Modelling the vulnerability of groundwater to contamination in an unconfined alluvial aquifer in Pakistan

The area of Thal Doab is located in the Indus Basin and is underlain by a thick alluvial aquifer called the Thal Doab aquifer (TDA). The TDA is undergone intense hydrological stress owing to rapid population growth and excessive groundwater use for livestock and irrigated agricultural land uses. The potential impact of these land uses on groundwater quality was assessed using a DRASTIC model in a Geographic Information System environment. Seven DRASTIC thematic maps were developed at fixed scale and then combined into a groundwater vulnerability map. The resultant vulnerability index values were grouped into four zones as low, moderate, high and very high. The study has established that 76% of the land area that is underlain by the TDA has a high to very high vulnerability to groundwater contamination mainly because of a thin soil profile, a shallow water table and the presence of soils and sediments with high hydraulic conductivity values. In addition, only 2 and 22% of the total area lie in low and moderate vulnerability zones, respectively. The outcomes of this study can be used to improve the sustainability of the groundwater resource through proper land-use management.     

Greenhouse Gas Emissions from Agro-Ecosystems and Their Contribution to Environmental Change in the Indus Basin of Pakistan

There is growing concern that increasing concentrations of greenhouse gases in the atmosphere have been responsible for global warming through their effect on radiation balance and temperature. The magnitude of emissions and the relative importance of different sources vary widely, regionally and locally. The Indus Basin of Pakistan is the food basket of the country and agricultural activities are vulnerable to the effects of global warming due to accelerated emissions of GHGs. Many developments have taken place in the agricultural sector of Pakistan in recent decades in the background of the changing role of the government and the encouragement of the private sector for investment in new ventures. These interventions have considerable GHG emission potential. Unfortunately, no published information is currently available on GHG concentrations in the Indus Basin to assess their magnitude and emission trends. The present study is an attempt to estimate GHG （CO2, CH4 and N2O） emissions arising from different agro-ecosystems of Indus Basin. The GHGs were estimated mostly using the IPCC Guidelines and data from the published literature. The results showed that CH4 emissions were the highest （4.126 Tg yr^-1） followed by N20 （0.265 Tg yr^-1） and CO2 （52.6 Tg yr^-1）. The sources of CH4 are enteric fermentation, rice cultivation and cultivation of other crops. N2O is formed by microbial denitrification of NO3 produced from applied fertilizer-N on cropped soils or by mineralization of native organic matter on fallow soils. CO2 is formed by the burning of plant residue and by soil respiration due to the decomposition of soil organic matter.     

Building a semantic based public transportation geoportal compliant with the INSPIRE transport network data theme

Interoperability is becoming essential for the today’s geographic information systems. Geographic information is usually available as datasets stored in databases and accessible via GIS. However, these information sources are increasingly heterogeneous and show differences in data formats, database schema and object concepts. To satisfy the increased demand for the use and sharing of geographic data in common applications, considering the heterogeneity and the methods to support interoperability are required by the GIS community. The implementation of Spatial Data Infrastructure (SDI) such as the European INSPIRE (Infrastructure for Spatial Information in the European Community) enables accessibility and the sharing of geographic data and interoperability among the systems. In addition to this, traditional GIS systems perform spatial queries using a keyword-based method. However, this approach remains incapable of fully expressing the users' needs due to a lack of geographic concepts (semantics) in the dataset. Different terms may refer to similar concepts, while the same terms may refer to different concepts. This causes semantic heterogeneity in the dataset. In this context, the most promising approach is the implementation of geospatial semantics by means of ontology in the geospatial dataset to overcome this kind of ambiguity. The aim of this research is to investigate the implementation of INSPIRE as a SDI standard and the use of Semantic Technology to empower the traditional GIS approach. In this regard, a public transportation geoportal has been developed for the experimental investigation which uses a revised sample transportation data complaint with the INSPIRE Transport Network Data Theme and a developed Transportation Ontology Domain, including concepts, relationships and individuals to provide a semantic spatial search.     

Effect of Pozzolanic Reactivity on Compressibility Characteristics of Stabilised Low Lime Fly Ashes

This paper presents the effects of addition of lime and lime along with gypsum on the compressibility behavior of two class F fly ashes. Since the fly ashes develop strength and exhibit lower compression, consolidation testing with conventional duration of load increment may not be appropriate. Hence, an attempt has been made to assess the minimum duration of load increment necessary to study the compressibility characteristics of such materials. Thus compressibility behavior of fly ashes with additives has been studied using conventional consolidation test with different durations of load increments varying from 30 min to 48 h. The results obtained indicated that 30 min of duration of load increment can be used to assess the compressibility behavior of such materials. The effect of lime which reduces the compression is seen to be maximum from the results obtained with the duration of load increment of 30 min but gradually reduces with higher durations of load increment. It has also been observed that the rate of decrease in the compressibility is maximum up to 2.5% lime and gradual thereafter. The compressibility of lime treated fly ashes further reduces when gypsum is incorporated, the optimum gypsum percentage being 2.5. This reduction in the compressibility of fly ashes enhanced by incorporating lime and gypsum makes them versatile in the construction of embankments and for structural fills, particularly reducing the time required in between laying of each lift.     

Host rock characteristics and source of chromium and beryllium for emerald mineralization in the ophiolitic rocks of the Indus Suture Zone in Swat,NW Pakistan

Bodies of magnesite-rich rocks (magnesite ± talc ± quartz ± dolomite), locally containing emerald deposits, occur within the Swat Valley. These rocks, part of the Indus suture mélange group, are distributed mostly along contacts of serpentinized ultramafic rocks with carbonate ± graphite-bearing metasedimentary rocks. Their field association, petrographic details, mineralogical composition and geochemical characteristics show that they likely formed due to carbonate alteration of previously serpentinized ultramafic rocks by CO₂-bearing fluids released as a result of metamorphism of spatially associated, originally sedimentary rocks of the Indo-Pakistan plate.Locally, late-stage hydrothermal activity affected these highly fissile magnesite-rich rocks to produce veins and stockworks of quartz as well as emerald, Cr-rich tourmaline and Cr, Ni-rich muscovite. Detailed petrographic and mineral chemical investigations suggest that all three Cr-bearing silicates are genetically related and their Cr, as well as Ni and Mg found in Cr-rich muscovite and Cr-rich tourmaline, was derived from the original ultramafic protoliths.Detailed geochemical comparison reveals that relative to non-mineralized sections, magnesite-rich rocks in mineralized zones show significant enrichment in B and Be as well as As, Pb, Zr, Rb, Ba, W, Sn, Sr and Y. Boron and Be enrichment in these rocks appears to be structurally controlled. More extreme B and Be enrichment is evident in small granitic dikes cutting granite gneisses and in Miocene leucogranitic stocks at Malakand 45 km southwest. These geochemical features argue strongly for a leucogranite-associated source for Be-transporting fluids to the emerald's host rocks.     

Geochemical and mineralogical characteristics of recent clastic sediments from lower Godavari river: Implications of source rock weathering

The major, trace and rare earth elements geochemistry and clay mineral compositions in the river bed sediments from lower reaches of Godavari river suggest that they are derived from weathering of felsic rocks. Trace and rare earth elemental compositions indicate evidence of sedimentary sorting during transportation and deposition. Lower concentrations of transition elements, such as V, Ni and Cr imply enrichment of felsic minerals in these bed sediments. The REE pattern in lower Godavari sediments is influenced by the degree of source rock weathering. The light rare earth elements (LREE) content are indicating greater fractionation compared to the heavy rare earth elements (HREE). A striking relationship is observed between TiO₂ and gZREE content suggesting a strong control by LREE-enriched titaniferous minerals on REE chemistry. Shale-normalized REE pattern demonstrate a positive Eu anomaly, suggesting weathering of feldspar and their secondary products, which are enriched in Eu. Chondrite-normalised REE pattern is characteristic of felsic volcanic, granites and gnessic source rocks. Trace elemental compositions in sediments located near urban areas suggest influence of anthropogenic activity. Chemical Index of Alteration (CIA) is high (avg. 65.76), suggesting a moderate chemical weathering environment. X-ray diffraction analysis of clay fraction shows predominance of clay minerals that are formed because of the chemical weathering of felsic rocks.