Boron isotopic composition of fumarolic condensates from some volcanoes in Japanese island arcs

Boron samples from 40 fumarolic condensates from volcanoes in the Ryukyu arc (Satsuma Iwo-jima and Shiratori Iwo-yama) and the North-east Japan arc (Usu-shinzan, Showa-shinzan, Esan and Issaikyo-yama) all have ${}^{11}\text{B}{}^{10}\text{B}$ ratios close to 4.07. Higher values, from 4.09 to 4.13, were only observed in condensates from volcanoes in the southernmost end of the North-east Japan arc (Nasu-dake), the northern part of the Izu-Bonin arc (Hakone), and the North Mariana arc (Ogasawara Iwo-jima). These higher values suggest geological interaction of the magmas with sea-water enriched in ¹¹B.     

Paleomagnetic evidence for clockwise rotation of the northern arm of Sulawesi,Indonesia

Paleomagnetic results from the northern arm of Sulawesi show that the arm has been subjected to a clockwise rotation of more than 90° and that its rotational motion began no later than the middle Miocene. The mean direction showing a normal polarity at the Eocene to the early Miocene isD = 98.0° andI = 6.9°. A declination value ofD = 50.1° obtained from Miocene rocks indicates a transition stage of the rotational motion. The datum from Plio-Pleistocene volcanics isD = ?4.6° andI = ?9.3°. This suggests that the rotational motion terminated before the initiation of volcanic activity during the Plio-Pleistocene.     

Upper limit of heaving pressure derived by pore-water pressure measurements of partially frozen soil

Experiments were conducted to estimate heaving pressures of saturated soil partially frozen in a closed system. Temperatures at both ends of a specimen were kept constant, i.e., positive at the top and negative at the bottom. When the overburden pressure P was maintained at a constant value, the pore-water pressure P_w, which showed a certain value before freezing, decreased gradually as freezing progressed, finally attaining a specific value, whereafter the specimen ceased taking water into it. The pressure difference between P and P_w, at this stage was defined as the upper limit of heaving pressure σ_u, which evidently depended on the temperature θ_c of the cooling end, in accordance with the relation: σ_u = −11.4 θ_c (kg/cm²)

It corresponds to the modified Clausius-Clapeyron's formula, which gives the freezingpoint depression of an ice—water system, where the pressure acting on the ice differs from that on the water. This is the same as the value obtained by Radd and Oertle (1973). It is considered, however, that, when θ_c lowers, the value of θ_u reaches finally a constant value smaller than the one obtained by the above equation. Denoted by σ_{u max}, it was defined as a maximum heaving pressure. The value of σ_{u max} depended on soil type.     

Hydrogen isotopic fractionation factor between brucite and water in the temperature range from 100° to 510° C

The hydrogen isotopic fractionation factor between brucite and water has been determined in the temperature range of 100°–510° C. Brucite is always depleted in deuterium relative to the coexisting water, and the degree of depletion becomes larger with decreasing temperature. The fractionation factor changes smoothly in the temperature range of 144°–510° C and its temperature dependence was obtained by the method of least square fit in the following form: 10³In=8.72×10⁶ T ^–2–3.86×10⁴ T ^–1+14.5However, a marked decrease of about 5 was observed at 100°–144° C. The D/H fractionation factor for the brucite-water system is not similar to that for serpentine-water system presented by Sakai and Tsutsumi (1978), though all the hydroxyl ions coordinate to magnesium ion in both minerals. This discrepancy cannot be attributed to hydrogen bonding but to distortion of Mg-octahedron of serpentine, in which the Mg-OH bonding length is shorter than the sum of ionic radius of Mg²⁺ and O^2– and there is no distortion in brucite. It is indicated that aside from hydrogen bonding, the structure effect also controls the D/H fractionation between hydrous mineral and water.     

Seismic Wavefields in the Deep Seafloor Area from a Submarine Landslide Source

We use the finite difference method to simulate seismic wavefields at broadband land and seafloor stations for a given terrestrial landslide source, where the seafloor stations are located at water depths of 1,900–4,300 m. Our simulation results for the landslide source explain observations well at the seafloor stations for a frequency range of 0.05–0.1 Hz. Assuming the epicenter to be located in the vicinity of a large submarine slump, we also model wavefields at the stations for a submarine landslide source. We detect propagation of the Airy phase with an apparent velocity of 0.7 km/s in association with the seawater layer and an accretionary prism for the vertical component of waveforms at the seafloor stations. This later phase is not detected when the structural model does not consider seawater. For the model incorporating the seawater, the amplitude of the vertical component at seafloor stations can be up to four times that for the model that excludes seawater; we attribute this to the effects of the seawater layer on the wavefields. We also find that the amplification of the waveform depends not only on the presence of the seawater layer but also on the thickness of the accretionary prism, indicating low amplitudes at the land stations and at seafloor stations located near the trough but high amplitudes at other stations, particularly those located above the thick prism off the trough. Ignoring these characteristic structures in the oceanic area and simply calculating the wavefields using the same structural model used for land areas would result in erroneous estimates of the size of the submarine landslide and the mechanisms underlying its generation. Our results highlight the importance of adopting a structural model that incorporates the 3D accretionary prism and seawater layer into the simulation in order to precisely evaluate seismic wavefields in seafloor areas.     

Water transportation from the subducting slab into the mantle transition zone

Using a recently developed petrogenetic grid for MORB + H₂O, we propose a new model for the transportation of water from the subducting slab into the mantle transition zone. Depending on the geothermal gradient, two contrasting water-transportation mechanisms operate at depth in a subduction zone. If the geothermal gradient is low, lawsonite carries H₂O into mantle depths of 300 km; with further subduction down to the mantle transition depth (approximately 400 km) lawsonite is no longer stable and thereafter H₂O is once migrated upward to the mantle wedge then again carried down to the transition zone due to the induced convection. At this depth, hydrous β-phase olivine is stable and plays a role as a huge water reservoir. In contrast, if the geothermal gradient is high, the subducted slab may melt at 700–900 °C at depths shallower than 80 km to form felsic melt, into which water is dissolved. In this case, H₂O cannot be transported into the mantle below 80 km. Between these two end-member mechanisms, two intermediate types are present. In the high-pressure intermediate type, the hydrous phase A plays an important role to carry water into the mantle transition zone. Water liberated by the lawsonite-consuming continuous reaction moves upward to form hydrous phase A in the hanging wall, which transports water into deeper mantle. This is due to a unique character of the reaction, because Phase A can become stable through the hydration reaction of olivine. In the case of low-pressure intermediate type, the presence of a dry mantle wedge below 100 km acts as a barrier to prevent H₂O from entering into deeper mantle.