Evolution of Heterogeneous Mixed Siliciclastic/Carbonate Aquifers Containing Metastable Sediments

Mixed carbonate and siliciclastic marine sediments commonly become freshwater aquifers in eastern coastal regions of the United States and many other global locations. As these deposits age, the carbonate fraction of the sediment is commonly removed by dissolution and the aquifer can become a solely siliciclastic system or contain zones or beds of pure quartz sand. During aquifer evolution, the sediment grain size characteristics, hydraulic conductivity, and porosity change. An investigation of these changes using mixed carbonate/siliciclastic sediment samples collected from a modern barrier island beach in southern Florida showed that the average mean grain diameter decreased with removal of the carbonate fraction, but the average hydraulic conductivity and porosity increased slightly, but not to statistical significance. This counterintuitive result occurs because of the change in the pore types from a combined shelter and intergranular pore system producing a dual porosity system in the mixed sediments to a single intergranular pore system in the siliciclastic sediment fraction. Within the mixed carbonate/siliciclastic sediment, in the pure carbonate fraction, large shell fractions form grain‐supported large pores, which become filled with sand‐sized quartz as the shell fragments decrease in size or as the sediment becomes compacted. The hydraulic conductivity increases because the shell fragments that were oriented perpendicular to flow caused an increase in the length of the flow path, or a larger scale tortuosity, compared with the flow through pure quartz sand.     

Dissolved iron(III) speciation in the high latitude North Atlantic Ocean

On voyages in the Iceland Basin in 2007 and 2009, we observed low (ca. 0.1 nM) total dissolved iron concentrations [dFe] in surface waters (<150 m), which increased with depth to ca. 0.2–0.9 nM. The surface water [dFe] was low due to low atmospheric Fe inputs combined with biological uptake, with Fe regeneration from microbial degradation of settling biogenic particles supplying dFe at depth. The organic ligand concentrations [L_T] in the surface waters ranged between 0.4 and 0.5 nM, with conditional stability constants (log K′_FeL) between 22.6 and 22.7. Furthermore, [L_T] was in excess of [dFe] throughout the water column, and dFe was therefore largely complexed by organic ligands (>99%). The ratio of [L_T]/[dFe] was used to analyse trends in Fe speciation. Enhanced and variable [L_T]/[dFe] ratios ranging between 1.6 and 5.8 were observed in surface waters; the ratio decreased with depth to a more constant [L_T]/[dFe] ratio in deep waters. In the Iceland Basin and Rockall Trough, enhanced [L_T]/[dFe] ratios in surface waters resulted from decreases in [dFe], likely reflecting the conditions of Fe limitation of the phytoplankton community in the surface waters of the Iceland Basin and the high productivity in the Rockall Trough.Below the surface mixed layer, the observed increase in [dFe] resulted in a decrease of the [L_T]/[dFe] ratios (1.2–2.6) with depth. This indicated that the Fe binding ligand sites became occupied and even almost saturated at enhanced [dFe] in the deeper waters. Furthermore, our results showed a quasi-steady state in deep waters between dissolved organic Fe ligands and dFe, reflecting a balance between Fe removal by scavenging and Fe supply by remineralisation of biogenic particles with stabilisation through ligands.     

Probabilistic assessment of annual repair rates in pipelines and of direct economic losses in water and sewage networks: application to Manizales,Colombia

A methodology for the development of fully probabilistic seismic risk assessments on water and sewage networks is presented in this paper together with a case study for the system of Manizales, Colombia. These kinds of assessments require the development of probabilistic seismic hazard analysis, the consideration of local site effects, when relevant, the assembly of databases to identify and characterize the exposed elements and the development and assignment of vulnerability models for each type of component. For the case of Manizales, a high-resolution exposure database has been developed (element by element, segment by segment) based on the information and data provided by the owner and operator of the network, Aguas de Manizales. Losses due to earthquakes are obtained after convoluting the hazard and vulnerability inputs in a fully probabilistic manner, using the state-of-the-art methodologies incorporated in the CAPRA risk assessment module. Several risk metrics such as the loss exceedance curve, the loss exceedance probabilities for different time frames and the average annual loss are obtained for the system as a whole as well as disaggregated by component. In addition, repair rates for the pipelines were also calculated. The risk results obtained in this study have been useful for the company in designing and implementing expansion and maintenance plans that explicitly account for seismic risk mitigation issues, as well as to explore and negotiate financial protection alternatives by means of risk transfer and retention schemes, thus becoming a valuable input in the continuous development of good disaster risk management practices in this city.     

The disruption and recovery of fish communities in the Indian River Lagoon, Florida, following two hurricanes in 2004

During the summer of 2004, four hurricanes (Charley, Frances, Ivan, and Jeanne) affected Florida between August 13 and September 27. Two storms (Frances: category 2 and Jeanne: category 3) made landfall in the southern portion of the Indian River Lagoon (IRL) on the east-central coast of Florida. The presence of Florida Fish and Wildlife Conservation Commission's long-term fisheries monitoring program in the IRL provided a unique opportunity to examine the effects of large tropical events on estuarine fish communities. Increased sampling efforts to monitor the effects of tropical disturbances on the fish community within the IRL and one of its major tributaries (St. Sebastian River) were initiated within days after the passing of the last hurricane (Jeanne). The objectives of the study were to characterize changes to the composition of the fish community within the lagoon and river immediately after the passage of two hurricanes, and to examine the recovery of the fish communities. Analyses indicated that immediately after the last hurricane passed, community diversity within the estuary decreased following these storms due to the absence of many marine species, whereas the fish community within the St. Sebastian River shifted to one containing a greater percentage of freshwater species. Recovery of the community structure to pre-hurricane conditions was evident within several weeks following the last hurricane, and by mid December 2004 (ca. 3 mo after the last storm), there was little difference between the pre-hurricane and post-hurricane fish communities.     

Late Cretaceous extension overprinting a steep belt in the Northern Calcareous Alps (Schesaplana, R?tikon, Switzerland and Austria)

The Triassic to Cretaceous sediment succession of the Lechtal Nappe in the western part of the Northern Calcareous Alps (NCA) has been deformed into large-scale folds and crosscut by thrust and extensional faults during Late Cretaceous (Eoalpine) and Tertiary orogenic processes. The following sequence of deformation is developed from overprinting relations in the field: (D1) NW-vergent folds related to thrusting; (D2) N–S shortening leading to east–west-trending folds and to the formation of a steep belt (Arlberg Steep Zone) along the southern border of the NCA; (D3) E–W to NE–SW extension and vertical shortening, leading to low-angle normal faulting and recumbent “collapse folds” like the Wildberg Syncline. D1 and D2 are Cretaceous in age and predate the Eocene emplacement of the Austroalpine on the Penninic Nappes along the Austroalpine basal thrust; the same is probably true for D3. Finally, the basal thrust was deformed by folds related to out-of-sequence thrusting. These results suggest that the NCA were at least partly in a state of extension during the sedimentation of the Gosau Group in the Late Cretaceous.     

Inflow and outflow from the accretion disc of the microquasar SS 433: UKIRT spectroscopy

A succession of near-infrared (near-IR) spectroscopic observations, taken nightly throughout an entire cycle of SS 433's orbit, reveal (i) the persistent signature of SS 433's accretion disc, having a rotation speed of  ∼500 km s⁻¹  , (ii) the presence of circumbinary disc recently discovered at optical wavelengths by Blundell, Bowler & Schmidtobreick (2008) and (iii) a much faster outflow than has previously been measured for the disc wind, with a terminal velocity of  ∼1500 km s⁻¹  . The increased wind terminal velocity results in a mass-loss rate of  ∼10⁻⁴ M_⊙ yr⁻¹  . These, together with the newly (upwardly) determined masses for the components of the SS 433 system, result in an accurate diagnosis of the extent to which SS 433 has super-Eddington flows. Our observations imply that the size of the companion star is comparable with the semiminor axis of the orbit which is given by     , where e is the eccentricity. Our relatively spectral resolution at these near-IR wavelengths has enabled us to deconstruct the different components that comprise the Brackett-γ (Brγ) line in this binary system, and their physical origins. With this line being dominated throughout our series of observations by the disc wind, and the accretion disc itself being only a minority (∼15 per cent) contribution, we caution against use of the unresolved Brγ line intensity as an 'accretion signature' in X-ray binaries or microquasars in any quantitative way.     

Multiphase lattice Boltzmann simulations for porous media applications

Over the last two decades, lattice Boltzmann methods have become an increasingly popular tool to compute the flow in complex geometries such as porous media. In addition to single phase simulations allowing, for example, a precise quantification of the permeability of a porous sample, a number of extensions to the lattice Boltzmann method are available which allow to study multiphase and multicomponent flows on a pore scale level. In this article, we give an extensive overview on a number of these diffuse interface models and discuss their advantages and disadvantages. Furthermore, we shortly report on multiphase flows containing solid particles, as well as implementation details and optimization issues.     

Options for accounting carbon sequestration in German forests

Background  

The Accra climate change talks held from 21–27 August 2008 in Accra, Ghana, were part of an ongoing series of meetings leading up to the Copenhagen meeting in December 2009. During the meeting a set of options for accounting carbon sequestration in forestry on a post-2012 framework was presented. The options include gross-net and net-net accounting and approaches for establishing baselines.     

Exploring possible connections between hydrological extreme events and climate change in central south Chile

Abstract

Motivated by recent extreme flow events in the Mataquito River located in the Mediterranean region of Chile, we performed a detailed trend analysis of critical hydroclimatic variables based on observed daily flow, precipitation and temperature within the basin. For the period 1976–2008, positive trends in temperature were observed, especially during spring and summer months. At the same time, we found negative trends in the frequency and intensity of precipitation, especially during spring months. We observed an increasing difference between average streamflow in the rainy season as compared to the snowmelt season. Part of this trend is caused by larger flows during autumn months, although no positive precipitation trends are observed for these months. Finally, significant reductions in minimum flow during spring/summer and a disproportionate concentration of high-flow events occurring in the last 10 years were also identified. These high-flow events tend to happen during autumn months, and are associated with high precipitation and high minimum temperatures. Based on a simple assessment of changes in irrigated agriculture and land use, we concluded that other non-climatic factors seem not to be as relevant to the detected flow trends. All these results are in accord with future climate change scenarios that show an increase in temperature, a reduction in average precipitation and a reduction in snow accumulation. Such future scenarios could seriously hamper the development of economic activities in this basin, exemplifying also a fate that may be shared by other similar basins in Chile and in other regions of the world.

Editor Z.W. Kundzewicz

Citation Vicuña, S., Gironás, J., Meza, F.J., Cruzat, M.L., Jelinek, M., Bustos, E., Poblete, D., and Bambach, N., 2013. Exploring possible connections between hydrological extreme events and climate change in central south Chile. Hydrological Sciences Journal, 58 (8), 1598–1619.