Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.     

Upper Jurassic record of Polyphylloseris (Egypt, Northern Sinai)

Genus Polyphylloseris is a scleractinian colonial coral that has been established by d’Orbigny (1849) from the Neocomian of Yonne, France. The genus is characterized by having elevated domal calices that are mammillar or craterlike in shape and with porous confluent septa. Columella is absent or rudimentary, and the lower surface of the corallum is covered with a thick and wrinkled holotheca. Specimens having the above-mentioned characteristics have been collected from the Upper Jurassic Arousiah Member of the Masajid Formation (Callovian–Oxfordian) of Gebel Maghara, Northern Sinai, Egypt. They are characterized by having a cupolate colonial form and porous pennulate septa which reach 40–50 in number. Based on these characters and other characters such as density of septa, height, and width of mammillar calices, the studied material is attributed to a new species named Polyphylloseris magharensis. The new species is a first undoubted record of Polyphylloseris in the Jurassic. Previously recorded undoubted ages of the genus are Early and Late Cretaceous. The fewer number of septa and the smaller-sized and closer mammillar calices allow differentiation of the species from other species such as Polyphylloseris icaunensis d’Orbigny and Polyphylloseris convexa d’Orbigny.     

The use of tracers to assess drill-mud penetration depth into sandstone cores during deep drilling: method development and application

For the utilization of deep saline aquifers in the frame of geotechnical use, such as geological sequestration of CO₂, H₂ or energy storage, a baseline characterization of pristine reservoir rock cores is required to monitor changes in the indigenous microbial communities and pore fluids, and to study alterations in rock characteristics resulting from interaction with geological storage technologies. However, drilling procedures and technical fluids, particularly drill mud, are sources of core contamination. To measure the penetration of drill mud into the cores, three tracers (fluorescein, microspheres, and 4′,6-diamidino-2-phenylindole stained bacteria) were tested under laboratory conditions. The flow of drill mud into core samples was induced by applying uniaxial pressure differentials to the core, and the penetration depth was microscopically determined for each tracer. Fluorescein was extracted from the rock samples and quantified fluorometrically. The results indicate that all tested tracers are suitable for tracking drill-mud penetration. The actual penetration depth seems to be related to differences in mineral composition and texture as well as microfractures. Among all tested tracers, fluorescein labelling is the simplest, cheapest and most accurate method for analyzing the contamination of rock cores by technical fluids. The application of this tracer was successfully applied during two deep drilling campaigns at the CO₂ storage pilot site in Ketzin, Germany. The results highlight that the use of tracers is indispensable to ensure the quality of core samples for microbiological and biogeochemical analysis.     

Spatial analysis of morphometric indices: the case of Bolu pull-apart basin,western section of North Anatolian Fault System,Turkey

Advances in quality, acquisition and processing of high-resolution digital topography over the past decade have enabled geomorphologists to interpret topography in terms of tectonic processes in a quantitative and more objective way. This study defines the tectonic impact of the North Anatolian fault system (NAFS) on the evaluation and activity of the Bolu pull-apart basin using morphometric indices based on topographic maps. In this study, three different indices including valley floor width to height ratio (Vf), asymmetry factor (Af), and Stream Length Gradient Index (SL) are applied to the tectonic basin area. To detect the deviation from spatial randomness of applied indices, the weighted correlation coefficient Moran’s I is used, and results are interpreted at 99% confidence interval. According to the results, the tectonic impact of NAFS on the northern and western sides of the basin distinctly differs from one another. Clustered distribution of Vf and Af values on the southern side of the basin margin reveals that this side of the basin margin is tectonically more deformed compared with the northern side. The applied methodology reveals that the spatial analysis of the morphometric indices proved to be the effective tool in analyzing tectonic influence of the fault system on the opposite side of the basin margins.     

Geological and archaeological evidence for post– Roman earthquake surface faulting at Cibyra,SW Turkey

Abstract

The NE-SW-trending Burdur–Fethiye fault zone is one of the major active fault zones of southwestern Turkey and the ancient city of Cibyra is located on this zone. Segments of the Burdur–Fethiye fault zone have ruptured in the historical period and during the 20th century. A detailed investigation in the ancient city of Cibyra showed the presence of faults sinistrally offset sitting rows of the stadium up to 50 cm. In addition, there are broken corners of blocks, collapsed walls, broken columns, and tilted and toppled blocks in existing major buildings in the city centre. Field observations showed that fractures and associated damage at Cibyra Produced by a post-Roman earthquake, possibly during the 417-A.D.-earthquake which had an intensity of 9 on the MSK scale. © 2001 Éditions scientifiques et médicales Elsevier SAS.     

Geochemistry of Pliocene/Pleistocene basalts along the Central Anatolian Fault Zone (CAFZ), Turkey

Abstract

Pliocene-Pleistocene volcanism accompanied strike-slip-related transtensional deformation along the K?z?l?rmak fault segment of the Central Anatolian fault zone (CAFZ) in the west of ?ark??la (Sivas-central Turkey). These volcanic rocks are represented by alkali olivine basalts. They can be divided into four different sub-groups on the basis of their Zr, Nb, TiO₂ contents. A primitive mantle-normalized incompatible trace element diagram for four subgroups shows close similarity to typical OIB pattern. Some of the incompatible trace element ratios (Ce/Y, Zr/Nb, La/Ba, La/Nb) are also akin to OIB values. Highly fractionated REE patterns (La/Yb_N=24.7–9.2) with no Eu anomaly are the main features of the alkali basalts and are comparable to alkaline volcanism in continental rift zones. On the basis of Al₂O₃/TiO₂, Nb/Y, Zr/Y Zr/Nb ratios, the geochemical differences among four sub-groups can be explained by variable degrees of partial melting of compositionally similar mantle source. Th/Nb, Th/Y, Nb/Y ratios and the primitive mantle-normalized trace element diagram suggests significant amount of crustal involvement for most of the alkali olivine basalts erupted along the CAFZ. Rupture of the continental lithosphere by strike-slip-related transtensional deformation might have caused decompressional partial melting of the asthenospheric mantle and generating alkali olivine basalts in this region. © 2001 Éditions scientifiques et médicales Elsevier SAS.     

Paraglacial sedimentation and denudation processes in an Alpine valley of Switzerland. An approach to the quantification of sediment budgets

Abstract

As a result of recent drillings in the Walensee Valley (eastern Switzerland) a new facies model for the Quaternary filling of Alpine valleys has been developed. A detailed lithological model and some new radiocarbon dating allowed the calculation of regional sedimentation and denudation rates and their change during the Late- and Postglacial period. It is shown that these changes follow the paraglacial sedimentation model by Church and Ryder [1]. The absolute quantification of the sediment budgets between the Last Glaciation and today points to denudation rates in the order of 1.5 mm y^?1 for the catchment of the Lake of Walenstadt. This is 50 % higher than suggested from current tectonic and isostatic estimates up to now. In that case present day uplift of the Alps would not be in balance with denudation. © Elsevier, Paris     

Neogene basin development around Söke-Kuşadası (western Anatolia) and its bearing on tectonic development of the Aegean region

The AMS study has been performed on various types of the basement – Variscan granitic and surrounding – Mesozoic sedimentary rocks in the Velká Fatra Mountains, Tatric Superunit of the Central Western Carpathians. The Velká Fatra Mts. provides good opportunity for AMS study because of composite S-type and I-type granite character of pluton and clear relations to Mesozoic sedimentary rocks in the cover and nappe positions. The granitic massif consists of the three types of weakly magnetic peraluminous granites (350 – 340 Ma in age), ranging from two-mica granites to biotite granodiorites in composition and carrying accessory monazite and ilmenite; whereby they resemble common S-type and/or Ilmenite Series granite. This pre-existing granitic body was intruded by relatively young (304 Ma old) metaluminous to subaluminous, strongly magnetic (due to magnetite) tonalitic intrusion of the I-type and/or Magnetite Series granite. In all S-types investigated as well as in the I-type tonalite body, the magnetic fabrics are not uniform, but slightly variable within a body and differing from body to body. The magnetic fabrics in all granitic rocks can be classified as mostly magmatic in origin, only subordinately affected by ductile deformation. The Alpine overprint of the magnetic fabric of the Variscan granite frequent in the central areas of the Central Western Carpathians was only weak in the Velká Fatra Mts. and the magnetic fabrics of these granites thus mostly comprise the original Variscan magmatic fabrics. On the other hand, in the marginal parts of the Velká Fatra Mts. the magnetic fabrics in granites are locally conformable to the deformational magnetic fabrics in surrounding sedimentary rocks (Mesozoic in age) thus indicating at least local effects of the Alpine deformation. The magnetic fabrics in Mesozoic sedimentary rocks covering the crystalline basement are partially (Cover Formation) to entirely (Nappe Units) deformational in origin.     

Variations of Magnetic Bright Point Properties with Longitude and Latitude as Observed by Hinode/SOT G-band Data

Small-scale magnetic fields can be observed on the Sun in high-resolution G-band filtergrams as magnetic bright points (MBPs). We study Hinode/Solar Optical Telescope (SOT) longitude and latitude scans of the quiet solar surface taken in the G-band in order to characterise the centre-to-limb dependence of MBP properties (size and intensity). We find that the MBP’s sizes increase and their intensities decrease from the solar centre towards the limb. The size distribution can be fitted using a log–normal function. The natural logarithm of the mean (μ parameter) of this function follows a second-order polynomial and the generalised standard deviation (σ parameter) follows a fourth-order polynomial or equally well (within statistical errors) a sine function. The brightness decrease of the features is smaller than one would expect from the normal solar centre-to-limb variation; that is to say, the ratio of a MBP’s brightness to the mean intensity of the image increases towards the limb. The centre-to-limb variations of the intensities of the MBPs and the quiet-Sun field can be fitted by a second-order polynomial. The detailed physical process that results in an increase of a MBP’s brightness and size from Sun centre to the limb is not yet understood and has to be studied in more detail in the future.