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331.
332.
333.
J.A. Saunders M.-K. Lee M. Shamsudduha P. Dhakal A. Uddin M.T. Chowdury K.M. Ahmed 《Applied Geochemistry》2008
Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO4 to stimulate metabolism of indigenous SO4-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO4, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO4 reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS2. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO4 reduction commenced but increased to pre-experiment level once SO4 reduction ended. In the ongoing experiment, both SO4 and Fe(II) were amended to groundwater to evaluate if FeS/FeS2 formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions. 相似文献
334.
Sewage water rich in P poses a threat to natural water systems. In households that are not connected to a sewer network, an easily maintained purification technique is needed to remove P from domestic waste waters. In the present study, the P retention properties of phlogopite-rich mine tailings were studied to determine whether the untapped tailings can be utilised in wastewater treatment for this purpose. On the basis of its chemical and mineralogical properties, this material, produced in the enrichment process of apatite ore in Siilinjärvi, Finland, can be assumed to act as a P sorbent. The P retention capacity and the P sorption mechanisms of phlogopite-rich tailings were studied with desorption–sorption isotherms and various chemical extractions. The impact of the artificial weathering of the material as well as the reaction time and particle size on P retention were also investigated. The fluctuating shape of the isotherm determined for the untreated material suggests the operation of several sorption mechanisms. The results imply that phlogopite-rich tailings retain P efficiently through specific sorption by amorphous Al and Fe oxides and possibly also by calcite present as an accessory mineral. Acidification of the material, extended reaction time and decrease in particle-size markedly increased the P retention. 相似文献
335.
Memorial landscapes: analytic questions and metaphors 总被引:1,自引:0,他引:1
Over the past two decades, geographers have probed the intersection of collective memory and urban space. Their sustained
interest in the subject reflects an understanding of the social condition of commemoration and the important role that space
plays in the process and politics of collective memory. Along with other critical social scientists, geographers envision
these public symbols as part of larger cultural landscapes that reflect and legitimate the normative social order. A review
of the extant literature indicates that geographers scrutinize memorial landscapes through three conceptual lenses that may
be understood via the metaphors of ‘text,’ ‘arena,’ and ‘performance.’ These metaphors are in turn mobilized through a series
of analytic questions that serve to identify the interests served and denied by landscape ‘texts,’ the ‘arenas’ in which they
are produced, and the ways in which they are enacted via ‘performance.’ This article’s synopsis of the subfield’s predominant
metaphors and its attendant questions contributes to the ongoing cultural geographic project of articulating and implementing
methods for interpreting landscapes as open-ended symbolic systems.
相似文献
Derek H. AldermanEmail: |
336.
Biaxial test simulations using a packing of polygonal particles 总被引:1,自引:0,他引:1
The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
337.
A.R. Salgueiro P. Freire vila H. Garcia Pereira J.M. Santos Oliveira 《Journal of Geochemical Exploration》2008,98(1-2):15
Based on an environmental geochemistry case study carried out in the neighbourhood of a W–Sn abandoned mine, the pollution in stream sediments was modelled through a Global Contamination Index. Such an index permits one to summarize the combination of deleterious elements in a single variable, obtained by the projection of samples onto the first axis of a PCASD (Principal Components Analysis of Standardized Data) applied to the entire n × p matrix containing the available concentrations of p = 16 elements in the set of n = 220 collected samples.In order to provide a sound basis for a coherent planning of the remediation process which will be put in operation in the affected area, it is necessary to balance the costs of reclaiming with the probabilities of exceeding the upper limits accepted for concentrations of environmentally harmful elements in sediments. Given these limits, they are back-transformed in the index values, providing a practical threshold between ‘clean’ and ‘contaminated’ samples. On the other hand, the minimum dimension of the cell to be reclaimed is restrained by the selected remediation process to be applied in the affected area. Hence, to meet the constraints of such a remediation process, it is required to estimate the probabilities of exceeding the index threshold in technologically meaningful sub-areas. For this end, the Indicator Block Kriging technique was applied, producing a series of maps where sub-areas to be reclaimed can be spotted for different probability levels. These maps, on which the decision making remediation agency can rely for its cost-benefit analysis, take into account both the spatial structure of ‘clean’ vs. ‘contaminated’ samples and the constraints of the reclaiming process. 相似文献
338.
The Nordic geological surveys: Geology for society in practice 总被引:1,自引:0,他引:1
Morten Smelror Andreas AhlstrФm Lena Ekelund Jens Morten Hansen Keijo Nenonen Anette K. Mortensen 《《幕》》2008,31(1):193-200
Since the mid-nineteenth century., when the first of the Nordic Geological Surveys were established, they have generated a substantial amount of information on the Earth's crust, its natural resources, its processes, and on the geological history of Nordic areas. The collective mission of the geological surveys is to carry out "Geology for Society", by doing research and providing services, and by making geological information and data easily accessible to all the varied end users in industry, government agencies, government institutes, public administrations, technical offices, academia and research institutes, as well as for private individuals. The present paper gives a brief overview of a few, selected, research areas and projects currently undertaken by the Nordic geological surveys. These serve as practical examples of how the Nordic geological surveys address important societal problems and challenges that require geological input for their solution. 相似文献
339.
Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process
with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al2O3 contents (60 and 70 mol%, respectively) and varying SiO2 plus B2O3 contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing
bulk B2O3 content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding
infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is
able to incorporate large amounts of boron into its structure (up to about 20 mol% B2O3 depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the
mullite structure in form of planar three-fold coordinated BO3 groups.
Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria 相似文献
340.
K. Vinod kumar R. C. Lakhera Tapas R. Martha R. S. Chatterjee A. Bhattacharya 《Environmental Geology》2008,55(4):789-799
Mass movements such as landslides in mountainous terrains are natural degradation processes and one of the most important
landscape-building factors. Varunawat Parbat overlooking Uttarkashi town witnessed a series of landslides on 23 September
2003 and the debris slides and rock falls continued for 2 weeks. This landslide complex was triggered due to the incessant
rainfall prior to the event, and its occurrence led to the blockage of the pilgrim route to Gangotri (source of the Ganges
river) and evacuation of thousands of people to safer places. Though there was no loss of lives due to timely evacuation,
heavy losses to the property were reported. High-resolution stereoscopic earth observation data were acquired after the incidence
to study the landslide in detail with emphasis on the cause of the landslide and mode of failure. Areas along the road and
below the Varunawat foothill region are mapped for landslide risk. It was found that the foothill region of the Varunawat
Parbat was highly disturbed by man-made activities and houses are dangerously located below steep slopes. The potential zones
for landslides along with the existing active and old landslides are mapped. These areas are critical and their treatment
with priority is required in order to minimise further landslide occurrences. 相似文献