Experimental determination of photostability and fluorescence‐based detection of PAHs on the Martian surface

Abstract– Even in the absence of any biosphere on Mars, organic molecules, including polycyclic aromatic hydrocarbons (PAHs), are expected on its surface due to delivery by comets and meteorites of extraterrestrial organics synthesized by astrochemistry, or perhaps in situ synthesis in ancient prebiotic chemistry. Any organic compounds exposed to the unfiltered solar ultraviolet spectrum or oxidizing surface conditions would have been readily destroyed, but discoverable caches of Martian organics may remain shielded in the subsurface or within surface rocks. We have studied the stability of three representative polycyclic aromatic hydrocarbons (PAHs) in a Mars chamber, emulating the ultraviolet spectrum of unfiltered sunlight under temperature and pressure conditions of the Martian surface. Fluorescence spectroscopy is used as a sensitive indicator of remaining PAH concentration for laboratory quantification of molecular degradation rates once exposed on the Martian surface. Fluorescence‐based instrumentation has also been proposed as an effective surveying method for prebiotic organics on the Martian surface. We find the representative PAHs, anthracene, pyrene, and perylene, to have persistence half‐lives once exposed on the Martian surface of between 25 and 60 h of noontime summer UV irradiation, as measured by fluorescence at their peak excitation wavelength. This equates to between 4 and 9.6 sols when the diurnal cycle of UV light intensity on the Martian surface is taken into account, giving a substantial window of opportunity for detection of organic fluorescence before photodegradation. This study thus supports the use of fluorescence‐based instrumentation for surveying recently exposed material (such as from cores or drill tailings) for native Martian organic molecules in rover missions.     

Regional trends in crude birth,death, and natural increase rates in Russia and the USSR: 1897-1989

"This paper establishes and discusses briefly regional patterns and trends in crude birth, death, and natural increase rates in Russia and the USSR from the turn of the century to 1989. The study is based on a comparable regional framework and placed in the context of the demographic transition theory. It discusses sources, collection, and quality of data, as well as necessary estimating procedures. An attempt also is made to examine briefly regional age-standardized rates."     

Migrating magmatism in the northern US Cordillera: in situ U–Pb geochronology of the Idaho batholith

New in situ laser ablation-inductively coupled plasma-mass spectrometry and sensitive high-resolution ion microprobe U–Pb geochronology of zircons from the Idaho batholith and spatially overlapping Challis intrusions reveals a series of discrete magmatic belts of different ages and compositions. Following the accretion of the Blue Mountains province to North America along the Salmon River suture zone, two compositionally diverse belts of metaluminous plutons formed both adjacent to the suture and well inboard of it. These were constructed from ~100 to 85 Ma and were followed by a voluminous pulse of peraluminous magmatism, forming the bulk of the Atlanta lobe and largest fraction of the batholith between ~80 and 67 Ma. Around 70 Ma, a later and more spatially restricted suite of metaluminous plutons formed around the Bitterroot lobe of the batholith. This was followed by another pulse of voluminous peraluminous magmatism in the Bitterroot lobe, lasting from ~66 to 54 Ma. The changes from low volume metaluminous to high volume peraluminous magmatism may reflect a combination of changes in the angle and segmentation of the subducting Farallon plate and over thickening of the continental lithosphere. All of these features were then cut by plutons and dikes associated with the Challis volcanic field, lasting from ~51 to 43 Ma. Inherited components are pervasive in zircons from most phases of the batholith. While Precambrian components are very common, zircons also often contain cores or mantles that are 5–20 million years older than their rims. This suggests that the early phases of the batholith were repeatedly cannibalized by subsequent magmas. This also implies that the older suites may have been originally more aerially extensive than their currently exposed forms.     

A new water-level history for Lake Ontario basin: evidence for a climate-driven early Holocene lowstand

Piston cores from deep-water bottom deposits in Lake Ontario contain shallow-water sediments such as, shell-rich sand and silt, marl, gyttja, and formerly exposed shore deposits including woody detritus, peat, sand and gravel, that are indicative of past periods of significantly lower water levels. These and other water-level indicators such as changes in rates of sedimentation, mollusc shells, pollen, and plant macrofossils were integrated to derive a new water-level history for Lake Ontario basin using an empirical model of isostatic adjustment for the Great Lakes basin to restore dated remnants of former lake levels to their original elevations. The earliest dated low-level feature is the Grimsby-Oakville bar which was constructed in the western end of the lake during a near stillstand at 11–10.4 (12.9–12.3 cal) ka BP when Early Lake Ontario was confluent with the Champlain Sea. Rising Lake Ontario basin outlet sills, a consequence of differential isostatic rebound, severed the connection with Champlain Sea and, in combination with the switch of inflowing Lake Algonquin drainage northward to Ottawa River valley via outlets near North Bay and an early Holocene dry climate with enhanced evaporation, forced Lake Ontario into a basin-wide lowstand between 10.4 and 7.5 (12.3 and 8.3 cal) ka BP. During this time, Lake Ontario operated as a closed basin with no outlets, and sites such as Hamilton Harbour, Bay of Quinte, Henderson Harbor, and a site near Amherst Island existed as small isolated basins above the main lake characterized by shallow-water, lagoonal or marsh deposits and fossils indicative of littoral habitats and newly exposed mudflats. Rising lake levels resulting from increased atmospheric water supply brought Lake Ontario above the outlet sills into an open, overflowing state ending the closed phase of the lake by ~7.5 (8.3 cal) ka BP. Lake levels continued to rise steadily above the Thousand Islands sill through mid-to-late Holocene time culminating at the level of modern Lake Ontario. The early and middle Holocene lake-level changes are supported by temperature and precipitation trends derived from pollen-climate transfer functions applied to Roblin Lake on the north side of Lake Ontario.