Chemical composition of Russian Arctic precipitation in 2007-2015

The results of observations of the chemical composition of precipitation in the Russian Arctic in 2007-2015 are summarized including the data from NP-35 drifting ice station obtained in 2007-2008 in the framework of the joint program of Arctic and Antarctic Research Institute and Voeikov Main Geophysical Observatory. The qualitative and quantitative difference in the chemical composition of precipitation in the Atlantic, Siberian, and Pacific sectors of the Russian Arctic is revealed. It is found that the concentration of microelements (heavy metals) in precipitation at NP-35 ice station did not exceed 12% of total ions at the lowest mineralization. The comparative analysis is presented of the concentration of sulfate ions in precipitation in Norilsk and at NP-35 ice stations.     

The charge distribution on interstellar grains—The effect of induced charge

A calculation of the equilibrium charge acquired by interstellar grains is given, which takes account of polarization charges that are induced in a grain by incident ions and electrons.Both metal and dielectric grains are considered and photoionization of the latter grains by UV radiation is taken into account where necessary. It is found that the inclusion of the polarization charges in the calculation is only important in gas clouds where the mean charge on a grain is low (<1e); that is, for HI regions and dense molecular clouds. In such clouds, the effect of the polarization charges is to increase the amount of negative charge acquired by a grain. A discussion is given concerning the validity of the classical electrostatic theory employed in the paper for small grains of radius 10^–6 cm, and some astrophysical consequences of the modification of the grain charge by polarization effects are considered.     

Occurrence and characteristics of sporadic sodium layer observed by lidar at a mid-latitude location

Na lidar observations of SSL during the past 5 years at a mid-latitude location (Wuhan, China, 31°N, 114°E) are reported in this paper. From 26 SSL events detected in about 230 h of observation, an SSL occurrence rate of 1 event/9 h at our location was obtained. This result, combined with that reported by Nagasawa and Abo (Geophys. Res. Lett. 22 (1995) 263) at Tokyo, Japan, reveals that the SSL occurrence can be relatively frequent at some mid-latitude locations. The statistical analyses of main parameters for the 26 SSL events were made, and the results were compared with those previously reported. By examining the corresponding data from a nearby ionosonde, it was found that there was a fairly good correlation between SSL and Es. Of the 18 pairs of SSL and Es events checked, 15 of SSL were accompanied by Es, and 8 pairs of them were correlated within 1 h in time and within 5 km in altitude. From the analyses of observed perturbations during SSL development, the role of dynamic processes of atmosphere in the SSL formations were emphasized.     

The environmental planning and management approach towards the development and management of the Osun natural spring project,Ibadan, Nigeria

There is a general shortage of potable water in Nigeria, partly through the lack of natural provision and partly because of rapid urban growth that has largely been unplanned. The paper describes the recent redevelopment of a public water facility in a run-down area of Ibadan which is part of the Sustainable Ibadan Project. Despite funding from national and international bodies, the development is strongly based at community level. The local inhabitants feel they have control over their own water supply through their representatives on the various planning and managing committees. This aims to reduce vandalism and to increase pride and involvement in the community. The project is a pilot for other projects around Ibadan, some of which have begun and others are being planned. This paper describes the administrative structures and management principles that have been employed. It forcefully advocates community-based planning and management which respects both the environment and the water-users, and involves a major “bottom-up” element. This revised version was published online in July 2006 with corrections to the Cover Date.     

Deep structure of the Racha earthquake source zone from seismic tomography data

The Racha earthquake of 1991 was the strongest of the earthquakes recorded in the Caucasus. It was studied by an international epicentral expedition. Unique data gathered by this expedition included records of aftershocks whose swarm was very intense. A 3-D velocity model is obtained from analysis of these data by the method of local earthquake tomography. The ancient crystalline basement and the sedimentary-volcanic Mesozoic-Cenozoic cover could be identified from cross sections of the P wave field. The eastern and western boundaries of an uplift in the basement of the Dzirulskii Massif are delineated. Linear low velocity heterogeneities correlating with the active Kakheti-Lechkhumi fault zone and two Trans-Caucasian linear fault zones are discovered in the basement. The cloud of aftershock hypocenters is shown to correlate with a reflector coinciding with the cover-basement interface.     

Mapping of sound scattering objects in the northern part of the Barents Sea and their geological interpretation

On cruises 25 (2007) and 28 (2011) of the R/V Akademik Nikolai Strakhov in the northern part of the Barents Sea, the Geological Institute, Russian Academy of Sciences, conducted comprehensive research on the bottom relief and upper part of the sedimentary cover profile under the auspices of the International Polar Year program. One of the instrument components was the SeaBat 8111 shallow-water multibeam echo sounder, which can map the acoustic field similarly to a side scan sonar, which records the response both from the bottom and from the water column. In the operations area, intense sound scattering objects produced by the discharge of deep fluid flows are detected in the water column. The sound scattering objects and pockmarks in the bottom relief are related to anomalies in hydrocarbon gas concentrations in bottom sediments. The sound scattering objects are localized over Triassic sequences outcropping from the bottom. The most intense degassing processes manifest themselves near the contact of the Triassic sequences and Jurassic clay deposits, as well as over deep depressions in a field of Bouguer anomalies related to the basement of the Jurassic–Cretaceous rift system     

Westward moving dynamic substorm features observed with the IMAGE magnetometer network and other ground-based instruments

We present the ground signatures of dynamic substorm features with particular emphasis on the event interpretation capabilities provided by the IMAGE magnetometer network. This array covers the high latitudes from the sub-auroral to the cusp/cleft region. An isolated substorm on 11 Oct. 1993 during the late evening hours exhibited many of well-known features such as the Harang discontinuity, westward travelling surge and poleward leap, but also discrete auroral forms, known as auroral streamers, appeared propagating westward along the centre of the electrojet. Besides the magnetic field measurements, there were auroral observations and plasma flow and conductivity measurements obtained by EISCAT. The data of all three sets of instruments are consistent with the notion of upward field-aligned currents associated with the moving auroral patches. A detailed analysis of the electro-dynamic parameters in the ionosphere, however, reveals that they do not agree with the expectations resulting from commonly used simplifying approximations. For example, the westward moving auroral streamers which are associated with field-aligned current filaments, are not collocated with the centres of equivalent current vortices. Furthermore, there is a clear discrepancy between the measured plasma flow direction and the obtained equivalent current direction. All this suggests that steep conductivity gradients are associated with the transient auroral forms. Also self-induction effects in the ionosphere may play a role for the orientation of the plasma flows. This study stresses the importance of multi-instrument observation for a reliable interpretation of dynamic auroral processes.     

Effect of Silica Activity on OH- IR Spectra of Olivine: Implications for Low-aSiO2 Mantle Metasomatism

Hydrogen solubility and hydroxyl substitution mechanism in olivineat upper-mantle conditions are not only a function of pressure,temperature, water fugacity and hydrogen fugacity, but are alsoinfluenced by silica activity. Olivine synthesized in equilibriumwith magnesiowüstite displays hydroxyl stretching bandsin the wavenumber range from 3640 to 3430 cm^–1. In contrast,olivine in equilibrium with orthopyroxene shows absorption bandsin a narrower wavenumber range from 3380 to 3285 cm^–1.The two fundamentally different spectra are assigned to hydroxylin tetrahedral and octahedral sublattices, respectively. Olivinein equilibrium with orthopyroxene is also less capable of incorporatinghydroxyl, relative to olivines in equilibrium with magnesiowüstite,by about a factor of ten. A comparison of spectra obtained aspart of this study with hydroxyl spectra of natural mantle olivinesshows that the latter display hydroxyl stretching patterns reminiscentof equilibrium with magnesiowüstite, although undoubtedlyolivine in the Earth’s mantle coexists with orthopyroxene.This may be attributed to a metasomatic overprint by a low-silicafluid and/or melt that was in reaction relationship with orthopyroxene.A likely metasomatic agent is a carbonatitic melt. When carbonatiticmelts decompose to oxides and CO₂, they may temporarily imposea low-aSiO₂ environment inherited by the olivine structure.If this suggestion proves true, Fourier transform IR spectroscopymay be used to fingerprint metasomatic episodes in the lithosphericmantle. KEY WORDS: FTIR spectrometry; olivine; mantle; metasomatism; water     

Simulation of forsterite protonation by the interatomic potential method

The interatomic potential method in an ionic approximation was used to model the protonation of forsterite crystals. The formation of isolated OH^? groups in iron-free and iron-bearing crystals and neutral clusters of protonated cation vacancies was considered. It was shown that the presence of trivalent impurities may significantly facilitate protonation processes owing to their reduction to a divalent state or formation of clusters with cation vacancies. In most cases, charge balancing of hydrogen-bearing defects by magnesium vacancies is energetically favorable over that involving silicon vacancies.