The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.     

The objective determination of the instantaneous predominant frequency of seismic signals and inferences onQ of coda waves

A technique to detect spectrum variations versus time along seismic signals is applied to coda waves of local earthquakes (Friuli, Northern Italy). The technique consists of an autoregressive modeling and utilizes nonlinear spectral analysis where the spectrum of stochastic processes is estimated as the transfer function of the filter that whitens the process under analysis. This approach appears to be particularly well suited to those investigations where automatic measurements of the instantaneous frequency have to be carried out on digital data. The detection of variations of the instantaneous frequency along the coda allows computation of seismic-Q in the lithosphere and its frequency dependence: the result obtained is $$Q = 100f^{0.4} $$ which appears to be strongly consistent with that, based on the estimate of the coda amplitude decay in the band including the most significant frequencies of the signals under analysis.     

Atomic structures and energies of grain boundaries in Mg2SiO4 forsterite from atomistic modeling

Grain boundaries influence many physical and chemical properties of crystalline materials. Here, we perform molecular dynamics simulations to study the structure of a series of [100] symmetric tilt grain boundaries in Mg₂SiO₄ forsterite. The present results show that grain boundary energies depend significantly on misorientation angle. For small misorientation angles (up to 22°), grain boundary structures consist of an array of partial edge dislocations with Burgers vector $\frac{1}{2}[001]$ associated with stacking faults and their energies can be readily fit with a model which adds the Peach-Koehler equation to the Read-Shockley dislocation model for grain boundaries. The core radius of partial dislocations and the spacing between the partials derived from grain boundary energies show that the transition from low- to high-angle grain boundaries occurs for a misorientation angle between 22° and 32°. For high misorientation angles (32.1° and 60.8°), the cores of dislocations overlap and form repeated structural units. Finally, we use a low energy atomic configuration obtained by molecular dynamics for the misorientation of 12.18° as input to simulate a high-resolution transmission electron microscopy (HRTEM) image. The simulated image is in good agreement with an observed HRTEM image, which indicates the power of the present approach to predict realistic atomic structures of grain boundaries in complex silicates.     

A note on modeling double diffusive mixing in the global ocean

Though ubiquitous in the global oceans, double diffusive mixing has been largely ignored or poorly represented in the models of turbulent mixing in the ocean and in 3-D ocean models, until recently. Salt fingers occur in the interior of many marginal seas and ocean basins, the Tyrrhenian Sea and the subtropical Atlantic being two examples. Diffusive convection type of double diffusion occurs in the upper layers of many sub-polar seas and polar oceans due to cold melt water from sea ice. Consequently, it is important to be able to properly parameterize double diffusive mixing in basin scale and global ocean models, so that the water mass structure in the interior of the ocean can be properly simulated. This note describes a model for double diffusive mixing in the presence of background shear, based on Mellor–Yamada type second moment closure, more specifically Kantha, 2003, Kantha and Clayson, 2004 second moment closure models of resulting turbulence, following Canuto et al. (2008a) but employing a different strategy for modeling the pertinent terms in the second moment equations. The resulting model is suitable for inclusion in ocean general circulation models.     

The role of the land use, land use change and forestry sector in achieving Annex I reduction pledges

Annex I Parties may receive credits or debits from Land Use, Land Use Change and Forestry (LULUCF) activities, contributing to achieving individual emission reduction targets. In the Durban climate negotiations, Parties agreed new LULUCF accounting rules for the second commitment period of the Kyoto Protocol (CP2). By using these new rules, this paper presents key differences among Parties at the minimum (assuming no additional action) and potential (assuming additional actions) contribution of the forest-related LULUCF activities in achieving the pledges for 2020. Overall, the potential contribution of LULUCF is relatively modest (up to about 2 % of 1990 emissions) for the EU, the Annex I Parties likely joining the CP2, and for the Annex I Parties that joined the CP1 as a whole. However, for specific Parties, LULUCF can make a substantial contribution to achieving the pledges. For New Zealand, for instance, the potential contribution of future LULUCF credits may equal 33 % of its 1990 emission level. For Australia, the pledges are expressed relative to 2000 emission levels including LULUCF emissions. Given that LULUCF emissions have strongly declined between 1990 and 2000, and a further decline in foreseen by 2020 (based on Australia’s projections), the minimum contribution of LULUCF to meet the Australian pledges appears to be about 19 % and 7 % relative to its 1990 and 2000 emission level, respectively. A further 3 % potential contribution is estimated from additional actions.     

Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

Chemical and isotopic assessment of surface water–shallow groundwater interaction in the arid Grande river basin,North-Central Chile

ABSTRACT

This paper analyses the composition of surface water and shallow groundwater in the Grande River basin, North-Central Chile, using this information to characterize water interactions. Chemical and isotopic data for surface water and groundwater (7 and 6 sampling locations, respectively) were obtained from three sampling campaigns performed in March–April (autumn), August–September (late winter) and December (early summer) 2012. Precipitation samples were also collected. Data was processed using spatial distribution charts, Piper and Stiff diagrams, and multivariate analysis. In general, the results for each method converge on a high degree of connectivity between surface water and shallow groundwater in the study area. Furthermore, approximately a 10% of groundwater contribution to the surface flow discharge was estimated for a particular reach. This multi-method approach was useful for the characterization of surface water–groundwater interactions in the Grande River basin, and may become a suitable and replicable scheme for studies in arid and semi-arid basins facing similar water management challenges.

Editor D. Koutsoyiannis; Associate editor B. Dewals     

XMM–Newton observations of soft gamma-ray repeaters

All the confirmed Soft Gamma-ray Repeaters have been observed with the EPIC instrument on the XMM–Newton satellite. We review the results obtained in these observations, providing the most accurate spectra on the persistent X-ray emission in the 1–10 keV range for these objects, and discuss them in the context of the magnetar interpretation.      

Nature and Properties of sub-DLAs (absorbers with 1019 ≤ N(HI) ≤ 2 * 1020 cm-2)

Quasar absorbers provide an alternative approach to the study of galaxies. In particular, the detection of high-column density systems allow to measure the cosmological evolution of the neutral gas mass and metals in the Universe. At z <3.5, 90% of the HI mass is in damped Lyα systems (DLAs). But it has been suggested that atz > 3.5, 45% of the HI lies in systems below the traditional DLA definition (2 x 10²⁰ cm^-2), in ‘sub-DLAs’ with 10¹⁹ < N(HI) < 2 x 10²⁰ cm^-2. Here we present a sample of sub-DLAs issued from UVES archive quasar spectra. We have measured the sub-DLA number density redshift evolution and directly establish their column density distribution function. We have also undertaken a detailed metal abundance analysis of this class of absorbers to compare with the characteristics of the well studied DLAs. This revised version was published online in September 2006 with corrections to the Cover Date.     

Crystal-chemistry of clinopyroxenes from potassic and ultrapotassic rocks in central Italy: implications on their genesis

The clinopyroxenes mentioned have been investigated by single crystal X-ray diffraction combined with electron microprobe analysis. The aim of this study was to characterize the crystal-chemical variations of clinopyroxenes in order to delineate the intracrystalline constraints which are characteristic of specific magmatic environments. Clinopyroxenes (cpx) crystallized from peralkaline ultrapotassic melt with kamafugitic and lamproitic affinities are characterized by high Si contents, which are insensitive to variations in silica abundance and silica saturation of the melt. The high Si occupancy in clinopyroxenes from kamafugitic magma is coupled to large M1 (i.e. Mg and Fe²⁺) and M2 (high Ca occupancy) sites, whereas in clinopyroxenes from magmas with lamproitic affinity, high Si content is combined with large M1 but small M2 sites. Clinopyroxenes from Romantype alkaline potassic and ultrapostassic rocks are characterized by an expanded tetrahedron (high ^IVA1 content) and small M1 site which is combined with small M2 polyhedron in clinopyroxenes from the potassic rocks and large M2 site in those from the ultrapotassic rocks.