Role of γ-ray spectrometry in detecting potassic alteration associated with Um Ba’anib granitic gneiss and metasediments, G. Meatiq area, Central Eastern Desert, Egypt

The radiometric responses of the Gebel (G., which means mountain in Arabic) Meatiq area display the overall high radiation of the high grade metamorphic Um Ba’anib granite gneiss, metasediments, as well as Arieki adamellite rocks. Whereas, the low grade metamorphic ophiolitic nappes country reveal the lowest radiometric response. The eU, eTh, and K contents tend to increase with the youthfulness of the plutons with a maximum amounts in the more alkali varieties, e.g., Arieki adamellite (580 Ma), then the high grade metamorphic rocks of the younger Meatiqian orogeny (626?±?2 Ma). Also, these rocks reveal that the major radiometric anomaly with exposure rates ≈139 nGy/h, more than double of the global terrestrial values. While, the low grade metamorphic ophiolitic rocks reveal the lowest average exposure rates ≈46.8 nGy/h. The areas of high gamma ray values of F-parameter of Efimov (K × U/Th), ternary composite map, K map, K/eTh, and K/eU ratios maps are related to K enrichment conditions during formation (diagenesis) or deformation of the high grade metamorphic rocks and the Arieki adamellite intrusion. From the geochemical point of view, these areas are associated with rocks that are characterized by high-K calc-alkaline, calc-alkaline affinity, and enriched in REE.     

Physically based maximum precipitation estimation under future climate change conditions

Estimation of the extreme precipitation over a target watershed under a changing climate would be necessary to design safe large hydraulic structures. For this purpose, the maximum precipitation (MP) estimation approach was applied to the American River Watershed (ARW) in Northern California under several future climate conditions over 90 water years (2010–2099). These future climate conditions were obtained using 13 future climate projections from two general circulation models (ECHAM5 and CCSM3) based on four future climate scenarios (Special Report on Emissions Scenarios: A1B, A1FI, A2, and B1). A total of 1,170 future projected severe storm events (90 years × 13 projections) were selected with respect to the 72‐hr basin‐average precipitation over the ARW. The 72‐hr basin‐average precipitation for each of the selected severe storm events was maximized over the ARW by horizontally shifting the atmospheric boundary conditions of a regional atmospheric model in order to optimize the path of the storm system that corresponded to the particular event. After maximization, the MP estimates, which are the largest precipitation depths among the maximized results, were obtained as 836.7 mm for the early half‐century period (2010–2054) and 1,056.5 mm for the late half‐century period (2055–2099).     

Free and steady state vibration of non-linear structures using a finite element–non-linear eigenvalue technique

The problem of free vibration of non-linear structures is considered initially. It is shown that this problem can be represented as a non-linear eigenvalue problem. Variational principles for non-linear eigenvalue problems are defined. These variational principles are implemented with finite element models to define numerical approximations for the free vibration problem. The solution of these approximate equations provides a set of non-linear modal vectors and natural frequencies which vary with the amplitude of the solution. The non-linear eigenvalue parameters can be used in modal expansion approximations for the non-linear transient or steady state response of structural systems. To demonstrate the proposed techniques the free vibration and steady state vibration characteristics of a geometrically non-linear circular plate are determined.     

Evaluating the performance of a deterministic daily rainfall–runoff model in a low-flow context

The characterization of a stream's low-flow regime is required for ecological purposes, water quality studies and various other water projects. If observed stream flow records are insufficient, low-flow characteristics may need to be estimated from simulated daily stream flow time-series. The model employed should conceptualize low-flow generation mechanisms and surface–subsurface interactions adequately. The ability of the model to simulate low-flow regimes may be assessed by means of various low-flow analysis techniques. This paper illustrates the approach using the example of the physically based, semi-distributed VTI daily rainfall–runoff model. The model has been applied to five perennial headwater catchments in South Africa, which are located in different parts of the country, represent different physiographical environments and are characterized by different baseflow responses. The model simulations are evaluated in terms of both conventional goodness-of-fit criteria and several low-flow measures such as recession characteristics, baseflow volumes, flow duration curves and continuous low-flow events below specified threshold discharges. For all the catchments considered the model has been found to perform successfully in terms of conventional fit statistics and flow duration curves. However, its ability to reproduce recession characteristics and continuous low-flow spells appears to be less satisfactory. This suggests that daily model simulations should be evaluated by low-flow criteria, which are frequently ignored in water resource assessment practices. © 1998 John Wiley & Sons, Ltd.     

Nitrogen Mass Fraction and Stable Isotope Ratios for Fourteen Geological Reference Materials: Evaluating the Applicability of Elemental Analyser Versus Sealed Tube Combustion Methods

Thirteen commercially available silicate reference materials (RM) and one in‐house reference material, eleven of which have no previously published values, were analysed for nitrogen mass fraction and isotopic ratios with an Elemental Analyser (EA), and a Sealed Tube Combustion line, coupled to a continuous flow isotope ratio mass spectrometer (IRMS). These materials ranged from < 10 μg g^?1 to 1% m/m nitrogen mass fractions and δ¹⁵N of ?0.5 to +19.8‰. Existing nitrogen RM BHVO‐2, MS#5 and SGR‐1b were used to assess the accuracy of the data from the sealed tube combustion line, which was found to be in good agreement with existing published values. In contrast, the EA‐IRMS failed to fully liberate nitrogen from all silicate rocks and minerals (achieving a mean of 44 ± 10% nitrogen yield) resulting in kinetic fractionation of isotope values by ?1.4‰ on average. Therefore, sealed tube combustion is better suited for analyses of silicate‐bound nitrogen. The EA worked reliably for organic samples, but care should be taken when using the EA for silicate nitrogen research. Moving forward, it is recommended that BHVO‐2, Biotite‐Fe, FK‐N and UB‐N be used as quality control materials as they appear to be most reproducible in terms of nitrogen mass fraction (relative error < 10%, 1s), and isotopic composition (< 0.6‰, 1s).     

Tidal and annual variability of the population structure of Eurytemora affinis in the middle part of the Seine Estuary during 2005

Annual variability in abundance and population structure of the copepod Eurytemora affinis was studied in the maximum turbidity zone of the Seine Estuary in 2005. An Eulerian sampling strategy was applied monthly from March to July and from September to December. Chlorophyll a and suspended particulate matter (SPM) concentration, copepod abundance and stage distribution, and phytoplankton abundance were measured in sub-surface and near-bottom water during the ebb phase. Total E. affinis abundance was at a maximum in March and April (>200 × 10³ ind. m⁻³), and decreased from May to September (<25 × 10³ ind. m⁻³). This decrease corresponds to annual increases in temperature, salinity, chlorophyll a concentration and phytoplankton abundance, which was dominated by large diatoms, and decreases in SPM and river discharge. The phenology observed in 2005 was almost two months earlier compared to previous studies in the 1990s, when E. affinis reached maximum abundance in May and June. The low proportion of nauplii (<50%) in the population and high abundance of ovigerous females suggests that low recruitment is probably related to anomalously low temperatures in late winter (<5 °C). Whatever the horizontal position of the population in the estuary, adult and late copepodid stages are distributed in higher salinity than naupliar stages. Overall E. affinis population abundance was driven by parameters that characterize water masses at the tidal scale and by river discharge and chlorophyll a at the annual scale. By integrating the tidal effect, the high-frequency sampling protocol used appears to be optimal for investigating annual variability of planktonic communities in megatidal estuaries.     

Groundwater quality in parts of Central Ganga Basin, India

 This paper deals with the drinking water quality of the Ganga-Kali sub-basin which occupies 1300 km² over parts of Aligarh and Etah districts. Water samples were collected from shallow and deep aquifers and were analyzed for major ions and trace elements. The analytical data were interpreted according to published guidelines. Chemical analysis shows that the groundwater in the basin is alkali bicarbonate type. Trace element studies of water from the shallow aquifer show that the concentration of toxic metals Fe, Mn, Cd, Pb, and Cr⁺⁶ are above permissible limits which may present a health hazard. The water from the deep aquifer is comparatively free from contamination. The aquifers are subject to contamination due to sewage effluents and excessive use of fertilizers and pesticides in agriculture. Received: 7 December 1998 · Accepted: 2 March 1999     

Prediction of geometrical properties of perfect breaking waves on composite breakwaters

Breaking wave loads on coastal structures depend primarily on the type of wave breaking at the instant of impact. When a wave breaks on a vertical wall with an almost vertical front face called the “perfect breaking”, the greatest impact forces are produced. The correct prediction of impact forces from perfect breaking of waves on seawalls and breakwaters is closely dependent on the accurate determination of their configurations at breaking. The present study is concerned with the determination of the geometrical properties of perfect breaking waves on composite-type breakwaters by employing artificial neural networks. Using a set of laboratory data, the breaker crest height, h_b, breaker height, H_b, and water depth in front of the wall, d_w, from perfect breaking of waves on composite breakwaters are predicted using the artificial neural network technique and the results are compared with those obtained from linear and multi-linear regression models. The comparisons of the predicted results from the present models with measured data show that the h_b, H_b and d_w values, which represent the geometry of waves breaking directly on composite breakwaters, can be predicted more accurately by artificial neural networks compared to linear and multi-linear regressions.     

New exact cosmologies on the brane

We develop a method for constructing exact cosmological solutions in brane world cosmology. New classes of cosmological solutions on Randall–Sandrum brane are obtained. The superpotential and Hubble parameter are represented in quadratures. These solutions have inflationary phases under general assumptions and also describe an exit from the inflationary phase without a fine tuning of the parameters. Another class solutions can describe the current phase of accelerated expansion with or without possible exit from it.     

Evaluation of hydrocarbon pollution in marine sediments of Sfax coastal areas from the Gabes Gulf of Tunisia,Mediterranean Sea

The Tunisian environmental legislation that follows the EC Directives requires monitoring of persistent, toxic and bio-accumulated substances commonly considered as hazardous substances. In order to comply with this requirement, samples of sea water, sediment and biota from the urbanized and industrialized coast line of Sfax city are investigated. This study presents the results of petroleum hydrocarbon content, distribution and probable origin (anthropogenic and/or biogenic) in 16 intertidal sediments of Sfax coastal area. Alkane distribution indices and hydrocarbon distribution patterns are used to identify natural and anthropogenic input. Non-aromatic hydrocarbons present a high concentration with a range varying from 180 to 1,400 μg/g of dry sediment. The total concentrations of polycyclic aromatic hydrocarbons (PAHs) varied from 0.41 to 5.6 μg/g dry weight. These concentrations are comparable to other marine areas that receive important inputs. n-Alkanes with carbon number ranging from 15 to 35 are identified to be derived from both biogenic and anthropogenic sources in varying proportions. Pristane/phytane ratio shows values lower than 1.4 suggesting the presence of petroleum contamination. This is confirmed by the presence of a large group of unresolved complex mixture and the identification of hopanes with predominant C29 and C30 compounds and steranes with predominance of C27 over C28 and C29 compounds. Ratios of selected PAH concentrations indicate petrogenic and pyrolytic origin of hydrocarbons. Anthropogenic hydrocarbon inputs were more apparent at sites associated with industrial discharges, shipping activities and sewage outfalls.