components of the Reynolds stress tensor and its parameterization in terms of turbulent viscosity and Λ-effect. The turbulence is forced in an anisotropic fashion by enhancing the strength of the forcing in the vertical direction. The Coriolis force is included with a rotation axis inclined relative to the vertical direction. The system studied here is significantly simpler than that of turbulent stratified convection which has often been used to study Reynolds stresses. Certain puzzling features of the results for convection, such as sign changes or highly concentrated latitude distributions, are not present in the simpler system considered here. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Atmospheric methane,southern European vegetation and low-mid latitude links on orbital and millennial timescales

Pollen records from marine and terrestrial sequences in southern Europe reveal a strong coherence between changes in tree populations and atmospheric methane concentrations over the last 800 thousand years. Variations in the continental hydrological balance provide a link for the observed patterns, leading to concomitant changes in southern European vegetation, and low-latitude wetland extent and methane/volatile organic compound emissions, although additional contributions to the methane budget from extratropical sources are not excluded. Here we propose that the close coupling between low- and mid-latitude hydrological changes reflects shifts in the mean latitudinal position of the Intertropical Convergence Zone, which determines the extent to which southern Europe is dominated by subtropical or mid/high-latitude influences. This provides a conceptual framework within which to view vegetation variability in southern Europe on orbital and millennial timescales.     

Relevance of Deterministic Structures for Modeling of Transport: The Lauswiesen Case Study

Knowledge of site‐specific contaminant transport processes is an essential requirement for performing various tasks concerning the protection and management of groundwater resources. However, prediction of their behavior is often difficult, especially in heterogeneous aquifers because of the lack of information about flow‐ and transport‐governing subsurface structures and parameters. Hence, stochastic approaches have been developed and frequently used. However, extensive modeling studies on sedimentary structures have shown that consideration of hydrogeological subunits and their distribution can be essential for transport modeling. A case study from the intensely investigated Lauswiesen site is used to demonstrate that more accurate predictions are possible with improved knowledge of deterministic structures. Results of this case study using direct‐push injection logging (DPIL) provide a more reliable characterization of hydraulic conductivity than sieve and flow meter data.     

Cross-national patterns of governance mechanisms in nationally determined contributions (NDCs) under the Paris Agreement

ABSTRACT

The continuous submission and scaling-up of Nationally Determined Contributions (NDCs) constitutes a key feature of the Paris Agreement. In their NDCs, states propose governance mechanisms for implementation of climate action, in turn distinguishing appropriate roles for the state in climate governance. Clarity on Parties’ suggested roles for the state makes explicit assumptions on the premise of climate policy, in turn contributing to enhanced transparency in negotiations on the scaling-up of NDCs. This also speaks to ongoing debates on roles for the state in climate governance literature. This article identifies the governance mechanisms proposed by states in their NDCs and the roles for the state envisioned by those governance mechanisms, and also examines how cross-national patterns of roles for the state break or converge with conventional patterns of international politics. The analysis shows that states propose a plurality of roles, which to different extents may be complementary or conflictual. We conclude that income, region, and the Annexes under the United Nations Framework Convention on Climate Change (UNFCCC) are important for understanding suggested roles for the state, but that there are nuances to be further explored. We argue that this paper has three key findings: i) a majority of states rely on market mechanisms to implement their NDCs while rules on implementation and assessment of market mechanisms are still an outstanding issue in the negotiations, meaning that resolving this issue will be essential; ii) the process for evaluating and assessing qualitative governance mechanisms needs to be specified; and iii) increased awareness of differing views on the state’s roles makes explicit different perspectives on what constitutes an ambitious and legitimate contribution to combating climate change.

Key policy insights

• A majority of states (> 75%) envision the state as regulator (creating and strengthening legislation), market facilitator (creating and maintaining market structures), or facilitator (creating more favourable material conditions for climate-friendly behaviour).

• Greater awareness of differing views on roles for the state can increase understanding of different perspectives on ambition and legitimacy of contributions, in turn facilitating trust in negotiations.

• A distinction between substantive and procedural qualitative governance mechanisms and their function and interaction would facilitate the stocktaking dialogues.

     

Complexing capacity of the nutrient medium and its relation to inhibition of algal photosynthesis by copper

The toxic effect of copper on phytoplankton production is investigated in waters having different complexing capacities. It is demonstrated that a water’s complexing capacity does not guarantee that an equivalent amount of copper could be tolerated without adversely affecting algal production. Possible explanations for these findings are offered and discussed. It is deduced that ionic copper probably is already toxic to planktonic algae at concentrations of about 10^?10 mole/l.     

Petrographische und Kalium-Argon-Untersuchungen an basischen tertiären Vulkaniten zwischen Westerwald und Vogelsberg

Between the upper tertiary volcanic areas of Westerwald and Vogelsberg (central Western Germany) occur more than 40 isolated tertiary volcanic dikes, eroded necks, plugs and domes. Twelve of these volcanic rocks have been investigated petrographically and chemically and classified by means of their modal and chemical composition. Additional modal analyses have been performed on seven other volcanics. On seventeen volcanic occurences K-Ar-whole rock age determinations have been made. The K-Ar age determinations yield- with the exception of an olivine-nephelinite — values between 27 and 15 Ma. Regarding the known intervals of volcanic activities of the Westerwald- and Voge1sberg-areas, most of the examined volcanics can be related genetically with one of the adjacent volcanic areas. There seems to be no geographical overlapping of volcanics showing Westerwaldages and Vogelsberg-ages. A possible influence of excess-Ar-bearing phases (e. g. mantle xenoliths) and an Ar-loss of constituent matter of the groundmass have been estimated by additional age determinations of enriched samples. These influences — partially compensating each other — may shift the K-Ar whole rock age to a maximum of 5 % and thus do not exceed the dimension of the standard deviations. A distinct NNE-SSW-striking fault in the region between Marburg and Gießen is situated parallel with the eastern border of the “Rheinisches Schiefergebirge”. Volcanics showing Westerwald-age and Vogelsberg-age respectively reach this fault, but obviously do not overlap it. Relations between rock-type an rock age, as it has been observed for the volcanics of the northern Hessian Depression (Kreuzer et al. 1973;Wedepohl 1982) cannot be proved certainly. On the other hand, similar to the basaltic rocks of the northern Hessian Depression, the youngest volcanic product is an olivine-nephelinite (9 Ma).     

Mendigite,Mn2Mn2MnCa(Si3O9)2, a new mineral species of the bustamite group from the Eifel volcanic region,Germany

A new mineral, mendigite (IMA no. 2014-007), isostructural with bustamite, has been found in the In den Dellen pumice quarry near Mendig, Laacher Lake area, Eifel Mountains, Rhineland-Palatinate (Rheinland-Pfalz), Germany. Associated minerals are sanidine, nosean, rhodonite, tephroite, magnetite, and a pyrochlore-group mineral. Mendigite occurs as clusters of long-prismatic crystals (up to 0.1 × 0.2 × 2.5 mm in size) in cavities within sanidinite. The color is dark brown with a brown streak. Perfect cleavage is parallel to (001). D _calc = 3.56 g/cm³. The IR spectrum shows the absence of H₂O and OH groups. Mendigite is biaxial (–), α = 1.722 (calc), β = 1.782(5), γ = 1.796(5), 2V _meas = 50(10)°. The chemical composition (electron microprobe, mean of 4 point analyses, the Mn²⁺/Mn³⁺ ratio determined from structural data and charge-balance constraints) is as follows (wt %): 0.36 MgO, 10.78 CaO, 37.47 MnO, 2.91 Mn₂O₃, 4.42 Fe₂O₃, 1.08 Al₂O₃, 43.80 SiO₂, total 100.82. The empirical formula is Mn_2.00(Mn_1.33Ca_0.67) (Mn_0.50 ²⁺ Mn_0.28 ³⁺ Fe_0.15 ³⁺ Mg_0.07)(Ca_0.80 (Mn_0.20 ²⁺)(Si_5.57 Fe_0.27 ³⁺ Al_0.16O₁₈). The idealized formula is Mn₂Mn₂MnCa(Si₃O₉)₂. The crystal structure has been refined for a single crystal. Mendigite is triclinic, space group \(P\bar 1\); the unit-cell parameters are a = 7.0993(4), b = 7.6370(5), c = 7.7037(4) Å, α = 79.58(1)°, β = 62.62(1)°, γ = 76.47(1)°; V = 359.29(4) ų, Z = 1. The strongest reflections on the X-ray powder diffraction pattern [d, Å (I, %) (hkl)] are: 3.72 (32) (020), 3.40 (20) (002, 021), 3.199 (25) (012), 3.000 (26), (\(01\bar 2\), \(1\bar 20\)), 2.885 (100) (221, \(2\bar 11\), \(1\bar 21\)), 2.691 (21) (222, \(2\bar 10\)), 2.397 (21) (\(02\bar 2\), \(21\bar 1\), 203, 031), 1.774 (37) (412, \(3\bar 21\)). The type specimen is deposited in the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, registration number 4420/1.