Study of the seawater transparency field in the Crimea-Caucasus shelf area

This paper discussesin situ observational data on the directed light attenuation index in the near-surface layer, collected in September 1987. The absolute light attenuation index has been evaluated for a near-shore strip of water 10–15 miles in width. When multidisciplinary research is conducted in the open sea, this part of the sea surface remains unstudied, as the observational grid for it is made larger than the spatial-temporal parameters of the biophysical processes producing optical inhomogeneities.Translated by Vladimir A. Puchkin.     

A revised chronology for the adoption of agriculture in the Southern Levant and the role of Lateglacial climatic change

This paper re-examines the chronology and environmental context for the transition to agriculture in the Southern Levant, seen as the likely starting point for the adoption of agriculture in Europe and the Near East. The role in this process of abrupt late Quaternary climate change has been discussed widely, but limitations on the archaeological and palaeoenvironmental chronologies have led to varying interpretations. Here we attempt to clarify the situation by first testing the available radiocarbon database for the archaeological transitions from the Natufian through to the PPNA. We apply internationally accepted radiocarbon quality assurance procedures and find that a significant number of the published dates fall bellow acceptable standards. The cleaning process significantly clarifies and constrains the reported time ranges for the Natufian, Late Natufian and PPNA. We then apply the new IntCal09 calibration curve and Bayesian calibration methods, using the archaeological phasing to constrain the data and calculate the most likely timing of the transitions between each phase. We then compare the onset and duration of archaeological phases to data representing the key Northern Hemisphere climatic transitions, using the new GICC05 Greenland Ice core timescale and the timing of transitions between wet and dry phases in the southern Levant from published high precision isotopic analyses of Speleothem data. The results of this exercise present the currently best available chronology for these events and suggest that during the second part of the Lateglacial interstadial, drying of the southern Levant may have triggered the transition to the Late Natufian, when hunter-gatherer communities resorted to a more mobile lifestyle. The Late Natufian culture appears to have disappeared from the southern Levant during the Younger Dryas, as drying intensified. There is then a gap in well dated evidence for human occupation until a reappearance of humans at the onset of the Pre-Pottery Neolithic A (PPNA) period at the beginning of the Holocene. Thus the onset of the Holocene can be hypothesised to be the driver behind the onset of the Neolithic in this region.     

RAGLAND,AN LL3.4 CHONDRITE FIND FROM NEW MEXICO

The Ragland, New Mexico chondrite was found in 1978, and consists of a single stone of 12.16 kg that broke into three pieces. The stone is moderately weathered and has a pronounced chondritic texture. Bulk composition favors an LL classification, and modal analysis and oxygen isotopic composition are consistent with this. The thermoluminescence sensitivity of 0.056 ± 0.020 normalized to Dhajala, compositional variability of olivine (mean Fa 18.3, σ = 10.1) and low-Ca pyroxene (mean Fs 14.6, σ = 6.7), and Ca concentrations in olivine indicate metamorphic subtype 3.4 ± 0.1. The isotopically heavy oxygen composition, which is characteristic of subtypes 3.0–3.1, may be a primary characteristic and not a result of weathering. Low concentrations of radiogenic ⁴⁰Ar and planetary ³⁶Ar suggest noble gas loss.     

Combustion as the cause of comet P/Halley's activity

The totality of the results obtained in the VEGA, GIOTTO and SUISEI projects does not lend itself to interpretation within the old sublimation models of comet activity considering solar radiation as the sole source of energy. Among them are the systematic excess of the velocity and temperature of the gas escaping from the nucleus over the theoretical values, the outflow being concentrated in several ( ~ 12–15) narrow ( ~ 300 m in size at the nucleus) hypersonic jets carrying very large amounts of remarkably fine CHON dust and located along continuous lines on the nuclear surface, intense release from the nucleus or very close to it (2 × 10³km) of CO (Q _Co/Q _{H2 O} = 0.05–0.2) with a smaller amount of CO₂ (Q _{CO 2}/ Q _{H2 O} 0.015), large near-nucleus abundances of C, C⁺ (Q _C/Q _CO 0.29), etc.The new observations, together with some earlier data still poorly understood (e.g. the appearance in the coma of large amounts of C₃) can be accounted for by assuming the cometary ices to contain, apart from hydrocarbons, nitrogen-containing compounds, etc. also of free oxygen ( ~ 15 wt.%). Under these conditions, burning should occur in the products of sublimation under deficiency of oxidizer accompanied by the production of soot, smoke, etc. The burning should propagate under the surface crust and localize primarily at a few sites.The presence of oxygen in cometary ices follows from a new eruption theory assuming the minor bodies of the Solar System to have formed in explosions of the massive ice envelopes saturated by electrolysis products on distant moonlike bodies of the type of Ganymede and Callisto.     

Oxidation of pyrite during extraction of carbonate associated sulfate

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.     

The gawler ranges,South Australia: an unusual volcanic massif

The volcanic residuals of the Gawler Ranges together form an extensive massif that in its gross morphology differs markedly from most exposures of silicic volcanic rocks. The upland developed in two stages, the first involving differential fracture‐controlled subsurface weathering, the second the stripping of the regolith. As a result, an irregular weathering front was exposed, with domical projections prominent. These bornhardts are etch forms, and they are of considerable antiquity.

The differential weathering of the rock mass reflects the exploitation of various fracture systems by shallow groundwaters. Orthogonal fracture systems at various scales, sheet fractures and columnar joints control the morphology of the bornhardts in gross and in detail.

The exploitation of the structural base, which was established in the Middle Protero‐zoic, probably took place throughout the Late Proterozoic and the Palaeozoic, though only minor remnants of the Proterozoic land surface remain. The major landscape features developed during the Mesozoic. The weathering which initiated the bornhardts occurred in the Jurassic or earlier Mesozoic, and the landforms were exposed in Late Cretaceous to Early Tertiary times.

Though structural forms dominate the present landscape, some major and some minor landforms are best explained in terms of climatic changes of the later Cainozoic. The palaeodrainage system, established under humid conditions by the Early Tertiary, was alluviated during the Cainozoic arid phases, and salinas were formed. The sand dunes of the region also reflect this aridity.