ASSESSMENT OF 17β-ESTRADIOL IN AQUATIC ENVIRONMENTS AROUND KLANG VALLEY, MALAYSIA

This study was conducted to assess the existing concentration of 17β-estradiol(E2)in the surface water samples collected from rivers and lakes around Klang Valley,Malaysia.E2,which is a natural feminizing chemical produced in female organisms,regularly used to compare with other environmental estrogens because they behave similarly and react effectively as a hormone at a very low concentration.It was found that the average concentration of E2 in the aquatic environment of Klang Valley was(14.08 ±3.67)pg/mL,which was 14 times higher than those in the Japanese aquatic environment in this study.The river system had the average concentration of(20.02±5.26)pg/mL while the lake had an average concentration of(5.91±3.39)pg/mL.The E2 concentration was presumed high if the sources occurred nearby the area.Current levels of E2 in the aquatic environment may possess threats to existing aquatic organisms.Since high level of E2 has been discovered in the aquatic environment around Klang Valley,further studies and monitoring of E2 and other EDCs concentrations are needed to determine their levels in Malaysian aquatic environment and help to control these chemicals pollution in the aquatic environment.     

Modelling the effects of climatic and hydrological regime changes on the sediment dynamics of the Fraser River Basin,British Columbia,Canada

Future sediment dynamics may be affected by changing climates or hydrological regimes because of the close link between hydrology and sediment erosion, deposition, and transport. Previously, investigations of these potential changes have been constrained by a combination of limited observational data, hydrological drivers, and appropriate mechanistic models. Additionally, there is often ambiguity regarding how to disentangle the impacts of climate and hydrology from direct human factors such as reservoirs and land‐use change, which often exert more control over sediment dynamics. In this study, we utilize a recently developed, large‐scale, distributed, mechanistic sediment transport model to project future sediment erosion, deposition, and transportation within the Fraser River Basin in British Columbia, Canada—a basin with historical water flux and sediment load observations and limited anthropogenic influences upstream of its delta. The sediment model is driven by synthetic land‐surface hydrology derived from Scenarios A1B, A2, and B1 of the Special Report on Emissions Scenarios, which were provided by the Pacific Climate Impacts Consortium. Resulting simulations of water flux and sediment load from 1965 to 1994 are first validated against observational data then compared with future projections. Future projections show an overall increase in annual hillslope erosion and in‐channel transportation, a shift towards earlier spring peak erosion and transportation, and longer persistence of the sediment signal through the year. These shifts in timing and annual yield may have deleterious effects on spawning sockeye salmon and are insufficient to counteract future coastal retreat caused by sea‐level rise.     

Superconducting gravimeter observations without a tilt compensation system

This paper examines the possibility of using superconducting gravimeter (SG) observations without a tilt compensation system. SG data obtained at Syowa Station, Antarctica, were recorded without tilt compensation from April 5, 2001 to January 4, 2002, however, tilt signals were registered during this time period. A tilt correction was applied to gravity data from August 2, 2001 to January 4, 2002. After the tilt correction, errors of tidal parameters were dramatically reduced and tidal parameters themselves almost coincide with those from the same length of tilt-controlled gravity data recorded in 2000, when tilt compensation system was used. The noise level of the thermal leveler in the seismic band was also investigated. Averaged power spectra of gravity from 15 quiet days each in 2000 and 2001 recorded with and without the tilt compensation system, respectively, were compared. ‘Quiet’ in this case, means very low earthquake activity and calm wind conditions. No significant difference in the seismic band, except at the frequency of 2 mHz, was noticed. The difference at 2 mHz occurred because of room temperature variations caused by the water cooler, which cools down a compressor by automatically switching on and off.     

Tidal triggering of earthquakes in the subducting Philippine Sea plate beneath the locked zone of the plate interface in the Tokai region, Japan

We found a characteristic space–time pattern of the tidal triggering effect on earthquake occurrence in the subducting Philippine Sea plate beneath the locked zone of the plate interface in the Tokai region, central Japan, where a large interplate earthquake may be impending. We measured the correlation between the Earth tide and earthquake occurrence using microearthquakes that took place in the Philippine Sea plate for about two decades. For each event, we assigned the tidal phase angle at the origin time by theoretically calculating the tidal shear stress on the fault plane. Based on the distribution of the tidal phase angles, we statistically tested whether they concentrate near some particular angle or not by using Schuster's test. In this test, the result is evaluated by p-value, which represents the significance level to reject the null hypothesis that earthquakes occur randomly irrespective of the tidal phase angle. As a result of analysis, no correlation was found for the data set including all the earthquakes. However, we found a systematic pattern in the temporal variation of the tidal effect; the p-value significantly decreased preceding the occurrence of M ≥ 4.5 earthquakes, and it recovered a high level afterwards. We note that those M ≥ 4.5 earthquakes were considerably larger than the normal background seismicity in the study area. The frequency distribution of tidal phase angles in the pre-event period exhibited a peak at the phase angle where the tidal shear stress is at its maximum to accelerate the fault slip. This indicates that the observed small p-value is a physical consequence of the tidal effect. We also found a distinctive feature in the spatial distribution of p-values. The small p-values appeared just beneath the strongly coupled portion of the plate interface, as inferred from the seismicity rate change in the past few years.     

Evolution of the Komiji Syncline in the North Fossa Magna, central Japan: Paleomagnetic and K–Ar age insights

Abstract We carried out paleomagnetic measurements and K–Ar dating on Neogene andesitic lavas and sills of the Shigarami Formation in North Fossa Magna, central Japan. The Shigarami Formation is distributed in the axial part of the Komiji Syncline in the folding zone of the southwestern North Fossa Magna. Results of the present study indicate that the Komiji Syncline was formed shortly after 4.42 ± 0.12 Ma during the Pliocene. The sedimentary rocks of the Shigarami Formation consist of shallow marine and fluvial deposits. Intrusions of andesitic sills are found in the shallow marine deposits and two andesitic lava flows are present in the fluvial deposits. Oriented samples were taken from the sills at four sites and from the lavas at three sites. The samples produced stable remanent magnetization through stepwise alternating field and thermal demagnetizations. Results of a positive fold test indicate that the stable remanent magnetizations concentrate around a mean reversed polarity of declination = 169.0°, inclination = ?58.5° and 95% confidence limit = 9.0° after corrections have been made according to the direction of the bedding of the sedimentary rocks. Four fresh samples were selected for K–Ar dating from the samples used for paleomagnetic measurements. The groundmass of three samples taken from the sills yield ages of 4.42 ± 0.12, 4.49 ± 0.22 and 4.69 ± 0.13 Ma, whereas the one taken from the lower lava has an age of 5.91 ± 0.26 Ma. We believe that the Komiji Syncline was formed after the emplacement of lavas and sills in the area, because the descending Miocene strata were folded concordantly with the Shigarami Formation. The Pliocene and Pleistocene strata rest unconformably on the folded strata. The deformation might have progressed during the Pliocene, then slowed down in the Early Pleistocene. Our results suggest that the northwestward motion of the Philippine Sea Plate and the collision of the Tanzawa Block affected not only the South Fossa Magna, but also the North Fossa Magna.     

Skewed Water Temperature Occurrence Frequency in the Sea off Sanriku, Japan, and Intrusion of the Pure Kuroshio Water

Temperature and salinity data obtained by the Iwate Fisheries Technology Center were analyzed for the period 1971–1995. It was found that occurrence frequency distributions of temperature and salinity are very skewed at depths deeper than 200 m and that temperature sometimes exceeds m + 5σ (m: mean and σ: standard deviation. If such abnormally high temperatures are real the 3σ criterion cannot be adopted. Oceanic conditions were surveyed in 1972 and 1979, when temperatures exceeding m + 5σ were observed. It was found that the abnormally high temperature (and high salinity) water was the pure Kuroshio Water introduced into the region due to some special conditions such as abnormal approach of large warm-core ring to the Sanriku Coast or abnormal northward extension of the Kuroshio along the coast. These events are very rare, occurring only twice in the 25-year period analyzed, but the abnormally high temperature observed is real. This revised version was published online in July 2006 with corrections to the Cover Date.     

3‐D elemental and isotopic composition of presolar silicon carbides

Abstract— Thirteen presolar silicon carbide grains—three of supernova (SN) origin and ten of asymptotic giant branch (AGB) star origin—were examined with time‐of‐flight‐secondary ion mass spectrometry (TOF‐SIMS). The grains had been extracted from two different meteorites—Murchison and Tieschitz—using different acid residue methods. At high lateral resolution of ～300 nm, isotopic and elemental heterogeneities within the micrometer‐sized grains were detected. The trace elemental abundances, when displayed in two‐element correlation plots, of Li, Mg, K, and Ca show a clear distinction between the two different meteoritic sources. The different concentrations might be attributed to differences of the host meteorites and/or of extraction methods whereas the stellar source seems to be less decisive. In one SN grain with ²⁶Mg‐enrichment from extinct ²⁶Al, the acid treatment, as part of the grain separation procedure, affected the Mg/Al ratio in the outer rim and therefore the inferred initial ²⁶Al/²⁷Al ratio. A second SN grain exhibits a lateral heterogeneity in ²⁶Al/²⁷Al, which either is due to residual Al‐rich contamination on the grain surface or to the condensation chemistry in the SN ejecta.     

NanoSIMS isotopic analysis of small presolar grains: Search for Si3N4 grains from AGB stars and Al and Ti isotopic compositions of rare presolar SiC grains

We report isotopic ratio measurements of small SiC and Si₃N₄ grains, with special emphasis on presolar SiC grains of type Z, and new nucleosynthesis models for ²⁶Al/²⁷Al and the Ti isotopic ratios in asymptotic giant branch (AGB) stars. With the NanoSIMS we analyzed 310 SiC grains from Murchison (carbonaceous CM2 chondrite) separate KJB (diameters 0.25-0.45 μm) and 153 SiC grains from KJG (diameters 1.8-3.7 μm), 154 SiC and 23 Si₃N₄ grains from Indarch (enstatite EH4 chondrite) separate IH6 (diameters 0.25-0.65 μm) for their C and N isotopic compositions, 549 SiC and 142 Si₃N₄ grains from IH6 for their C and Si isotopic compositions, 13 SiC grains from Murchison and 66 from Indarch for their Al-Mg compositions, and eight SiC grains from Murchison and 10 from Indarch for their Ti isotopic compositions. One of the original objectives of this effort was to compare isotopic analyses with the NanoSIMS with analyses previously obtained with the Cameca IMS 3f ion microprobe. Many of the Si₃N₄ grains from Indarch have isotopic anomalies but most of these apparently originate from adjacent SiC grains. Only one Si₃N₄ grain, with ¹³C and ¹⁴N excesses, has a likely AGB origin. The C, N, and Si isotopic data show that the percentage of SiC grains of type Y and Z increase with decreasing grain size (from ∼1% for grains >2 μm to ∼5-7% for grains of 0.5 μm), providing an opportunity for isotopic analyses in these rare grains. Our measurements expand the number of Al-Mg analyses on SiC Z grains from 4 to 23 and the number of Ti analyses on Z grains from 2 to 11. Inferred²⁶Al/²⁷Al ratios of Z grains are in the range found in mainstream and Y grains and do not exceed those predicted by models of AGB nucleosynthesis. Cool bottom processing (CBP) has been invoked to explain the low ¹²C/¹³C ratios of Z grains, but this process apparently does not lead to increased ²⁶Al production in the parent stars of these grains. This finding is in contrast to presolar oxide grains where CBP is needed to explain their high ²⁶Al/²⁷Al ratios. The low ^46,47,49Ti/⁴⁸Ti ratios found in Z grains and their correlation with low ²⁹Si/²⁸Si ratios extend the trend seen in mainstream grains and confirm an origin in low-metallicity AGB stars. The relatively large excesses in ³⁰Si and ⁵⁰Ti in Z grains are predicted by our models to be the result of increased production of these isotopes by neutron-capture nucleosynthesis in low-metallicity AGB stars. However, the predicted excesses in ⁵⁰Ti (and ⁴⁹Ti) are much larger than those found. Even lowering the strength of the ¹³C pocket cannot solve this discrepancy in a consistent way.     

Isotopic compositions of different presolar silicon carbide size fractions from the Murchison meteorite

Abstract— We report measurements of isotopic ratios of C, N, Mg, Si, Ca, Ti, Cr, and Fe in bulk samples (aggregates of many grains) of up to seven different fractions of silicon carbide (SiC), ranging from 0.38 to 3.0μm in diameter, from the Murchison CM2 carbonaceous chondrite. Ratios of ¹²C/¹³C range from 37 to 42 and ¹⁴N/¹⁵N ratios from 370 to 520, within the range of single‐grain measurements on coarser samples and in agreement with an asymptotic giant branch (AGB) star origin of most of the grains. Variations among size fractions do not show any simple trend and can be explained by varying contamination with isotopically normal material. Silicon isotopic ratios vary only little and, with one exception, lie to the right of the singlegrain mainstream correlation line. This might indicate a higher percentage of the minor populations Y and Z among finer grain‐size fractions. All bulk samples have large ²⁶Mg excesses attributed to the presence of short‐lived ²⁶Al at the time of grain formation. Inferred ²⁶Al/²⁷Al ratios are much larger than those measured in single larger mainstream grains. This is probably because of the presence of SiC grains of type X; we obtain an estimate of 0.4 for their ²⁶Al/²⁷Al ratio. Our Ca‐isotopic measurements, the first made on presolar SiC grains, show excesses in ⁴²Ca and ⁴³Ca, which is in general agreement with theoretical expectations for AGB stars. Calcium‐44 excesses are much larger than expected and are probably because of X grains, which have high⁴⁴Ca excesses because of the decay of short‐lived ⁴⁴Ti produced in supernova explosions. We arrive at an estimate of 0.014 for the initial ⁴⁴Ti/⁴⁸Ti ratio of the X grains, within the range obtained from previous single X grain measurements. The Ti‐isotopic ratios of the bulk samples show a V‐shaped pattern with excesses of all isotopes relative to ⁴⁸Ti. Isotopes ⁴⁶Ti, ⁴⁷Ti, and ⁵⁰Ti show excesses relative to the correlation between Ti and Si ratios for single grains and are in general agreement with theoretical models of s‐process nucleosynthesis in AGB stars. In contrast, ⁴⁹Ti does not show any excess relative to the singlegrain data; it also fails to agree with theory, which predicts much larger excesses than observed. Measured ⁵³Cr/⁵²Cr and ⁵⁷Fe/⁵⁶Fe ratios are normal within errors. The first result is expected even for Cr in AGB star envelopes, but the second result suggests that most of the Fe analyzed originates from contamination. We have found no simple trends in isotopic composition with respect to grain size that can be interpreted in terms of nucleosynthetic origin, unlike the results for Kr, Xe, Ba, and Sr.     

Isotopic properties of silicon carbide X grains from the Murchison meteorite in the size range 0.5‐1.5 μm

Abstract— We report isotopic abundances for C, N, Mg‐Al, Si, Ca‐Ti, and Fe in 99 presolar silicon carbide (SiC) grains of type X (84 grains from this work and 15 grains from previous studies) from the Murchison CM2 meteorite, ranging in size from 0.5 to 1.5 μm. Carbon was measured in 41 X grains, n in 37 grains, Mg‐Al in 18 grains, Si in 87 grains, Ca‐Ti in 25 grains, and Fe in 8 grains. These X grains have ¹²C/¹³C ratios between 18 and 6800, ¹⁴N/¹⁵n ratios from 13 to 200, δ²⁹Si/²⁸Si between ?750 and +60%₀, δ³⁰Si/²⁸Si from ?770 to ?10%₀, and ⁵⁴Fe/⁵⁶Fe ratios that are compatible with solar within the analytical uncertainties of several tens of percent. Many X grains carry large amounts of radiogenic ²⁶Mg (from the radioactive decay of ²⁶Al, half‐life ? 7 times 10⁵ years) and radiogenic ⁴⁴Ca (from the radioactive decay of ⁴⁴Ti, half‐life = 60 years). While all X grains but one have radiogenic ²⁶Mg, only ～20% of them have detectable amounts of radiogenic ⁴⁴Ca. Initial ²⁶Al/²⁷Al ratios of up to 0.36 and initial ⁴⁴Ti/⁴⁸Ti ratios of up to 0.56 can be inferred. The isotopic data are compared with those expected from the potential stellar sources of SiC dust. Carbon stars, Wolf‐Rayet stars, and novae are ruled out as stellar sources of the X grains. The isotopic compositions of C and Fe and abundances of extinct ⁴⁴Ti are well explained both by type Ia and type II supernova (SN) models. The same holds for ²⁶Al/²⁷Al ratios, except for the highest ²⁶Al/²⁷Al ratios of >0.2 in some X grains. Silicon agrees qualitatively with SN model predictions, but the observed ²⁹Si/³⁰Si ratios in the X grains are in most cases too high, pointing to deficiencies in the current understanding of the production of Si in SN environments. The measured ¹⁴n/¹⁵n ratios are lower than those expected from SN mixing models. This problem can be overcome in a 15 M_odot; type II SN if rotational mixing, preferential trapping of N, or both from ¹⁵n‐rich regions in the ejecta are considered. The isotopic characteristics of C, N, Si, and initial ²⁶Al/²⁷Al ratios in small X grains are remarkably similar to those of large X grains (2–10 μm). Titanium‐44 concentrations are generally much higher in smaller grains, indicative of the presence of Ti‐bearing subgrains that might have served as condensation nuclei for SiC. The fraction of X grains among presolar SiC is largely independent of grain size. This implies similar grain‐size distributions for SiC from carbon stars (mainstream grains) and supernovae (X grains), a surprising conclusion in view of the different conditions for dust formation in these two types of stellar sources.