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31.
Darren F. Mark Paul F. Green John Parnell Simon P. Kelley Martin R. Lee Sarah C. Sherlock 《Geochimica et cosmochimica acta》2008,72(10):2510-2533
Geochemical analysis of bitumen- and hydrocarbon-bearing fluid inclusions from the Devonian-Carboniferous Clair field indicates that the reservoirs contain a mixture of oils from different marine and lacustrine sources. Reconstruction of the Clair field oil-charge history using fluid inclusion petrography show that oil-charging occurred at times of K-feldspar, quartz and calcite cementation. Temperature–composition–time data yielded from the integration of fluid inclusion microthermometry with high-resolution Ar–Ar dating, date hydrocarbon-bearing K-feldspar overgrowths at 247 ± 3.3 Ma. These data show that in order for oil to be trapped within primary fluid inclusions in K-feldspar overgrowths, hydrocarbon migration throughout the UK Atlantic margin must have been taking place during the Late Palaeozoic and as such, current industry oil-play models based solely on oil charging from Jurassic-Cretaceous marine sources are clearly incomplete and need revision. Apatite fission track analysis and vitrinite reflectance data were used to reconstruct thermal burial histories and assess potential oil generation from Middle Devonian lacustrine source rocks. Thermal history data from wells along The Rona Ridge adjacent to the Clair field show that the Palaeozoic section was heated to greater than 100 °C at some time between 270 and 230 Ma, confirming that Devonian source rocks were mature and expelling oil during the Late Palaeozoic at the time that authigenic K-feldspar overgrowths were growing in the Clair field. 相似文献
32.
John F. Rudge Marian B. Holness Graham C. Smith 《Contributions to Mineralogy and Petrology》2008,156(4):413-429
The spatial distribution of grains in a solidifying igneous rock controls the physical properties of the crystal mush, and
in turn is controlled by the rate of crystal growth and accumulation. A predominant non-spherical habit for igneous minerals
brings into question the use of spherical particles in reference packings used for quantification of spatial distribution.
Furthermore, variations of crystal clustering/ordering with length scale require spatial statistics which take into account
the distribution of particles beyond nearest neighbours. Using random close packings of spherocylinders, we demonstrate the
importance of aspect ratio for the aggregation index (usually known as R) and show that packings of spherical particles have more structure than packings of rods. The spatial distribution functions
demonstrate that the plagioclase grains in the colonnade from the Holyoke basalt are clustered on a length scale of 0.5 mm.
Understanding the controls on grain spatial distribution in igneous rocks will depend on the application of these techniques
to well-understood environments. 相似文献
33.
This paper discusses the provision of water and sanitation services and the related urban impacts in Buenos Aires circa 2005. The first part of the paper focuses on the metropolitan region (BAMR) which is larger than the area served by the Aguas Argentinas S.A. (AASA) concession (i.e. the capital and its conurbano). It highlights a form of institutional fragmentation that is reflected in the diverse management practices of the numerous service providers and results in differentiated levels of and access to services. The paper discusses the technical, economic and regulatory factors that have historically resulted in this institutional fragmentation. The second part of the article focuses on AASA’s water concession agreement. It demonstrates that, although the agreement had an in-built splintering logic, its implementation led to a more “integrated approach” based on the “reality on the ground”. On the whole, the conclusion regarding the application of the splintering urbanism concept to Buenos Aires is a mixed one and depends on the scale of observation. Although at regional level (BAMR), a form of “institutional fragmentation” would appear to be obvious, it is the result of a long and complex historical process and, while recent neo-liberal reforms in service provisions have “cemented” this fragmentation, they did not actually cause it. If we take the AASA service area in isolation, the trend in the decade following the contracting out of the service has been one of improved service provision and access—although this was not achieved through increased integration of the supply system. Finally, in the case of the Buenos Aires metropolitan region, the splintering urbanism thesis defended by Marvin and Graham needs to be nuanced in several significant ways. 相似文献
34.
The analysis of the history of the management and distribution of electricity, water and sanitation networks in Santiago de Chile throws light on a problem which is central to thinking on the relationship between urban services management and territorial splintering: what is the impact of urban policy, in particular housing policy and urban planning, on access to services and on the potential levels of social segregation and institutional splintering of metropolises?The Chilean example is eminently anchored in its political and institutional history. We shall see, for example, that the authoritarian urban policy of the military government, associated with early liberal reform, enabled the improvement of access to networks in every municipality of the Greater Santiago area. However, this success, leading to the integration by urban services of a large territory, does not signify that networks remained neutral as regards the process of spatial segregation. Inversely, we can defend the theory that the presence of an integrated service was a necessary condition and a reinforcing factor of the process of urban spread and residential segregation. This paradoxical argument is a result of the ambivalent liberal network and urban policies of the military government. Urban expansion was largely sustained by the development of integrated infrastructures and universal services. The processes of liberalising land and urban services were mutually sustaining and provided the necessary conditions for the birth of an extremely intense movement of urban sprawl and segregation between 1985 and 2000. 相似文献
35.
Martin R. Lee Mark E. Hodson Maureen MacKenzie Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975
Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction. 相似文献
36.
Adam Stuart Smith 《Geology Today》2008,24(2):71-75
Plesiosaurs are an unusual and intriguing group of extinct aquatic reptiles ( Fig. 1 ). They are sauropterygians, a group known from an array of semi‐aquatic forms during the Triassic period: placodonts, pachypleurosaurs and nothosaurs. The first plesiosaurs are known from the very latest Triassic, but by the Early Jurassic plesiosaurs were cosmopolitan in distribution and lasted successfully to the latest Cretaceous, when they became victims of the K‐T extinction event. Plesiosaurs were predominantly marine organisms, although their fossils are not uncommon in brackish or even fresh water deposits. We know that all plesiosaurs were carnivorous; many of them were top predators in their respective ecosystems. But with no living descendants (or analogues) plesiosaurs are mysterious fossil organisms—as we will see, many questions regarding their biology remain unanswered or contentious. However, plesiosaurs are currently undergoing renewed scientific attention.
37.
Ramesh Sivanpillai X. Ben Wu R. Srinivasan Charles T. Smith Michael G. Messina 《GeoJournal》2008,71(4):211-220
Comparing satellite data derived map products are affected by differences in data characteristics, image acquisition dates,
processing techniques, and classification schemes used for assigning pixels to a thematic class. By comparing two forest maps
generated from Landsat Enhanced Thematic Mapper Plus (ETM+) and Advanced Very High Resolution Radiometer (AVHRR) images acquired
on the same day, and processed using identical classification scheme and methods these differences were minimized. The ETM+
derived map had higher classification accuracy values and more precise area estimates than the AVHRR derived map. In the ETM+
derived map, 87 of the 599 verification data were misclassified, whereas in the AVHRR derived map, 155 of the 469 verification
data were misclassified. Detailed error analyses by land cover class revealed that a land use based definition of forest accounted
for 74% (64 out of 87) and 57% (89 out of 155) of the classification errors in ETM+ and AVHRR derived maps, respectively. 相似文献
38.
Eduardo E. Alonso Sarah M. Springman Charles W. W. Ng 《Geotechnical and Geological Engineering》2008,26(6):817-826
Two large-scale “in situ” demonstration experiments and their instrumentation are described. The first test (FEBEX Experiment)
involves the hydration of a compacted bentonite barrier under the combined effect of an inner source of heat and an outer
water flow from the confining saturated granite rock. In the second case, the progressive de-saturation of Opalinus clay induced
by maintained ventilation of an unlined tunnel is analyzed. The paper shows the performance of different sensors (capacitive
cells, psychrometers, TDR’s) and a comparison of fill behaviour with modelling results. The long term performance of some
instruments could also be evaluated specially in the case of FEBEX test. Capacitive sensors provide relative humidity data
during long transient periods characterised by very large variations of suction within the bentonite. 相似文献
39.
F. Shuttleworth
J. Wardley Smith
《Marine pollution bulletin》1971,2(12):191-19240.
G. R. Cooper G. Petrie A. D. N. Smith M. Sowton K. B. Atkinson 《The Photogrammetric Record》1969,6(33):239-258
The International Society for Photogrammetry held the Xlth International Congress at Lausanne during July 1968. The authors review the activities of five of the seven I.S.P. Commissions. 相似文献