Refining the ice flow chronology and subglacial dynamics across the migrating Labrador Divide of the Laurentide Ice Sheet with age constraints on deglaciation

The Laurentide Ice Sheet was characterized by a dynamic polythermal base. However, important data and knowledge gaps have led to contrasting reconstructions in areas such as the Labrador Ice Divide. In this study, detailed fieldwork was conducted at the southeastern edge of a major landform boundary to resolve the relative ice flow chronology and constrain the evolution of the subglacial dynamics, including the migration and collapse of the Labrador Ice Divide. Surficial mapping and analysis of 94 outcrop‐scale ice flow indicators were used to develop a relative ice flow chronology. ¹⁰Be exposure ages were used with optical ages to confine the timing of deglaciation within the study area. Four phases of ice flow were identified. Flow 1 was a northeasterly ice flow preserved under non‐erosive subglacial conditions associated with the development of an ice divide. Flow 2 was a northwest ice flow, which we correlate to the Ungava Bay Ice Stream and led to a westward migration of the ice divide, preserving Flow 2 features and resulting in Flow 3's eastward‐trending indicators. Flow 4 is limited to sparse fine striations within and around the regional uplands. The new optical ages and ¹⁰Be exposure ages add to the regional geochronology dataset, which further constrains the timing of ice margin retreat in the area to around 8.0 ka. Copyright © 2019 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd.     

Observing changes in groundwater resource using hydro-chemical and isotopic parameters: a case study from Bist Doab,Punjab

The continuous and large-scale abstraction of groundwater has created a groundwater depletion problem in several parts of the Punjab state including Bist Doab, the interfluve region of Beas and Satluj rivers. In the present study, a few important parameters, viz. water level, stable isotope, EC, temperature, groundwater age, that can be used to fingerprint the over-exploitation of groundwater have been examined. It has been observed that with the increase in over-exploitation, the yield of shallow aquifer is progressively getting reduced and as a result forcing the farmers to sink their wells to deeper depths. With abstraction of deeper aquifer, the storage of old groundwater at the deeper aquifer is declining and getting replaced by induced accelerated inflow of young water from the recharge zone and the overlying shallow aquifer. The signatures of the modern water have been observed in the data analyzed for isotopic, hydro-chemical facies, electrical conductivity and temperature of water from deeper aquifer. The study has identified the usefulness of these parameters for identifying groundwater over-exploitation in the region. Depleting water resource may stagnate the economic progress of the region. The paper provides suitable water resource management strategies to be adopted to improve the sustainability of water resources and economic growth in the region.     

Rivers turned to rock: Late Quaternary alluvial induration influencing the behaviour and morphology of an anabranching river in the Australian monsoon tropics

Late Quaternary alluvial induration has greatly influenced contemporary channel morphology on the anabranching Gilbert River in the monsoon tropics of the Gulf of Carpentaria. The Gilbert, one of a number of rivers in this region, has contributed to an extensive system of coalescing low-gradient and partly indurated riverine plains. Extensive channel sands were deposited by enhanced flow conditions during marine oxygen isotope (OI) Stage 5. Subsequent flow declined, probably associated with increased aridity, however, enhanced runoff recurred again in OI Stages 4–3 (65–50 ka). Aridity then capped these plains with 4–7 m of mud. A widespread network of sandy distributary channels was incised into this muddy surface from sometime after the Last Glacial Maximum (LGM) to the mid Holocene during a fluvial episode more active than the present but less so than those of OI Stages 5 and 3. This network is still partly active but with channel avulsion and abandonment now occurring largely proximal to the main Gilbert flow path.A tropical climate and reactive catchment lithology have enhanced chemical weathering and lithification of alluvium along the river resulting in the formation of small rapids, waterfalls and inset gorges, features characteristic more of bedrock than alluvial systems. Thermoluminescence (TL) and comparative optically stimulated luminescence (OSL) ages of the sediments are presented along with U/Th ages of pedogenic calcrete and Fe/Mn oxyhydroxide/ oxide accumulations. They show that calcrete precipitated during the Late Quaternary at times similar to those that favoured ferricrete formation, possibly because of an alternating wet–dry climate. Intense chemical alteration of the alluvium leading to induration appears to have prevailed for much of the Late Quaternary but, probably due to exceptional dryness, not during the LGM. The result has been restricted channel migration and a reduced capacity for the channel to adjust and accommodate sudden changes in bedload. Consequent avulsions have caused local stream powers to increase by an order of magnitude, inducing knickpoint erosion, local incision and the sudden influx of additional bedload that has triggered further avulsions. The Gilbert River, while less energetic than its Pleistocene ancestors, is clearly an avulsive system, and emphasizes the importance in some tropical rivers of alluvial induration for reinforcing the banks, generating nickpoints, reworking sediment and thereby developing and maintaining an indurated and anabranching river style.     

Four-dimensional data assimilation method based on SVD: Theoretical aspect

Summary A new method of four-dimensional data assimilation based on Singular Value Decomposition (SVD) is proposed. In it, a set of atmospheric states is obtained by integrating a numerical weather prediction model and simulated observations are taken and calculated from the model variables. Then the SVD technique is used to create the base vectors from this coupled data set. Finally, the analysis is obtained by projecting actual observation data into a space spanned by the base vectors. Using this approach, the four-dimensional data assimilation becomes a simple linear inverse problem the linearization of the nonlinear forward model is avoided, and the developments of the adjoint and background error covariance matrix are no longer needed. Since the SVD technique is used here, the method is simply called 4DSVD.     

Evaluation of the first GOCE static gravity field models using terrestrial gravity,vertical deflections and EGM2008 quasigeoid heights

Recently, four global geopotential models (GGMs) were computed and released based on the first 2 months of data collected by the Gravity field and steady-state Ocean Circulation Explorer (GOCE) dedicated satellite gravity field mission. Given that GOCE is a technologically complex mission and different processing strategies were applied to real space-collected GOCE data for the first time, evaluation of the new models is an important aspect. As a first assessment strategy, we use terrestrial gravity data over Switzerland and Australia and astrogeodetic vertical deflections over Europe and Australia as ground-truth data sets for GOCE model evaluation. We apply a spectral enhancement method (SEM) to the truncated GOCE GGMs to make their spectral content more comparable with the terrestrial data. The SEM utilises the high-degree bands of EGM2008 and residual terrain model data as a data source to widely bridge the spectral gap between the satellite and terrestrial data. Analysis of root mean square (RMS) errors is carried out as a function of (i) the GOCE GGM expansion degree and (ii) the four different GOCE GGMs. The RMS curves are also compared against those from EGM2008 and GRACE-based GGMs. As a second assessment strategy, we compare global grids of GOCE GGM and EGM2008 quasigeoid heights. In connection with EGM2008 error estimates, this allows location of regions where GOCE is likely to deliver improved knowledge on the Earth’s gravity field. Our ground truth data sets, together with the EGM2008 quasigeoid comparisons, signal clear improvements in the spectral band ~160–165 to ~180–185 in terms of spherical harmonic degrees for the GOCE-based GGMs, fairly independently of the individual GOCE model used. The results from both assessments together provide strong evidence that the first 2 months of GOCE observations improve the knowledge of the Earth’s static gravity field at spatial scales between ~125 and ~110 km, particularly over parts of Asia, Africa, South America and Antarctica, in comparison with the pre-GOCE-era.     

An overview of socio-economic and ecological perspectives of Fiji's inshore reef fisheries

This paper reviews the socio-economic and ecological context of Fijian reef fisheries. This review is deemed necessary because improved understanding of the state and trends of Fiji's coral reef fisheries on a national level is required for designing an effective management plan for Fiji's inshore reef fisheries. The most important point that emerges from our review is that despite numerous studies of Fiji's reef fisheries, the current status of reef-associated fisheries at the national level is still uncertain due, mainly, to the lack of dependable data on the subsistence fisheries. This in turn leads to uncertainty about how the continuation of fishing, in particular, fishing focused on target species for the coral reef resources trade, will affect fishing communities and the ecosystem.     

ANABRANCHING RIVERS: THEIR CAUSE,CHARACTER AND CLASSIFICATION

Anabranching rivers consist of multiple channels separated by vegetated semi-permanent alluvial islands excised from existing floodplain or formed by within-channel or deltaic accretion. These rivers occupy a wide range of environments from low to high energy, however, their existence has never been adequately explained. They occur concurrently with other types of channel pattern, although specific requirements include a flood-dominated flow regime and banks that are resistant to erosion, with some systems characterized by mechanisms to block or constrict channels, thereby triggering avulsion. The fundamental advantage of an anabranching river is that, by constructing a semi-permanent system of multiple channels, it can concentrate stream flow and maximize bed-sediment transport (work per unit area of the bed) under conditions where there is little or no opportunity to increase gradient. On the basis of stream energy, sediment size and morphological characteristics, six types of anabranching river are recognized; types 1–3 are lower energy and types 4–6 are higher energy systems. Type 1 are cohesive sediment rivers (commonly termed anastomosing) with low w/d ratio channels that exhibit little or no lateral migration. They are divisible into three subtypes based on vegetative and sedimentary environment. Type 2 are sand-dominated, island-forming rivers, and type 3 are mixed-load laterally active meandering rivers. Type 4 are sand-dominated, ridge-forming rivers characterized by long, parallel, channel-dividing ridges. Type 5 are gravel-dominated, laterally active systems that interface between meandering and braiding in mountainous regions. Type 6 are gravel-dominated, stable systems that occur as non-migrating channels in small, relatively steep basins. Anabranching rivers represent a relatively uncommon but widespread and distinctive group that, because of particular sedimentary, energy-gradient and other hydraulic conditions, operate most effectively as a system of multiple channels separated by vegetated floodplain islands or alluvial ridges.     

Derivation of density and temperature from the Cassini–Huygens CAPS electron spectrometer

In this paper we present two methods to derive electron fluid parameters from the CAPS–ELS spectrometer on board the Cassini spacecraft currently in orbit around Saturn. In the first part of the paper we give a basic overview of the instrument and describe the challenges inherent in the derivation of density and temperature values using these techniques. We then describe a method to calculate electron moments by integrating the particle distribution function. We also describe a second technique in which we fit the electron energy spectrum with a Gaussian curve and use the peak energy of this curve to derive density and temperature values. We then compare the two methods with particular emphasis on their application to Cassini SOI observations in the saturnian environment and point out the limitations of the two techniques. We will show that results from the two very different methods are in agreement when the physical properties of the environment and of the observed electron populations have been inferred from inspection of the raw data. Finally we will suggest future developments that will remove these limitations.     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

BUILDING A COLONIAL RESOURCE MONOPOLY: THE EXPANSION OF SULPHUR MINING IN NEW SPAIN, 1600–1820*

The discovery, extraction, and monopolistic control of key natural resources was a priority of New Spain's colonial administration. Managing the region's abundant resources, however, often proved difficult for the Spanish Crown. Human and environmental challenges impeded protoindustrial growth and development, and monopolistic control of resources often met resistance. In this article I examine these processes in the context of New Spain's little‐known monopoly on sulphur—a yellow, powdery mineral the Crown jealously guarded as its own. Sulphur was critical for gunpowder and explosives production, yet the Crown often failed to produce enough of it to meet the growing demand by its military and the silver blast‐mining industry. Colonial documents reveal administrators’ attempts to improve sulphur production through reform measures, which included advising sulphur miners on how to discover sulphur deposits and, eventually, how to develop their mines. Efforts to improve sulphur production were moderately successful, although the process was messy and inefficient.