Element zoning trends in olivine phenocrysts from a supposed primary high-magnesian andesite: an electron- and ion-microprobe study

Electron and ion-probe microanalysis have been used to obtain zoning profiles for major and trace elements in olivine phenocrysts from a high-magnesian andesite from Shodo-Shima island, southwest Japan. This rock was previously thought to represent undifferentiated, primary magma. Some crystals have unzoned cores, while others show cores which are reversely zoned with respect to Mg/ (Mg+Fe), Ni, Mn and Cr. In addition, some Ni profiles show a normally zoned hump at the most central portions of the reversely zoned crystals. All crystals show normally zoned rims. The Li concentrations are constant throughout the cores of all crystals studied, but rise sharply, by a factor of up to at least six, in the rims. The Ca and Co concentrations are essentially constant throughout all the crystals. Mechanisms for producing the observed zoning profiles are discussed, and it is concluded that the reverse zoning was produced by the introduction of crystals into a less differentiated magma than that in which they grew. The reversely zoned crystals could therefore represent xenocrysts which were introduced into an undifferentiated magma, or phenocrysts introduced into a more primitive magma by a magma mixing process. The Ni profiles are used to estimate the residence time of these crystals in the more primitive magma. The following trace element partition co-efficients have been estimated for the olivine-groundmass system in this rock: D ^Ni=16; D ^Mn=1.1; D ^Co=4.2; D ^Ca =0.02; D ^Ti=0.005; D ^V=0.05; D ^Sc=0.2; D ^Na=0.0002. Studies of trace element zoning will become increasingly important as the new generation of trace element microprobes become available but a larger database of experimentally determined values for trace element partition coefficients and diffusion coefficients in crystals and magmas, and a better understanding of other disequilibrium processes are required to fully exploit the new data.     

Micromechanical approach to effective viscoelastic properties of micro‐fractured geomaterials

The aim of this paper is to formulate a micromechanics‐based approach to non‐aging viscoelastic behavior of materials with randomly distributed micro‐fractures. Unlike cracks, fractures are discontinuities that are able to transfer stresses and can therefore be regarded from a mechanical viewpoint as interfaces endowed with a specific behavior under normal and shear loading. Making use of the elastic‐viscoelastic correspondence principle together with a Mori‐Tanka homogenization scheme, the effective viscoelastic behavior is assessed from properties of the material constituents and damage parameters related to density and size of fractures. It is notably shown that the homogenized behavior thus formulated can be described in most cases by means of a generalized Maxwell rheological model. For practical implementation in structural analyses, an approximate model for the isotropic homogenized fractured medium is formulated within the class of Burger models. Although the approximation is basically developed for short‐term and long‐term behaviors, numerical applications indicate that the approximate Burger model accurately reproduce the homogenized viscoelastic behavior also in the transient conditions.     

The sedimentary rocks of macaronesia

In all the archipelagos forming Macaronesia, volcanis predominate, but pre-Quaternary sediments are also present, though playing a humble role.Calcareous deposits have by far the greatest significance throughout the known stratigraphic record. Tertiary occurrences tend to be thin, show more gentle dips, whereas the Mesozoics attain thicknesses of 400 m (certain), attitudes steeper, often vertical.To date, Mesozoics are recognized only in Maio (Cape Verde), are possible in S. Nicolau (Cape Verde) and Fuerteventura (Canary Islands). Whether strata as old as Jurassic is present in these three islands is a moot point. Ample arguments, pro and con, have been presented for Maio; there is meagre evidence in S. Nicolau; pure conjecture in Fuerteventura.Beginning with the Neogene, the stratigraphic record for Macaronesia is more substantial, the Vindobonian being present or then strongly suspected in all archipelagos.The sedimentary rocks in these islands have not aroused the same interests as the volcanics, and undeniably they are of far less importance as regards rock constitution. The status of investigations varies widely within the different islands, and as of the present, we must frankly recognize that our knowledge of the sedimentaries is only of reconnaissance standard.

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Zusammenfassung Auf allen Inselgruppen, die man als Makaronesen zusammenfaßt, überwiegen vulkanische Gesteine; prä-quartäre Sedimente gibt es — in geringem Umfang — ebenfalls.Kalkablagerungen haben, nach den bekannten stratigraphischen Zeugnissen zu urteilen, die größte Bedeutung. Tertiär ist in geringer Mächtigkeit und schwach geneigt vertreten, während das Mesozoikum bis zu 400 m nachgewiesene Mächtigkeit erreicht und verstellt, oft vertikal auftritt.Bisher ist Mesozoikum nur in Maio (Kapverden) bekannt, möglicherweise auch in S. Nicolau (Kapverden) und Fuerteventura (Kanarische Inseln). Ob Schichten jurassischen Alters und den drei Inseln vorkommen, ist umstritten. Argumente dafür und dagegen sind für Maio reichlich zusammengetragen worden; für S. Nicolau gibt es magere Hinweise, für Fuerteventura nur Vermutungen.Seit dem Neogen sind die stratigraphischen Zeugnisse auf den makaronesischen Inseln umfangreicher; so ist Vindobon auf allen Inselgruppen vorhanden oder sein Vorkommen mindestens sehr wahrscheinlich gemacht.Die sedimentären Gesteine haben auf den Inseln nicht das gleiche Interesse gefunden wie die vulkanischen, und sie sind auch ganz sicher von geringerer Bedeutung, soweit es sich um ihren Gesteinscharakter handelt. Der Forschungsstand ist innerhalb der Inseln sehr unterschiedlich, und wir müssen eingestehen, daß zur Zeit unser Wissen über die sedimentären Gesteine sieh noch im Anfangsstadium befindet.

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Résumé Le matériel volcanique domine dans les îles de l'archipel des Macaronesia. Les sédiments pré-quaternaires sont aussi présents, bien que jouant un rôle plus modeste.Les formations calcaires sont de loin les plus représentatives des dépôts reconnus de la colonne stratigraphique. Les dépôts cénozoiques sont généralement peu épais et présentent de faibles pendages, tandis que ceux du Mésozoique atteignent des épaisseurs de 400 m (démontrées), et des pendages importants, atteignant souvent la verticale.Jusqu'à présent, les dépôts mésozoiques ont été reconnus uniquement à Maio (Cap Vert), sont possibles à S. Nicolau (Cap Vert) et Fuerteventura (Iles des Canaries). La présence de Jurassique dans ces trois îles est encore un sujet de controverse. De nombreux arguments, positifs ou négatifs, ont été présentés concernant l'île de Maio; les arguments positifs sont légèrement dominants à S. Nicolau; le problème est à l'état de pure hypothèse à Fuerteventura.On peut faire débuter sans ambiguité la colonne stratigraphique des îles de l'archipel Macaronesia au Néogène, le Vindobonien étant présent ou fortement suspecté dans toutes les archipels.Les roches sédimentaires dans ces îles n'ont pas suscité le même intérêt que les roches volcaniques, et indéniablement leur importance est moindre. L'état d'avancement de ces travaux varie largement d'une île à l'autre, mais à l'heure actuelle, nous devons reconnaître qu'ils en sont seulement au stade de la reconnaissance.

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The measurements of the artificial atmospheric radioactivity

Summary There are some methods and types of instrument for measuring the specific artificial atmospheric radioactivity. In order to compare the simultaneous daily measurements, as made at different stations of a network, or to know the representativeness of a point measurement, it is necessary to consider the random and systematic errors, which are characteristic for the measuring method or the instrument. After having explained the meaning of these quantities, a method of calculation is developed, being illustrated by a numerical example. It is hoped that these considerations may be useful in analogous problems wherever and whenever one and the same quantity is measured with different methods or instruments.

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Zusammenfassung Es gibt verschiedene Methoden und Typen von Instrumenten zur Messung der spezifischen künstlichen atmosphärischen Radioaktivität. Um die gleichzeitigen täglichen Messungen verschiedener Stationen des Beobachtungsnetzes vergleichen zu können und ein Urteil über die Repräsentativität einer Punktmessung zu gewinnen, müssen die zufälligen und die systematischen Fehler der Meßmethode und des Meßinstrumentes berücksichtigt werden. Es wird eine Methode zur Berechnung dieser Fehler entwickelt und ein numerisches Beispiel wiedergegeben. Die Ergebnisse dieser Untersuchung sind auch bei anderen Problemen anwendbar, wo ein und dieselbe Größe auf Verschiedene Weise oder mit verschiedenen Instrumenten gemessen wird.

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Résumé On connaît quelques méthodes et types d'instrument à mesurer la valeur spécifique de la radioactivité artificielle dans l'air. Afin de comparer les mesures quotidiennes simultanées, faites aux diverses stations du réseau d'observation, ou pour d'étudier la représentativité, il faut considérer les erreurs aléatoires et systématiques qui sont caractéristiques pour la méthode ou pour l'instrument de mesure. On développe une méthode pour calculer ces erreurs; elle est illustrée par un exemple numérique. On a quelque espoir que les considérations présentées pourraient être utiles à des problèmes analogues partout et toujours si l'on mesure une même grandeur au moyen de méthodes différentes ou d'instruments différents.

     

Tuning a physically-based model of the air–sea gas transfer velocity

Air–sea gas transfer velocities are estimated for one year using a 1-D upper-ocean model (GOTM) and a modified version of the NOAA–COARE transfer velocity parameterization. Tuning parameters are evaluated with the aim of bringing the physically based NOAA–COARE parameterization in line with current estimates, based on simple wind-speed dependent models derived from bomb-radiocarbon inventories and deliberate tracer release experiments. We suggest that A = 1.3 and B = 1.0, for the sub-layer scaling parameter and the bubble mediated exchange, respectively, are consistent with the global average CO₂ transfer velocity k. Using these parameters and a simple 2nd order polynomial approximation, with respect to wind speed, we estimate a global annual average k for CO₂ of 16.4 ± 5.6 cm h^?1 when using global mean winds of 6.89 m s^?1 from the NCEP/NCAR Reanalysis 1 1954–2000. The tuned model can be used to predict the transfer velocity of any gas, with appropriate treatment of the dependence on molecular properties including the strong solubility dependence of bubble-mediated transfer. For example, an initial estimate of the global average transfer velocity of DMS (a relatively soluble gas) is only 11.9 cm h^?1 whilst for less soluble methane the estimate is 18.0 cm h^?1.     

Carbonate shedding and sedimentary cyclicities of a distally steepened carbonate ramp (Miocene, Great Bahama Bank)

Received: 10 May 1999 / Accepted: 16 October 1999     

The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.     

Assessment of predictions of the response of the Hualien containment model during forced vibration tests

Blind predictions for the response of the 1/4-scale reinforced concrete Hualien (Taiwan) containment model during forced vibration tests are compared with the observed data. The predictions obtained by the CLASSI approach reflect the experimental conditions prior to and after backfill of the soil surrounding the embedded foundation. The experimental data show a strong and unexpected coupling between the response in the NS and EW directions which is not present in the results for the axisymmetric theoretical models. Also, significant differences can be seen between the experimental responses in the two orthogonal horizontal directions which minimize cross-axis coupling. Although these differences are not accounted for in the theoretical models, the discrepancies between predictions and observations are within the uncertainty of the structural and geotechnical data. The obtained differences between predictions and observations give an excellent measure of the prediction error that can be expected in this type of analysis from uncertainty in the data. A detailed assessment of the initial structural and geotechnical data based on extensive comparisons with the results of previous identification studies is also presented. Finally, comparisons between the observed response and calculations based on revised models for the structure and the soil show that current methods of analysis can account accurately for the observed response.     

Using amphibole phenocrysts to track vapor transfer during magma crystallization and transport: An example from Mount St. Helens,Washington

In order to evaluate and further constrain models for volatile movement and vapor enrichment of magma stored at shallow levels, amphibole phenocrysts from 2004–2005 Mount St. Helens dacite were analyzed for major and selected trace elements (Li, Cu, Zn, Mn, and REE) and Li isotopes. Several recent studies have examined fluid-mobile trace element abundances in phencryst phases and melt inclusions as a means of tracking volatile movement within subvolcanic magmatic systems, and high Li contents in plagioclase phenocrysts from 1980 and 2004 Mount St. Helens dacites have been interpreted as evidence that shallow magma was fluxed by a Li-bearing vapor phase prior to eruption.     

Structural damage detection using the optimal weights of the approximating artificial neural networks

This work presents a novel neural network‐based approach to detect structural damage. The proposed approach comprises two steps. The first step, system identification, involves using neural system identification networks (NSINs) to identify the undamaged and damaged states of a structural system. The partial derivatives of the outputs with respect to the inputs of the NSIN, which identifies the system in a certain undamaged or damaged state, have a negligible variation with different system errors. This loosely defined unique property enables these partial derivatives to quantitatively indicate system damage from the model parameters. The second step, structural damage detection, involves using the neural damage detection network (NDDN) to detect the location and extent of the structural damage. The input to the NDDN is taken as the aforementioned partial derivatives of NSIN, and the output of the NDDN identifies the damage level for each member in the structure. Moreover, SDOF and MDOF examples are presented to demonstrate the feasibility of using the proposed method for damage detection of linear structures. Copyright © 2001 John Wiley & Sons, Ltd.