A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

Mean crustal velocity: a critical parameter for interpreting crustal structure and crustal growth

Mean crustal velocity is a critical parameter for genesis of continental crystalline crust because it is a function of mean crustal composition and therefore may be used to resolve continental crustal growth in space and time. Although the best values of mean crustal velocity are determined from wide-angle reflection measurements, most studied here necessarily come from vertical averages in crustal refraction determinations. The mode of 158 values of mean crustal velocity is 6.3 km/s, a velocity which corresponds to a mean crustal composition of granodiorite to felsic quartz diorite; Archean crust may be slightly more mafic. Mean crustal velocities range from 5.8 to 7.0 km/s. The lowest values invariably are found in thermally disturbed rift zones and the highest values correspond to velocities in gabbro. Velocities in island arcs may be as low as 6.0 km/s but are typically 6.5–6.9 km/s which corresponds to andesitic composition; estimates of island arc composition are andesitic. If values of mean crustal velocity are not biased, this observation suggests that continental crust did not grow simply by addition of island arc material. Possibilities are that crust formed from fusion of island arcs and was later changed to more felsic composition by addition of material from the mantle or that the late Archean episode of major crustal growth did not involve processes similar to younger island arcs. Some crustal blocks might be changed in composition and thickness by such processes as underplating, interthrusting, necking and sub-crustal erosion. Specially designed experiments are suggested to determine this parameter so critical for understanding genesis of continental crust.     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: V. Palynological evidence for deforestation and increased erosion

Pollen spectra from seven short cores taken from deltaic sites in the central and northern parts of Lake Tanganyika provide information about vegetation changes around the lake during the last 5000 years. Pollen analysis was undertaken to understand the history and timing of catchment deforestation and its causal linkage to excess sedimentation and ecosystem change in Lake Tanganyika. The spectra are dominated by grass pollen at all levels in every core. Grass pollen percentage values range between 40 and 80%. Low values of arboreal pollen taxa (1–20%) were documented from most cores except core LT-98-2M. Core LT-98-2M represents the longest duration vegetation record of this study (close to 5000 years BP), and records the onset of increasingly arid conditions in the Late Holocene, especially after 500 A.D., with the probable replacement of forest by open grassland in the Mahale Mountains region. The pollen/spore content for other cores showed a consistent trend of a decrease in grass pollen and an increase in pteridophyte and forest indicator pollen taxa during the last few centuries, contemporaneous with other indications of increased watershed disturbance from forest clearing (especially isotopes and lake faunal change). The timing or strength of this trend is not tied to specific levels of watershed disturbance. However, increasing fern spore abundance does occur progressively later towards the south, where modern human population densities are lower. Although increasing fern spore abundance is consistent with a land-clearing hypothesis, the rising arboreal pollen percentages are seemingly counterintuitive. One possible explanation is that increasing arboreal pollen proportions reflects the recycling of abundant pollen of this type from rapidly eroding soils. Another likely explanation for this finding is that land clearing involved the replacement of miombo woodland, with its mixture of trees producing little pollen and understory grasses producing large amounts of pollen, by the present day cassava, banana, and legume agricultural systems, all of which are poor pollen producers. This shift in catchment vegetation would increase the relative contribution of Afromontane pollen transported long distances from the surrounding highland regions. This hypothesis is consistent with both the lack of correlation of palynological history with specific watershed deforestation attributes, as well as the broader historical record of human habitation in the Lake Tanganyika region. This study also highlights the need for both modern pollen transect data from the region and comparative cores from low elevation swamps or ponds (wetlands) in the region with smaller catchment areas.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.     

E (B-V) determination from an UV-visual two-colour diagram: O and B stars in the catalogue of stellar ultraviolet fluxes

We present here, for the O and B type stars in the Catalogue of Stellar Ultraviolet Fluxes, an approach which does not require a precise knowledge of spectral type and luminosity class for derivingE(B-V) colour excesses. The method is based on the use of an UV-visual two-colour diagram; galactic variations in the interstellar extinction law are analyzed and fully taken into account. Our results have been compared with those derived by using the differences between observed and intrinsic colours for stars with known spectral classification. The very good agreement in a large number of cases (94 per cent) demonstrates that our approach permits the derivation of reliable colour excess values for early type stars even if only a rough spectral classification is available.     

On molecules in sunspots

Spectra of umbrae of several sunspots in the wavelength region 4000–8000 Å scanned photoelectrically at the Göttingen Locarno Observatory were used in order to search for absorption lines of molecules. Several thousands of lines of known molecules were reidentifled (see Table II and Table III). Newly identified molecules are CoH, NiH and H₂O (see Table IV and Wöhl (1969a)). The Zeemann effect on molecular lines (of MgH and CaH; see Table V and Wöhl (1969b)) in spectra of umbrae was detected.     

First Byurakan Spectral Sky Survey. Stars of Late Spectral Types. XI. Zone -7° ≤ δ ≤ -3°

The eleventh list of faint late M and carbon type stars detected on the plates of the First Byurakan Spectral Survey in zone -7° -3° and covering about 1000 square degrees is presented. From 126 detected stars, 88 are newly discovered objects: they are 6 carbon stars, 8 carbon star candidates, and 74 M-type stars; among the latter 38 (26 PSC + 12 FSC) are unclassified IRAS sources, and one object is an unclassified ROSAT source. Distances to the 6 newly discovered early-type carbon stars are estimated. Equatorial coordinates, red magnitudes, and spectral classes determined from the Palomar E-charts are provided. The lack of optical counterparts on Palomar O and E maps for two detected late M-type stars indicates a large variability in brightnesses of these objects (amplitude not smaller than 7.0 magnitude).