Geochronologic evidence for Early Cretaceous volcanic activity on Barton Peninsula, King George Island, Antarctica

Ages of six volcanic and plutonic rocks on Barton Peninsula, King George Island, were determined using ⁴⁰Ar/³⁹Ar and K-Ar isotopic systems. The ⁴⁰Ar/³⁹Ar and K-Ar ages of basaltic andesite and diorite range from 48 My to 74 My and systematically decrease toward the upper stratigraphic section. Two specimens of basaltic andesite which occur in the lowermost sequence of the peninsula, however, apparently define two distinct plateau ages of 52-53 My and 119-120 My. The latter is interpreted to represent the primary cooling age of basaltic andesite, whereas the former is interpreted as the thermally-reset age caused by the intrusion of Tertiary granitic pluton. The isochron ages calculated from the isotope correlation diagram corroborate our interpretation based on the apparent plateau ages. It is therefore likely that volcanism was active during the Early Cretaceous on Barton Peninsula. When the K-Ar ages of previous studies are taken into account with our result, the ages of basaltic andesite in the northern part of the Barton Peninsula are significantly older than those in the southern part. Across the north-west-south-east trending Barton fault bounding the two parts, there are significant differences in geochronologic and geologic aspects.     

Numerical and experimental studies on flow and pollutant dispersion in urban street canyons

In this study numerical simulations and water tank experiments were used to investigate the flow and pollutant dispersion in an urban street canyon. Two types of canyon geometry were tested. The studies indicate that in a step-up notch canyon （higher buildings on the downstream side of the canyon）, the height and shape of the upstream lower buildings plays an important role in flow pattern and pollutant dispersion, while in a step-down notch canyon （lower buildings on the downstream side）, the downstream lower buildings have little influence. The studies also show that the substitution of tall towers for parailelepiped buildings on one side of the canyon may enhance the street ventilation and decrease the pollutant concentration emitted by motor vehicles.     

Characteristics of the eddy caused by Izu-Oshima Island and the Kuroshio branch current in Sagami Bay,Japan

Direct current measurements of the branch current of the Kuroshio intruding into Sagani Bay were carried out during 1989–1990 in order to clarify the frequency characteristics of the eddies in the lee of Izu-Oshima Island, which are well recognized as cold water mass produced by upwelling. Satellite and ADCP (Acoustic Doppler Current Profiler) data indicated that current velocity in the eddy fluctuates with periods of 2–4 days and 6–8 days.When the Kuroshio branch current intruding into Sagami Bay from the western channel is weak and its velocity at the depth of 400 m is approximately 10 cm s^–1, the 6–8 day period fluctuation is dominant. On the other hand, when the branch current strongly intrudes from the western channel with a velocity of approximately 20 cm s^–1, the 2–4 day period fluctuation dominates. The relationship between the periods and velocities agrees well with theory based on laboratory experiments for a flow of a homogeneous fluid past a circular obstacle. These periods correspond to the time scale of appearance of the eddy caused by the intrusion of the Kuroshio branch current into Sagami Bay and Izu-Oshima Island.     

Microsomal cytochrome P-450 function in fish evaluated with polyclonal and monoclonal antibodies to cytochrome P-450E from scup (Stenotomus chrysops)

Monooxygenase reactions catalyzed by cytochromes P-450 are paramount in the oxidative metabolism of many xenobiotics, determining both the persistence and effects of numerous types of compounds. Immunological probes are proving useful in evaluating the functions of P-450 isozymes in microsomal preparations from many species. The regulation of specific isozymes by endogenous and exogenous factors can also be evaluated with such probes. Here we describe studies on the activities apparently catalyzed by induced P-450 in fish, evaluated with both polyclonal and monoclonal antibodies to cytochrome P-450E, the apparent major β-naphthoflavone(BNF) or methylcholanthrene(MC)-inducible isozyme purified from scup (S. chrysops) liver.     

Coupled BEM-FEM Analysis of the Large-Diameter Cylinder Structure System

A method of coupled BEM-FEM analysis for the elastic spatial structure system is presented. It can be applied to the calculation of the stress and deformation of the large-diamater cylinder structure system and it is suitable for symmetric or non-symmetric structures under the distributed or concentrated load. Numerical examples show that the proposed method and computer program BEFEM are quite efficient in the analysis of the large-diameter cylinder structure problems in ocean engineering.     

Simulating Groundwater-Streamflow Connections in the Upper Colorado River Basin

In mountain, snow driven catchments, snowmelt is supposed to be the primary contribution to river streamflows during spring. In these catchments the contribution of groundwater is not well documented because of the difficulty to monitor groundwater in such complex environment with deep aquifers. In this study we use an integrated hydrologic model to conduct numerical experiments that help quantify the effect of lateral groundwater flow on total annual and peak streamflow in predevelopment conditions. Our simulations focus on the Upper Colorado River Basin (UCRB; 2.8 × 10⁵ km²) a well-documented mountain catchment for which both streamflow and water table measurements are available for several important sub-basins. For the simulated water year, our results suggest an increase in peak flow of up to 57% when lateral groundwater flow processes are included—an unexpected result for flood conditions generally assumed independent of groundwater. Additionally, inclusion of lateral groundwater flow moderately improved the model match to observations. The correlation coefficient for mean annual flows improved from 0.84 for the no lateral groundwater flow simulation to 0.98 for the lateral groundwater flow one. Spatially we see more pronounced differences between lateral and no lateral groundwater flow cases in areas of the domain with steeper topography. We also found distinct differences in the magnitude and spatial distribution of streamflow changes with and without lateral groundwater flow between Upper Colorado River Sub-basins. A sensitivity test that scaled hydraulic conductivity over two orders of magnitude was conducted for the lateral groundwater flow simulations. These results show that the impact of lateral groundwater flow is as large or larger than an order of magnitude change in hydraulic conductivity. While our results focus on the UCRB, we feel that these simulations have relevance to other headwaters systems worldwide.     

High-resolution spectroscopy of Saturn at 3 microns: CH4, CH3D, C2H2, C2H6, PH3, clouds, and haze

We report observation and analysis of a high-resolution 2.87-3.54 μm spectrum of the southern temperate region of Saturn obtained with NIRSPEC at Keck II. The spectrum reveals absorption and emission lines of five molecular species as well as spectral features of haze particles. The ν₂+ν₃ band of CH₃D is detected in absorption between 2.87 and 2.92 μm; and we derived from it a mixing ratio approximately consistent with the Infrared Space Observatory result. The ν₃ band of C₂H₂ also is detected in absorption between 2.95 and 3.05 μm; analysis indicates a sudden drop in the C₂H₂ mixing ratio at 15 mbar (130 km above the 1 bar level), probably due to condensation in the low stratosphere. The presence of the ν₃+ν₉+ν₁₁ band of C₂H₆ near 3.07 μm, first reported by Bjoraker et al. [Bjoraker, G.L., Larson, H.P., Fink, U., 1981. Astrophys. J. 248, 856-862], is confirmed, and a C₂H₆ condensation altitude of 10 mbar (140 km) in the low stratosphere is determined. We assign weak emission lines within the 3.3 μm band of CH₄ to the ν₇ band of C₂H₆, and derive a mixing ratio of 9±4×¹⁰⁻⁶ for this species. Most of the C₂H₆ 3.3 μm line emission arises in the altitude range 460-620 km (at ∼μbar pressure levels), much higher than the 160-370 km range where the 12 μm thermal molecular line emission of this species arises. At 2.87-2.90 μm the major absorber is tropospheric PH₃. The cloud level determined here and at 3.22-3.54 is 390-460 mbar (∼30 km), somewhat higher than found by Kim and Geballe [Kim, S.J., Geballe, T.R., 2005. Icarus 179, 449-458] from analysis of a low resolution spectrum. A broad absorption feature at 2.96 μm, which might be due to NH₃ ice particles in saturnian clouds, is also present. The effect of a haze layer at about 125 km (∼12 mbar level) on the 3.20-3.54 μm spectrum, which was not apparent in the low resolution spectrum, is clearly evident in the high resolution data, and the spectral properties of the haze particles suggest that they are composed of hydrocarbons.     

Solar Wind Electron Parameters from Ulysses/URAP Quasi-Thermal Noise Measurements at Solar Maximum

We present the solar wind plasma parameters obtained from the Ulysses spacecraft during its second pole-to-pole fast latitude scan near the 2001 solar maximum. We study the solar wind properties from the electron density and core temperature measurements made by the radio receiver on Ulysses using the method of quasi-thermal noise spectroscopy. We analyze these parameters as functions of heliographic latitude and distance. We present their histograms normalized to 1 AU and find a bimodal distribution for the electron core temperature. The cooler population can be associated with the fast wind flow emanating from coronal holes present at various latitudes. We discuss a slight north/south asymmetry found for the electron density. Finally, we compare the present results to those obtained during the 1996 solar minimum and 1991 solar maximum.     

Retrieval and tentative indentification of the 3 μm spectral feature in Titan's haze

Recently, an unidentified 3.3-3.4 μm feature found in the solar occultation spectra of the atmosphere of Titan observed by Cassini/VIMS was tentatively attributed to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules, but without properly extracting the feature from adjacent influences of strong CH₄ and weak C₂H₆ absorptions (Bellucci et al., 2009). In this work, we retrieve the detailed spectral feature using a radiative transfer program including absorption and fluorescent emission of both molecules, as well as absorption and scattering by haze particles. The spectral features of the haze retrieved from the VIMS data at various altitudes are similar to each other, indicating relatively uniform spectral properties of the haze with altitude. However, slight deviations observed near 127 km and above 300 km suggest inhomogeneity at these altitudes. We find that the positions of the major spectral peaks occur at 3.33-3.37 μm, which are somewhat different from the typical 3.3 μm aromatic or 3.4 μm aliphatic C-H stretches usually seen in the spectra of dust particles of the interstellar medium and comets. The peaks, however, coincide with those of the solid state spectra of C₂H₆, CH₄, and CH₃CN; and a broad shoulder from 3.37 to 3.50 μm coincides with those of C₅H₁₂ and C₆H₁₂ as well as those of typical aliphatic C-H stretches. This result combined with high-altitude (∼1000 km) haze formation process recently reported by Waite et al. (2007) opens a new question on the chemical composition of the haze particles. We discuss the possibility that the 3 μm feature may be due to the solid state absorption bands of these molecules (or some other molecules) and we advocate additional laboratory measurements for the ices of hydrocarbon and nitrogen-bearing molecules present in Titan's atmosphere for the identification of this 3 μm feature.