Phase transitions in the system CaCO<Subscript>3</Subscript> at high P and T determined by in situ vibrational spectroscopy in diamond anvil cells and first-principles simulations

The stability of the high-pressure CaCO₃ calcite (cc)-related polymorphs was studied in experiments that were performed in conventional diamond anvil cells (DAC) at room temperature as a function of pressure up to 30 GPa as well as in internally heated diamond anvil cells (DAC-HT) at pressures and temperatures up to 20 GPa and 800 K. To probe structural changes, we used Raman and FTIR spectroscopy. For the latter, we applied conventional and synchrotron mid-infrared as well as synchrotron far-infrared radiation. Within the cc-III stability field (2.2–15 GPa at room temperature, e.g., Catalli and Williams in Phys Chem Miner 32(5–6):412–417, 2005), we observed in the Raman spectra consistently three different spectral patterns: Two patterns at pressures below and above 3.3 GPa were already described in Pippinger et al. (Phys Chem Miner 42(1):29–43, 2015) and assigned to the phase transition of cc-IIIb to cc-III at 3.3 GPa. In addition, we observed a clear change between 5 and 6 GPa that is independent of the starting material and the pressure path and time path of the experiments. This apparent change in the spectral pattern is only visible in the low-frequency range of the Raman spectra—not in the infrared spectra. Complementary electronic structure calculations confirm the existence of three distinct stability regions of cc-III-type phases at pressures up to about 15 GPa. By combining experimental and simulation data, we interpret the transition at 5–6 GPa as a re-appearance of the cc-IIIb phase. In all types of experiments, we confirmed the transition from cc-IIIb to cc-VI at about 15 GPa at room temperature. We found that temperature stabilizes cc-VI to lower pressure. The reaction cc-IIIb to cc-VI has a negative slope of ?7.0 × 10^?3 GPa K^?1. Finally, we discuss the possibility of the dense cc-VI phase being more stable than aragonite at certain pressure and temperature conditions relevant to the Earth’s mantle.     

Sediments and pollution in the Northern Adriatic Sea: a statistical analysis

Data concerning grain-size distribution, mineralogy, geochemistry, and chlorinated hydrocarbon concentrations, obtained from 246 surface sediment samples collected in the Northern Adriatic sea (Italian area), provide the basis for a multivariate statistical analysis which evaluates the influence of riverine inputs, the differences among various depositional environments and the presence of polluted zones.Cluster analysis applied to grain size has identified nine groups of lithotypes associated with the morphology and the hydrology of the basin.In the Gulf of Venice, principal component analysis on clay minerals and carbonates has permitted recognition of two main areas located north and south of the Brenta river. More subareas correspond to other lithological types.Principal component analysis of nine metal (Hg, Cd, Cu, Pb, Cr, Zn, Fe, Ni, and Co) concentrations reveals that the studied sea area is more complex from the geochemical point of view. Three geochemical zones related to riverine inputs, different lithotypes and specific forms of contamination are identified. High pollution of both halocarbons and heavy metals is associated with fine grain size.     

List of papers from other journals

List of papers from other journals     

Deformational features of the Ustica volcanic island in the Southern Tyrrhenian Sea (Italy)

Macro- and meso-structural analyses of the Ustica rock formations lead to an interpretation of most of the deformational features that define the structural framework of the island. A regime of sinistral transtension seems to be the best explanation for the most significant fault associations. This regime is consistent with the kinematic model for the Tyrrhenian back-arc-accretionary wedge system proposed by Doglioni (1991). A caldera collapse in the northern part of the island provides the major source of volcanotectonic deformation while cracks, open or filled by clastic and/or volcanic material, were formed by downslope block sliding mostly along the southern coastline. Joints in indurated surge deposits were generated by brittle deformations induced by gravity after deposition, rather than by tectonism.     

Ground‐based InSAR reveals conduit pressurization pulses at Stromboli volcano

At Stromboli volcano (Southern Italy), only few minor precursors (gas output) have been identified for ‘major’ Strombolian explosions. We use ground‐based interferometric synthetic aperture radar (GBInSAR) technology to monitor the displacement rate of the summit area of Stromboli. We analysed the 2009–2011 period. The analysis of the displacement rate has been performed by dividing the summit zone monitored by the GBInSAR into three regions, corresponding to the edge of the crater area (1 and 2), and to the slope of the NE crater (3). Pulses of rapid expansion of sector 3, of variable duration and amplitude, appear in coincidence with periods of intense activity that include lava flows and major explosions. We associate this expansion with the pressurization of the magma column that is recharged by deep‐derived gas, promoting the onset of ‘major explosion‐dominated’ activity.