Comparison of classification and clustering methods in spatial rainfall pattern recognition at Northern Iran

Pattern recognition is the science of data structure and its classification. There are many classification and clustering methods prevalent in pattern recognition area. In this research, rainfall data in a region in Northern Iran are classified with natural breaks classification method and with a revised fuzzy c-means (FCM) algorithm as a clustering approach. To compare these two methods, the results of the FCM method are hardened. Comparison proved overall coincidence of natural breaks classification and FCM clustering methods. The differences arise from nature of these two methods. In the FCM, the boundaries between adjacent clusters are not sharp while they are abrupt in natural breaks method. The sensitivity of both methods with respect to rain gauge density was also analyzed. For each rain gauge density, percentage of boundary region and hardening error are at a minimum in the first cluster while the second cluster has the maximum error. Moreover, the number of clusters was sensitive to the number of stations. Since the optimum number of classes is not apparent in the classification methods and the boundary between adjacent classes is abrupt, use of clustering methods such as the FCM method, overcome such deficiencies. The methods were also applied for mapping an aridity index in the study region where the results revealed good coincidence between the FCM clustering and natural breaks classification methods.     

Chemical stabilization of sabkha soils at high moisture contents

Vast expanses of arid, saline soils that occur along the Arabian Gulf seaboard and elsewhere possess a very low density and strength that necessitate improvement before any actual construction takesplace. For large-scale constructions, several field improvement techniques have recently been implemented with various degrees of success. In surficial, small-scale applications, chemical stabilization provides a potential technique to improve the inferior properties of these soils, known locally as sabkha. A literature search indicates that chemical stabilization of soils usingasphalt, lime and cement is usually conducted at lower moisture contents than the optimum. Such moisture contents are also much lower than the natural moisture content of sabkha, and if applied to sabkha in the field, this wouldrequire lowering the moisture content before any stabilization commenced; whichwould be neither feasible nor economical.

In this investigation, an eastern Saudi sabkha soil was chemically stabilized at its natural moisture level, which varies from 16% to 22%. In addition to the characterization of the soil and standard compaction tests, cement and lime sabkha mixtures were prepared at five additions and cured for up to 90 days in plastic wrap. Results indicate that cement-stabilized sabkha gained high strength with time and proved to have a potential use in construction.     

Green and Eco‐Friendly Removal of Mycotoxins with Organo‐Bentonites; Isothermal,Kinetic, and Thermodynamic Studies

In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g^?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g^?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g^?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination.     

Magnetic Resonance Imaging of Nonaqueous Phase Liquid Distribution in Unconsolidated Soils Using Discriminatory Freezing

Organic contaminants present as nonaqueous phase liquids (NAPLs) in the subsurface often pose a long-term risk to human health and the environment. Investigating the distribution of NAPLs in porous media remains a major challenge in risk assessment and management of contaminated sites. Conventional soil coring and monitoring wells have been widely used over past decades as the primary means of subsurface investigation to determine NAPL extent. Known limitations of conventional approaches have led us to explore an alternative or a complementary technique to provide high-quality information of NAPL source zone architecture. This work advances an imaging tool for a variety of organic NAPL contaminants in unconsolidated soils through magnetic resonance imaging (MRI) of frozen cores. Using trichloroethylene (TCE) and o-xylene as model species, we illustrate that discriminatory freezing of water, while keeping the NAPL in a liquid state, enables high-resolution qualitative delineation of NAPL distribution within porous media. This novel approach may help improve site conceptual models and consequentially lead to highly tailored, more efficient remedial measures.     

The plurality effect of topographical irregularities on site seismic response

Topography can have significant effects on seismic ground response during an earthquake because topographic irregularities cause considerable differences between the seismic waves emitted by the source and the waves reaching the ground surface. When a seismic motion happens in a topographically irregular area, seismic waves are trapped and reflected between the topographic features. Therefore, the interaction between topographies can amplify seismic ground response. In order to reveal how interaction between topographies influences seismic response, several numerical finite element studies have been performed by using the ABAQUS program. The results show that topographic features a greater distance between the seismic source and the site would cause greater seismic motion amplification and is perceptible for the hills far away from the source and the ridges. Also, site acceleration response is impacted by surrounding topography further than site velocity and displacement response.     

Evaluation of sediment contamination in the Red Sea coastal area combining multiple pollution indices and multivariate statistical techniques

In the recent years,the Red Sea coast of Yemen has been severely affected by intensive anthropogenic activities.The current study constitutes a thorough inquiry to evaluate the extent of heavy metals pollution in Yemen's Red Sea coast sediment and identifies the possible sources of pollution.The concentrations of five metals(copper(Cu),zinc(Zn),cadmium(Cd),lead(Pb),and nickel(Ni))collected from nine sites along the Red Sea coast of Yemen were assessed using an atomic absorption spectrophotometer(ASS).Sediment quality indices,such as the sediment quality guidelines(SQGs),potential ecological risk(RI),contamination factor(CF),pollution load index(PLI),geoaccumulation index(Igeo),and modified degree of contamination(mCd)were computed.In addition,multivariate statistical techniques(principal component analysis(PCA),hierarchical cluster analysis,and Pearson's correlation analysis)were applied to identify the potential sources of metals.The mean concentrations of Cu,Zn,Cd,Pb,and Ni were 51.3,61.9,4.02,9.9,and 33.4 mg/kg dry wt,respectively.The spatial distribution revealed that the metals concentrations were high at the middle zone and low southward of Hodeida city.According to the SQGs,the adverse biological effects of metals were occasionally associated with Cu and Cd,frequently associated with Ni,and not expected to occur with Zn and Pb.The RI indicated that the sediment of the studied sites pose low(RI<50)to considerable(100≤RI<200)ecological risk.The mean effect range-median quotient(M-ERM-Q)indicated that the combination of the studied metals had the toxicity probability of 21%at all studied sites.Igeo and CF indicated that the metals concentrations were in the descending order of:Zn>Ni>Pb>Cd>Cu,whereas the PLI and mCd indicated that Ras Isa(Site 5)and Urj village(Site 6)were the most polluted sites.PCA,cluster analysis,and correlation analysis found that Cd,Pb,and Ni mostly originated from anthropogenic sources while Cu and Zn were mainly derived from natural sources.Thus,it is evident that the intensive anthropogenic activities had negative influence on metals accumulation in the sediment of the Red Sea coast of Yemen leading to detrimental effects to the whole ecosystem.These comprehensive findings provide valuable information and data for future monitoring studies regarding heavy metals pollution and sediment quality at the Red Sea coast of Yemen.     

Timing of Late Neoproterozoic glaciation on Baltica constrained by detrital zircon geochronology in the Hedmark Group, south-east Norway

The Moelv Tillite is the Late Neoproterozoic Varanger glacial deposit recorded in the Hedmark Group, SE Norway. Paired U–Pb and Lu–Hf data collected on detrital zircons in the Rendalen Formation underlying the Moelv Tillite have identified an uncommon 677 ± 15 to 620 ± 14 Ma population, that constrain the deposition of the Moelv Tillite to be younger than 620 ± 14 Ma. The youngest detrital zircons may be derived from granite magmatism related to the 616 ± 3 Ma Egersund dolerite magmatism, situated in the western part of the Sveconorwegian orogen. The Moelv Tillite, which is not overlain by a cap carbonate, possibly correlates with the c. 580 Ma Squantum-Gaskiers glacial deposits of Avalonia. Available palaeomagnetic data for the Late Neoproterozoic suggest that Baltica was located at intermediate to high latitude between 620 and 555 Ma.     

Solving land-use suitability analysis and planning problem by a hybrid meta-heuristic algorithm

The aim of Land-use Suitability Analysis and Planning Problem (LSAPP) is to identify the most suitable parcels of land for future land-uses considering several conflicting criteria. LSAPP can be modeled using a variant of a well-known combinatorial optimization problem called Quadratic Assignment Problem (QAP). In this paper, a multi-objective mathematical model is developed for LSAPP based on QAP modeling. The large-size instances of the proposed multi-objective mathematical model are difficult to solve in a reasonable CPU time using exact algorithms. So, an efficient three-phase hybrid solution procedure is proposed. In the first phase, the compensatory objectives are integrated using Analytic Hierarchy Process (AHP) and Decision-Making Trial and Evaluation Laboratory. Then, based on the aforementioned suitability objective function and other spatial objectives and constraints, a multi-objective LSAPP is constructed. Finally, a hybrid multiple objective meta-heuristic algorithm is proposed to solve the LSAPP. The core of the proposed algorithm is based on Scatter Search while Tabu Search and Variable Neighborhood Search are also utilized. The proposed algorithm is equipped with the concepts of Pareto optimality and Veto Threshold, which improve its efficacy. The proposed algorithm is applied on a real LSAPP case study, in ‘Persian Gulf Knowledge Village’, wherein its performance is compared with a well-known evolutionary computation algorithm called Vector Evaluated Genetic Algorithm (VEGA) using comprehensive statistical analysis. A survey on time complexity of the proposed algorithm is also accomplished. The results show that MOSVNS is significantly superior to VEGA both in single and in multi-objective modes. Furthermore, analysis of time complexity of the proposed algorithm shows that it is of polynomial time and can be applied to significantly larger problems with multiple compensatory and non-compensatory objectives.     

Optical and physical characterization of ��Iraqi freedom�� dust storm, a case study

Kuwait was exposed to a severe dust storm on 19 March 2003, the eve of operation ??Iraqi Freedom??. Three days of dust events (19, 26, 27 March) were analyzed for their aerosol optical and physical properties using ground-based and satellite-retrieved measurements. Ground-based measurements of aerosol optical depth (or thickness; AOD or AOT) at 675?nm, ?? ₆₅₇, ?ngstrom coefficient ?? _936/657, particulate matter of diameter 10???m or less, PM₁₀ (??g/m³), and meteorological parameters were analyzed for March 2003. AOT exceeded 3 for the 3?days of interest and PM₁₀ concentrations reached as high value as 2,457???g/m³ on 19 March dust storm day. Retrieved aerosol characteristics from space using Moderate Resolution Imaging Spectrometer (MODIS) on board Terra and Aqua satellite were examined against ground-based measurements. A strong correlation was found between ground-based measurements of ?? ₆₇₅ and the Terra-MODIS retrieved AOD₅₅₀. The synoptic of the dust storm were analyzed and source regions were identified using back trajectory analysis and Total Ozone Mapping Spectrometer Aerosol Index.