Studies of multiple stellar systems – III. Modulation of orbital elements in the triple-lined system HD 109648

The triple-lined spectroscopic triple system HD 109648 has one of the shortest periods known for the outer orbit in a late-type triple, 120.5 d, and the ratio between the periods of the outer and the inner orbits is small, 22:1. With such extreme values, this system should show orbital element variations over a time-scale of about a decade. We have monitored the radial velocities of HD 109648 with the CfA Digital Speedometers for 8 yr, and have found evidence for modulation of some orbital elements. While we see no definite evidence for modulation of the inner binary eccentricity, we clearly observe variations in the inner and the outer longitudes of periastron, and in the radial velocity amplitudes of the three components. The observational results, combined with numerical simulations, allow us to put constraints on the orientation of the orbits.     

Numerical groundwater-flow modeling to evaluate potential effects of pumping and recharge: implications for sustainable groundwater management in the Mahanadi delta region,India

Process-based groundwater models are useful to understand complex aquifer systems and make predictions about their response to hydrological changes. A conceptual model for evaluating responses to environmental changes is presented, considering the hydrogeologic framework, flow processes, aquifer hydraulic properties, boundary conditions, and sources and sinks of the groundwater system. Based on this conceptual model, a quasi-three-dimensional transient groundwater flow model was designed using MODFLOW to simulate the groundwater system of Mahanadi River delta, eastern India. The model was constructed in the context of an upper unconfined aquifer and lower confined aquifer, separated by an aquitard. Hydraulic heads of 13 shallow wells and 11 deep wells were used to calibrate transient groundwater conditions during 1997–2006, followed by validation (2007–2011). The aquifer and aquitard hydraulic properties were obtained by pumping tests and were calibrated along with the rainfall recharge. The statistical and graphical performance indicators suggested a reasonably good simulation of groundwater flow over the study area. Sensitivity analysis revealed that groundwater level is most sensitive to the hydraulic conductivities of both the aquifers, followed by vertical hydraulic conductivity of the confining layer. The calibrated model was then employed to explore groundwater-flow dynamics in response to changes in pumping and recharge conditions. The simulation results indicate that pumping has a substantial effect on the confined aquifer flow regime as compared to the unconfined aquifer. The results and insights from this study have important implications for other regional groundwater modeling studies, especially in multi-layered aquifer systems.     

Removal of hazardous hexavalent chromium from aqueous solution using divinylbenzene copolymer resin

This paper presents the removal of hazardous hexavalent chromium from liquid waste streams using divinylbenzene copolymer resin Amberlite IRA 96. Important sorption parameters such as contact time, pH, resin dosage and initial metal concentration were studied at 30?°C. The kinetic study was conducted using pseudo-first and pseudo-second-order kinetics at 30?°C. The sorption process was found to be pH dependent. Maximum removal was obtained at pH 2 under optimized conditions. The sorption process was rapid and 99?% of the removal was achieved in first 30?min. The equilibrium data were fitted to both Langmuir and Freundlich models. The better regression coefficient (R ²) in Freundlich model suggests the multilayer sorption process. The value of Gibbs free energy for sorption process was found to be ?12.394?kJmol^?1. The negative value indicated the spontaneity of the sorption process. Scanning electron microscope and energy dispersive X-ray spectroscopy studies were conducted to find the role of surface morphology during sorption process. The Fourier transform infrared study was conducted to identify the functional groups responsible for interaction between the resin and chromium. Desorption and regeneration studies were also carried out.     

Mass-size distribution of PM10 and its characterization of ionic species in fine (PM2.5) and coarse (PM10−2.5) mode, New Delhi, India

Size distribution of PM₁₀ mass aerosols and its ionic characteristics were studied for 2 years from January 2006 to December 2007 at central Delhi by employing an 8-stage Andersen Cascade Impactor sampler. The mass of fine (PM_2.5) and coarse (PM_10?2.5) mode particles were integrated from particle mass determined in different stages. Average concentrations of mass PM₁₀ and PM_2.5 were observed to be 306 ± 182 and 136 ± 84 μg m^?3, respectively, which are far in excess of annual averages stipulated by the Indian National Ambient Air Quality Standards (PM₁₀: 60 μg m^?3 and PM_2.5: 40 μg m^?3). The highest concentrations of PM_10?2.5 (coarse) and PM_2.5 (fine) were observed 505 ± 44 and 368 ± 61 μg m^?3, respectively, during summer (June 2006) period, whereas the lower concentrations of PM_10?2.5 (35 ± 9 μg m^?3) and PM_2.5 (29 ± 13 μg m^?3) were observed during monsoon (September 2007). In summer, because of frequent dust storms, coarse particles are more dominant than fine particles during study period. However, during winter, the PM_2.5 contribution became more pronounced as compared to summer probably due to enhanced emissions from anthropogenic activities, burning of biofuels/biomass and other human activities. A high ratio (0.58) of PM_2.5/PM₁₀ was observed during winter and low (0.24) during monsoon. A strong correlation between PM₁₀ and PM_2.5 (r ² = 0.93) was observed, indicating that variation in PM₁₀ mass is governed by the variation in PM_2.5. Major cations (NH₄ ⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺) and anions (F^?, Cl^?, SO₄ ^2? and NO₃ ^?) were analyzed along with pH. Average concentrations of SO₄ ^2? and NO₃ ^? were observed to be 12.93 ± 0.98 and 10.33 ± 1.10 μg m^?3, respectively. Significant correlation between SO₄ ^2? and NO₃ ^? in PM_1.0 was observed indicating the major sources of secondary aerosol which may be from thermal power plants located in the southeast and incomplete combustion by vehicular exhaust. A good correlation among secondary species (NH⁺, NO₃ ^? and SO₄ ^2?) suggests that most of NH₄ ⁺ is in the form of ammonium sulfate and ammonium nitrate in the atmosphere. During winter, the concentration of Ca²⁺ was also higher; it may be due to entrainment of roadside dust particles, traffic activities and low temperature. The molar ratio (1.39) between Cl^? and Na⁺ was observed to be close to that of seawater (1.16). The presence of higher Cl^? during winter is due to western disturbances and probably local emission of Cl^? due to fabric bleaching activity in a number of export garment factories in the proximity of the sampling site.     

Time-series analysis of monthly rainfall data for the Mahanadi River Basin, India

Time series analysis has two goals, modeling random mechanisms and predicting future series using historical data. In the present work, a uni-variate time series autoregressive integrated moving average (ARIMA) model has been developed for (a) simulating and forecasting mean rainfall, obtained using Theissen weights; over the Mahanadi River Basin in India, and (b) simulating and forecasting mean rainfall at 38 rain-gauge stations in district towns across the basin. For the analysis, monthly rainfall data of each district town for the years 1901-2002 (102 years) were used. Theissen weights were obtained over the basin and mean monthly rainfall was estimated. The trend and seasonality observed in ACF and PACF plots of rainfall data were removed using power transformation (α=0.5) and first order seasonal differencing prior to the development of the ARIMA model. Interestingly, the ARIMA model (1,0,0)(0,1,1) 12 developed here was found to be most suitable for simulating and forecasting mean rainfall over the Mahanadi River Basin and for all 38 district town rain-gauge stations, separately. The Akaike Information Criterion (AIC), goodness of fit (Chi-square), R 2 (coefficient of determination), MSE (mean square error) and MAE (mea absolute error) were used to test the validity and applicability of the developed ARIMA model at different stages. This model is considered appropriate to forecast the monthly rainfall for the upcoming 12 years in each district town to assist decision makers and policy makers establish priorities for water demand, storage, distribution, and disaster management.     

Climate mean,variability and dominant patterns of the Northern Hemisphere wintertime mean atmospheric circulation in the NCEP CFSv2

In this study, the climate mean, variability, and dominant patterns of the Northern Hemisphere wintertime mean 200 hPa geopotential height (Z200) in a CMIP and a set of AMIP simulations from the National Centers for Environmental Prediction (NCEP) Climate Forecast System Version 2 (CFSv2) are analyzed and compared with the NCEP/NCAR reanalysis. For the climate mean, it is found that a component of the bias in stationary waves characterized with wave trains emanating from the tropics into both the hemispheres can be attributed to the precipitation deficit over the Maritime continent. The lack of latent heating associated with the precipitation deficit may have served as the forcing of the wave trains. For the variability of the seasonal mean, both the CMIP and AMIP successfully simulated the geographical locations of the major centers of action, but the simulated intensity was generally weaker than that in the reanalysis, particularly for the center over the Davis Strait-southern Greenland area. It is also noted that the simulated action center over Aleutian Islands was southeastward shifted to some extent. The shift was likely caused by the eastward extension of the Pacific jet. Differences also existed between the CMIP and the AMIP simulations, with the center of actions over the Aleutian Islands stronger in the AMIP and the center over the Davis Strait-southern Greenland area stronger in the CMIP simulation. In the mode analysis, the El Nino-Southern Oscillation (ENSO) teleconnection pattern in each dataset was first removed from the data, and a rotated empirical orthogonal function (REOF) analysis was then applied to the residual. The purpose of this separation was to avoid possible mixing between the ENSO mode and those generated by the atmospheric internal dynamics. It was found that the simulated ENSO teleconnection patterns from both model runs well resembled that from the reanalysis, except for a small eastward shift. Based on the REOF modes of the residual data, six dominant modes of the reanalysis data had counterparts in each model simulation, though with different rankings in explained variance and some distortions in spatial structure. By evaluating the temporal coherency of the REOF modes between the reanalysis and the AMIP, it was found that the time series associated with the equatorially displaced North Atlantic Oscillation in the two datasets were significantly correlated, suggesting a potential predictability for this mode.     

Gypsum Induced Strength Behaviour of Fly Ash-Lime Stabilized Expansive Soil

Physical and engineering properties of soil are improved with various binders and binder combinations. Fly ash and lime are commonly used to improve the properties of expansive soils. An attempt has been made, in this paper, to examine the role of gypsum on the physical and strength behaviour of fly ash-lime stabilized soil. The change in strength behaviour is studied at different curing periods up to 90 days, and the mechanism is elucidated through pH, mineralogical, microstructural and chemical composition study. The strength of soil-fly ash mixture has improved marginally with the addition of lime up to 4 % lime and with curing period for 28 day. Significant increase in strength has been observed with 6 % lime and enhanced significantly after curing for 90 days. The variations in the strength of soil with curing period is due to cation exchange and flocculation initially, and binding of particles with cementitious compounds formed after curing. With addition of 1 % gypsum to soil-fly ash-lime, the strength gain is accelerated as seen at 14 day curing. The accelerated strength early is due to formation of compacted structure with growth of ettringite needles within voids. However, strength at curing for 28 day has been declined due to annoyance of clay matrix with the increase in size of ettringite needle; and again increased after curing for 90 days. The rearrangement of clay matrix and suppression of sulphate effects with formation of cementitious compounds are observed and found to be the main responsible factors for strength recovered.     

Imaging of sand lens at a barrage site in the Indian Himalaya — a case study using cross-hole seismic tomography

Drilling at the barrage site of a hydropower project usually gives a reasonable picture of the sub-surface rock mass condition. However, when the overburden (OB) comprising river borne materials is very thick and the basement rock is deep, the drilling results become unreliable. In the present case, the depth to the granitic gneiss basement is 45m from the river level and the height of the proposed diversion barrage is only 24.5 m. For this reason, stripping of the overburden up to the basement is not considered feasible. Cross-borehole seismic tomography (CST) was carried out at the barrage site to investigate the inclusions and structure of the OB material in order to facilitate a foundation design suitable for permeable formation. Three sets of CST surveys were carried out up to a depth of 30 m between the three vertical boreholes that were prepared at the vertices of an equilateral triangle with a separation of 17.8 m. The tomograms precisely imaged the nature and disposition of the different constituents of the overburden material. A lens shaped low velocity layer (LVL) with seismic velocity V_p=2000–2500 ms^?1 was mapped at a depth of 14.5m from the surface. Hence, it was recommended to shift the barrage axis by 50 m towards the downstream side of the proposed axis. The outcome of this study proved valuable for the designer who finalised the foundation design. Successful application of CST in OB characterisation has reiterated the need of such studies for barrage site investigations particularly in the Himalayan terrain.     

Shear Wave Velocity Estimates through Combined Use of Passive Techniques in a Tectonically Active Area

We made an attempt to assess the shear wave velocity values V _S and, to a lesser extent, the V _P values from ambient noise recordings in an array configuration. Five array sites were situated in the close proximity to borehole sites. Shear wave velocity profiles were modeled at these five array sites with the aid of two computational techniques, viz. spatial autocorrelation (SPAC) and H/V ellipticity. Out of these five array sites, velocity estimates could be reliably inferred at three locations. The shear wave velocities estimated by these methods are found to be quite consistent with each other. The computed V _S values up to 30 m depth are in the range from 275 to 375 m/s in most of the sites, which implies prevalence of a low velocity zone at some pocket areas. The results were corroborated by evidence of site geology as well as geotechnical information.     

Estimation of crustal discontinuities from reflected seismic waves recorded at Shillong and Mikir Hills Plateau,Northeast India

In this study, an attempt is made to determine seismic velocity structure of the crust and upper mantle beneath the Shillong-Mikir Hills Plateau in northeast India region. The principle of the technique is to relate seismic travel times with crustal thickness above the Conrad and Moho discontinuities. Broadband digital waveforms of the local earthquakes make a precise detection of the seismic phases possible that are reflected at these discontinuities. The results show that the Conrad discontinuity is at 18–20 (±0.5) km beneath the Shillong-Mikir Hills Plateau and the Moho discontinuity is at 30 ± 1.0 km beneath the Shillong Plateau and at 35 ± 1.0 km beneath the Mikir Hills.