Effects of humic substances on Fe(II) sorption onto aluminum oxide and clay

We studied the effects of humic substances (HS) on the sorption of Fe(II) onto Al-oxide and clay sorbents at pH 7.5 with a combination of batch kinetic experiments and synchrotron Fe K-edge EXAFS analyses. Fe(II) sorption was monitored over the course of 4 months in anoxic clay and Al-oxide suspensions amended with variable HS types (humic acid, HA; or fulvic acid, FA) and levels (0, 1, and 4 wt%), and with differing Fe(II) and HS addition sequences (co-sorption and pre-coated experiments, where Fe(II) sorbate was added alongside and after HS addition, respectively). In the Al-oxide suspensions, the presence of HS slowed down the kinetics of Fe(II) sorption, but had limited, if any, effect on the equilibrium aqueous Fe(II) concentrations. EXAFS analyses revealed precipitation of Fe(II)–Al(III)-layered double hydroxide (LDH) phases as the main mode of Fe(II) sorption in both the HA-containing and HA-free systems. These results demonstrate that HS slow down Fe(II) precipitation in the Al-oxide suspensions, but do not affect the composition or stability of the secondary Fe(II)–Al(III)-LDH phases formed. Interference of HS with the precipitation of Fe(II)–Al(III)-LDH was attributed to the formation organo-Al complexes HS limiting the availability of Al for incorporation into secondary layered Fe(II)-hydroxides. In the clay systems, the presence of HA caused a change in the main Fe(II) sorption product from Fe(II)–Al(III)-LDH to a Fe(II)-phyllosilicate containing little structural Al. This was attributed to complexation of Al by HA, in combination with the presence of dissolved Si in the clay suspension enabling phyllosilicate precipitation. The change in Fe(II) precipitation mechanism did not affect the rate of Fe(II) sorption at the lower HA level, suggesting that the inhibition of Fe(II)–Al(III)-LDH formation in this system was countered by enhanced Fe(II)-phyllosilicate precipitation. Reduced rates of Fe(II) sorption at the higher HA level were attributed to surface masking or poisoning by HA of secondary Fe(II) mineral growth at or near the clay surface. Our results suggest that HS play an important role in controlling the kinetics and products of Fe(II) precipitation in reducing soils, with effects modulated by soil mineralogy, HS content, and HS properties. Further work is needed to assess the importance of layered Fe(II) hydroxides in natural reducing environments.     

Structures and morphotectonic evolution of the frontal fold–thrust belt,Kameng river section,Arunachal Himalaya,India

The Neogene–Quaternary Siwalik foreland fold and thrust belt is studied for better understanding of tectonics along the Kameng river section of Arunachal Pradesh, India. The Kimi, Dafla, Subansiri, and the Kimin Formation correspond to Lower, Middle and Upper Siwaliks, respectively. The lithology in the foreland basin is dominantly sandstones, siltstones, claystones, carbonaceous shales, and boulder beds in the upper part. The structural style of the sedimentary sequence from the Main Boundary Thrust southward shows first order ramp-flat geometry. The brittle shear transfers slip across glide horizons to shallower depth. Repeated splay generations from a major regional-scale floor transfers slip from one glide horizon to another that shortens and thickens the crust. In the micro-scale, the lithological response in the structural development is well documented as pressure solution seams and other diagenetic deformation signatures. The basement asperity plays a significant role as the moving thrust front produced a major lateral ramp. The differential movement of the mountain front on both sides of the ramp is decipherable. This is especially true at the western part of the SE flowing Kameng river. The tectonic evolution of the area initiated with slip along the MBT \(\sim \)11 Ma ago along with the deposition of the Siwalik sediments. With southward propagation of the mountain front, the foreland basin shifted towards S, produced splay thrusts from the Himalayan Frontal Thrust-1 (HFT-1), which has been uplifting the Kimin and the older terraces.     

Assessment of citrus crop condition in Umling block of Ri-Bhoi district using RS and GIS technique

Orange orchards of Meghalaya are small in size and are found together with other plants on the slopes of hills. It is also reported that the productivity of orchards is declining in some parts of the state. Therefore in this study, we have attempted to map areas prone to citrus productivity decline based on the integrated effect of soil erosion, vegetation condition and moisture stress. It is difficult to identify orchards on hilly terrain using standard FCC of IRS-P6 LISS III data. Hence, an enhanced color composite image was prepared from three images generated from indices namely SBI, NDWI and NDVI. This enhanced color image was classified using the maximum likelihood classification method and enabled identifying villages prone to citrus decline. The study shows that orchards of 29 villages which are suffering from moisture stress and mostly located on steep slopes that cause heavy soil loss leading to nutrient imbalances are prone to citrus decline. These data will be useful in mapping potential citrus decline areas over zones having similar climatic conditions so that the concerned state horticulture/agriculture departments and citrus growers can take necessary remedial actions.     

Boreal summer intraseasonal oscillations and seasonal Indian monsoon prediction in DEMETER coupled models

Even though multi-model prediction systems may have better skill in predicting the interannual variability (IAV) of Indian summer monsoon (ISM), the overall performance of the system is limited by the skill of individual models (single model ensembles). The DEMETER project aimed at seasonal-to-interannual prediction is not an exception to this case. The reasons for the poor skill of the DEMETER individual models in predicting the IAV of monsoon is examined in the context of the influence of external and internal components and the interaction between intraseasonal variability (ISV) and IAV. Recently it has been shown that the ISV influences the IAV through very long breaks (VLBs; breaks with duration of more than 10 days) by generating droughts. Further, all VLBs are associated with an eastward propagating Madden–Julian Oscillation (MJO) in the equatorial region, facilitated by air–sea interaction on intraseasonal timescales. This VLB-drought–MJO relationship is analyzed here in detail in the DEMETER models. Analyses indicate that the VLB-drought relationship is poorly captured by almost all the models. VLBs in observations are generated through air–sea interaction on intraseasonal time scale and the models’ inability to simulate VLB-drought relationship is shown to be linked to the models’ inability to represent the air–sea interaction on intraseasonal time scale. Identification of this particular deficiency of the models provides a direction for improvement of the model for monsoon prediction.     

Eastward propagating MJO during boreal summer and Indian monsoon droughts

Improved understanding of underlying mechanism responsible for Indian summer monsoon (ISM) droughts is important due to their profound socio-economic impact over the region. While some droughts are associated with ‘external forcing’ such as the El-Niño and Southern Oscillation (ENSO), many ISM droughts are not related to any known ‘external forcing’. Here, we unravel a fundamental dynamic process responsible for droughts arising not only from external forcing but also those associated with internal dynamics. We show that most ISM droughts are associated with at least one very long break (VLB; breaks with duration of more than 10 days) and that the processes responsible for VLBs may also be the mechanism responsible for ISM droughts. Our analysis also reveals that all extended monsoon breaks (whether co-occurred with El-Niño or not) are associated with an eastward propagating Madden–Julian Oscillation (MJO) in the equatorial Indian Ocean and western Pacific extending to the dateline and westward propagating Rossby waves between 10° and 25°N. The divergent Rossby wave associated with the dry phase of equatorial convection propagates westward towards Indian land, couple with the northward propagating dry phase and leads to the sustenance of breaks. Thus, the propensity of eastward propagating MJO during boreal summer is largely the cause of monsoon droughts. While short breaks are not accompanied by westerly wind events (WWE) over equatorial western Pacific favorable for initiating air–sea interaction, all VLBs are accompanied by sustained WWE. The WWEs associated with all VLB during 1975–2005 initiate air–sea interaction on intraseasonal time scale, extend the warm pool eastward allowing the convectively coupled MJO to propagate further eastward and thereby sustaining the divergent circulation over India and the monsoon break. The ocean–atmosphere coupling on interannual time scale (such as El-Niño) can also produce VLB, but not necessary.     

Possible role of warm SST bias in the simulation of boreal summer monsoon in SINTEX-F2 coupled model

Reasonably realistic climatology of atmospheric and oceanic parameters over the Asian monsoon region is a pre-requisite for models used for monsoon studies. The biases in representing these features lead to problems in representing the strength and variability of Indian summer monsoon (ISM). This study attempts to unravel the ability of a state-of-the-art coupled model, SINTEX-F2, in simulating these characteristics of ISM. The coupled model reproduces the precipitation and circulation climatology reasonably well. However, the mean ISM is weaker than observed, as evident from various monsoon indices. A wavenumber–frequency spectrum analysis reveals that the model intraseasonal oscillations are also weaker-than-observed. One possible reason for the weaker-than-observed ISM arises from the warm bias, over the tropical oceans, especially over the equatorial western Indian Ocean, inherent in the model. This warm bias is not only confined to the surface layers, but also extends through most of the troposphere. As a result of this warm bias, the coupled model has too weak meridional tropospheric temperature gradient to drive a realistic monsoon circulation. This in turn leads to a weakening of the moisture gradient as well as the vertical shear of easterlies required for sustained northward propagation of rain band, resulting in weak monsoon circulation. It is also noted that the recently documented interaction between the interannual and intraseasonal variabilities of ISM through very long breaks (VLBs) is poor in the model. This seems to be related to the inability of the model in simulating the eastward propagating Madden–Julian oscillation during VLBs.     

Tectonic controls on the geomorphic evolution of alluvial fans in the Piedmont Zone of Ganga Plain,Uttarakhand, India

The Piedmont Zone is the least studied part of the Ganga Plain. The northern limit of the Piedmont Zone is defined by the Himalayan Frontal Thrust (HFT) along which the Himalaya is being thrust over the alluvium of the Ganga Plain. Interpretation of satellite imagery, Digital Terrain Models (DTMs) and field data has helped in the identification and mapping of various morphotectonic features in the densely forested and cultivated Piedmont Zone in the Kumaun region of the Uttarakhand state of India. The Piedmont Zone has formed as a result of coalescing alluvial fans, alluvial aprons and talus deposits. The fans have differential morphologies and aggradation processes within a common climatic zone and similar litho-tectonic setting of the catchment area. Morphotectonic analysis reveals that the fan morphologies and aggradation processes in the area are mainly controlled by the ongoing tectonic activities. Such activities along the HFT and transverse faults have controlled the accommodation space by causing differential subsidence of the basin, and aggradation processes by causing channel migration, channel incision and shifting of depocentres. The active tectonic movements have further modified the landscape of the area in the form of tilted alluvial fan, gravel ridges, terraces and uplifted gravels.     

Urban air pollution: process identification, impact analysis and evaluation of forecast potential

The daily variations in the atmospheric pollutants like suspended particulate matter (SPM), respirable suspended particulate matter (RSPM), sulphur dioxide (SO₂) and nitrogen dioxide (NO₂) depend on both local meteorological processes and various natural as well as anthropogenic sources and sinks. It was shown in an earlier work (Goswami and Baruah in Mon Wea Rev 136(9):3597?C3607, 2008) that the daily variations in SPM over a location could be simulated quite well by considering daily meteorological fields from NCEP Reanalysis in combination with a model for natural and anthropogenic sources over Delhi. In the present work, we extend the scope of the model to include three other pollutants: RSPM, SO₂ and NO₂. While the basic conservation equations and the meteorological fields are common to all the three (and SPM) pollutants, the sources and sinks for each is modeled in a species-specific manner to obtain maximum skill. As we do not consider active chemistry, the present model provides the minimal dynamics of pollution over an urban location in terms of annual load; the model error is about 10% on the average, with no significant bias for any of the species.     

http://www.sciencedirect.com/science/article/pii/S1674987113001345

Many elongated, lenticular plutons of porphyritic granitoids are distributed mainly near the southern and northern margin of the Chhotanagpur Gneissic Complex （CGC） which belongs to the EW to ENE-WSW tending 1500 km long Proterozoic orogenic belt amalgamat ng the North and South Indian cratonic blocks. The late Grenvillian （1071 ±64 Ma） Raghunathpur porphyritic granitoid gneiss （PGG） batholith comprising alkali feldspar granite, granite, granodiorite, tonalite, quartz syenite and quartz monzonite intruded into the granitoid gneisses of southeastern part of CGC in the Purulia district, West Bengal and is aligned with ENE-WSW trending North Purulia sr~ear zone, Mineral chemistry, geochemistry, physical condition of crystallization and petrogenetic model of Raghunathpur PGG have been discussed for the first time. The petrographic and geochemical features （including major and trace- elements, mineral chemistry and S7Sr/S6Sr ratio） suggest these granitoids to be classified as the shosh- onitic type. Raghunathpur batholith was emplaced at around 800 ~C and at 6 kbar pressure tectonic discrimination diagrams reveal a post-collision tectonic setting while structural studies reveal its emplacement in the extensional fissure of North Purulia shear zone. l＇he Raghunathpur granitoid is compared with some similar granitoids of Europe and China to draw its petrogenetic model. Hybridi- zation of mantle-generated enriched mafic magma and crustal magma at lower crust and later fractional crystallization is proposed for the petrogenesis of this PGG. Mafic magma generated in a post-collisional extension possibly because of delamination of subducting slab. Raghunathpur batholith had emplaced in the CGC during the final amalgamation （~ 1.0 Ga） of the North and South Indian cratonic blocks. Granitoid magma, after its generation at depth, was transported to its present level along megadyke channel, ways within shear zones.